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1.
Melt and fluid inclusions were studied in the minerals of Cenozoic olivine melanephelinites from the Chukehi Peninsula, Russia. The rock contain several generations of olivine phenocrysts varying in composition at mg=0.88 - 0.77. The phenocrysts bear fluid and melt inclusions recording various stages of melt crystallization in volcanic conduits and shallow magma chambers. Primary fluid inclusions are CO2-dominated with a density of up to 0.93 g/cm^3. All fluid inclusions are partially leaked, which is indicated by haloes of tiny fluid bubbles around large fluid inclusions in minerals. Melt inclusions contain various daughter crystals, which were completely resorbed in thermometric experiments at about 1230~C. Assuming that this temperature corresponds to the entrapment conditions of the CO2 fluid inclusions, the minimum pressure of the beginning of magma degassing is estimated as 800MPa. Variations in the compositions of homogenized silicate melt inclusions indicate that olivine was the earliest crystalline phase followed by clinopyroxene, nepheline and orthoclase. This sequence is in agreement with the mineralogy of the rocks. The melts are strongly enriched in incompatible trace elements and volatiles (in addition to CO2 , high C1, F, and S contents were detected). There are some differences between the compositions of melts trapped in minerals from different samples. Variations in SiO2 , FeO, and incompatible element contents are probably related to melt generations at various levels in a homogeneous mantle reservoir.  相似文献   

2.
Mantle xenoliths are common in the Cenozoic basalts of the Changbaishan District, Jilin Province, China. Sulfide assemblages in mantle minerals can be divided into three types: isolated sulfide grains, sulfide-meh inclusions and filling sulfides in fractures. Sulfide-inch inclusions occur as single-phase sulfides, sulfide-silicate melt, and CO2-sulfide-silicate melt inclusions. Isolated sulfide grains are mainly composed of pyrrhotite, but cubanite was found occasionally. Sulfide-inch inclusions are mainly composed of pentlandite and MSS, with small amounts of chalcopyrite and talnakhite. The calculated distribution coefficient KD3 for lherzolite are similar to that of mean experimental value. The bulk sulfides in lherzolite were in equilibrium with the enclosing minerals, indicating immiscible sulfide melts captured in partial melting of upper mantle. Sulfide in fractures has higher Ni/Fe and (Fe + Ni)/S than those of sulfide melt inclusions. They might represent later metasomatizing fluids in the mantle. Ni/Fe and ( Fe + Ni )/S increase from isolated grains, sulfide inclusions to sulfides in fractures. These changes were not only affected by temperature and pressure, but by geochemistry of Ni, Fe and Cu, and sulfur fugacity as well.  相似文献   

3.
Crystalline and melt inclusions were studied in garnet, diopside, potassium feldspar, and sphene from the garnet syenite porphyry of the carbonatite-bearing complex Mushugai-Khuduk, southern Mongolia. Phlogopite, clinopyroxene, albite, potassium feldspar, sphene, wollastonite, magnetite, Ca and Sr sulfates, fluorite, and apatite were identified among the crystalline inclusions. The melt inclusions were homogenized at 1010℃~1080℃ and analyzed on an electron microprobe. Silicate, salt, and combined silicate-salt melt inclusions were found. Silicate melts show considerable variations in SiO2 concentration (56 to 66wt% ), high Na2O + K20 (up to 17wt% ), and elevated Zr, F, and Cl contents. In terms of bulk rock chemistry, the silicate melts are alkali syenites. During thermometric experiments, salt melt inclusions quenched into homogeneous glasses of predominantly sulfate compositions containing no more than 1.3wt% SiO2. These melts are enriched in alkalis, Ba, Sr, P, F, and Cl. The investigation of the silicate and salt melt inclusions in minerals of the garnet syenite porphyries indicate that these rocks were formed under influence of the processes of crystallization differentiation and magma separation into immiscible silicate and salt (sulfate)liquids.  相似文献   

4.
Fluid inclusion study has been carried out for the carbonatite dykes/veins and the ore-hosted dolostone of the Bayan Obo superlarge REE-Fe-Nb deposit in order to provide the evidence and constraint for their origin. Based on the detailed geological observation and mineralogical investigation, the heating and cooling stage and laser Raman spectroscopy were mainly used for the laboratory work of this study. Following results have been obtained: ( 1 ) The discovery of melt and melt-fluid inclusions from carbonatite dykes/veins in the Dulahara and Jianshan Mountains, combined with the fine-grained (aplitic) texture of rocks, as well as the types and features of fluid inclusions such as CO2 enrichment, higher homogenization temperature, provides a direct evidence for the magmatic origin of these dykes/veins. (2) The carbonatite dykes/veins distributed in two regions, nearby the axis of the Kuangou anticline and in the east to Bayan Obo town, mainly show coarse-grained texture. No melt inclusion was found, and the fluid inclusions possess features of less CO2, lower homogenization temperature and higher salinity. They are tentatively identified as veins formed by some carbonate-rich hydrothermal solution. (3) Bedding carbonate layers/lens within the hanging wall and foot wall of ore-hosted dolostone, previously recognized as of magmatic origin, mainly composed by dolomite. The existence of single phase pure aqueous inclusions with very low homogenization temperature indicates their sedimentary origin. (4) The ore-hosted dolostone possesses apparent bedding and laminated structures. No melt inclusion was found, but, both single phase pure aqueous inclusions and CO2 bearing muhi-phase fluid inclusions coexisted in dolostones. In the direction towards ore-bodies, the homogenization temperature and CO2 contents of fluid inclusion show an increasing tendency. It indicates the sedimentary origin of dolostone superimposed by late fluid metasomatism.  相似文献   

5.
The composition of fluid inclusions in the H2O-NaCl-CaCl2 system has been generally graphically estimated using the melting temperatures of hydrohalite ( Tm-HH ) and ice ( Tm-ice). Here we present two equations that can be used to calculate the relative proportion of NaCl ( i. e. , NaCL/[ NaCl + CaC12 ] , or XNacl ) and the total salinity ( i. e. , NaCl + CaCl2, wt% ) for fluid inclusions with ice as the last melting phase. XNacl can be calculated from Tm-HH using the following equation: y = (a+bx)^-1/c where y is XNacl, x is Tm_HH , a =0. 33124402, b =-0. 031518028, and c =0. 22932736. In the cases where only Tm-ice is measured and Tm-HH is not known, Tm-ice can be used as the maximum possible Tm-HH to calculate the maximum value of XNacl using the above equation. In these cases, the following equation can be used to calculate the maximum total salinity: y=(a+bx+cx2) l where y is salinity, x is Tm-HH , a =0, 057184817, b =0. 00078565757, and c = 5. 7262766E-6. Because the isothems in the field of ice are sub-parallel to the NaCl-CaCl2 binary side in the H2O-NaCl-CaCl2 ternary system, the errors in salinity calculation introduced by the above approximation are small ( less than 2 wt% ). A Windows program for calculation of XNacl and salinity is available at : http ://uregina. ca/-chiguox.  相似文献   

6.
山东招平断裂带大磨曲家金矿床流体包裹体初步研究   总被引:1,自引:0,他引:1  
The Damoqujia gold deposit, discovered recently and located in the north of Zhaoping fault zone, is a large altered rock type deposit. In this paper, we report the preliminary research results of the fluid inclusions and discuss its metallogenic implications. The homogenization temperatures of fluid inclusions fall into four ranges: 310 ~350℃, 230 ~270℃, 160 ~ 200℃ and 110 ~ 150℃ ; corresponding to the four stages of hydrothermal ore~forming processes : coarse grain pyrite~milk white quartz stage ( I ), smoky gray Au~bearing quartz~fine grain pyrite stage ( 11 ) , Au~bearing polymetallic sulfide~quartz stage ( III ) , and quartz~carbonate stage ( IV ). Ore~forming fluid is with low salinity and low density, ranging from 1.4 WtNacl% to 13.6 WtN~cl% and from 0.48g/cm~ to 1.03g/cm~ respectively. The inclusions are dominated by H20 and CO2 in gaseous compositions, and Na + and K ~ in positive ions, SO~~ and CI ~ in negative ions of liquid compositions. Au~S complex is the major form for transportation of gold. The pressure varied from 260MPa to 340MPa during the formation of CO2~bearing inclusions at the early mineralization; the fluids are rich in SO~~ and Na ". The pressure is 26 ~49 ~ 105 Pa during the formation of the aqueous salt inclusions in late mineralization, the inclusions are rich in CI~ ( F~ ), Na~. ~$18Oqu~,zis 10. 64 ~ 12.68%0, and the corresponding ~518 OH2o and ~&D is -5.44 ~ 6.47%0 and -95.52 ~ 106.48%o respectively. Based on the studies about compositions and hydrogen and oxygen isotopes of inclusions, it is evidenced that ore-forming fluid is magmatic hydrothermal fluid in early period, but affected by meteoric water in late.  相似文献   

7.
This paper is focused on the progress in the determination of water in glasses and melt inclusions with Raman spectroscopy. Using the presented "Comparator Technique" the water content of a sample is determined by siruple comparison with a known standard. A calibration curve is not necessary. Furthermore, with this technique the water concentration in silicate melt inclusions can be determined without exposing the inclusions for measurements. This is very important for extremely water-rich melt inclusions, which would loose H2O on exposure.  相似文献   

8.
The acoustic decrepitation method heats a small monomineralic sample and counts pressure impulses as the inclusions burst when they develop high internal pressures. For aqueous fluids, the decrepitation temperature is correlated with the homogenisation temperature, but gas rich fluids give a distinct and characteristic low temperature decrepitation peak which can be used to recognize gas rich fluid inclusions. This information is useful in exploration for Au deposits, which are frequently associated with CO2 rich and sometimes CH4 rich fluids. This distinctive decrepitation occurs because the CO2 rich inclusion fluids expand according to the gas law and develop internal pressures high enough to burst the host mineral grain at temperatures well below their homogenisation temperatures. In contrast, aqueous fluids condense to a liquid and vapour phase during post-entrapment cooling. Upon subsequent heating their internal pressures do not increase significantly until after homogenisation to a single phase occurs and hence they do not decrepitate "prematurely" as gas rich inclusions do. This behaviour is usually regarded as an annoyance in conventional microthermometric homogenisation studies, but can readily be used as an exploration aid to find mineralisation deposited from such gas rich fluids. Decrepitation results on samples from Cowra Ck, NSW, Australia, which have also been microthermometrically measured for CO2 content, show that amounts of less than 5 mole % CO2 are easily distinguished by decrepitation and amounts as low as 1 mole % CO2 may be determinable. Examples of the use of acoustic decrepitation in the study of 6 gold mines in the Shandong and Hebei provinces of China are discussed.  相似文献   

9.
The Partner Group does research in cosmology, focussing on the quantitative modeling of the structure and evolution of galaxies and galaxy clusters, the pattern of galaxies and of larger structures. The usual approach in this field is the dark matter paradigm, i.e. the assumption that the basic structures are laid out in a matter component of particles which interact only gravitationally. Numerical simulations of large scale and high resolution are used to follow the evolution of condensations of dark matter particles during cosmological evolution. Analytic models and detailed statistical investigations of astronomical data sets supplement the numerical work.  相似文献   

10.
In the work mitotic chromosomes in root-tips of 7 species native to Sichuan Pro- vince were examined and their karyotypes were analysed based on 7-8 cells at mitotic meta- phase, using Levan et al.'s (1964) nomenclature. The list of species and origin of the materials used in this work are provided in the appendix.  The micrographs of mitotic metaphase of all the materials are shown in Plates 1 and 2; the idiograms in Fig. 1, 1-9, and the parameters of chromosomes are provided in Tables 1-9.  All the chromosome countings and karyotypes in this paper are reported for the first time.      Characteristics of the karyotypes may be summarized as follows:      1.  2n=38 are found in all the materials except A. sichuanensis, which has 3 cytotypes, i.e, 2n=38+5B, 2n=38+lB and 2n=38+OB (Plate 2, 1-2, Fig. 1, 5-6).      2.  The karyotypes are of two major types: the karyotype of A. flaviflora falls into 3C in Stebbins's (1958, 197l) classification of karyotypes and those of all the other species into 2C. The two types are also different from each other in the number of large and medium-sized chromosomes pairs and morphology of the first pair of chromosomes (compare Plate 2, 5, Fig. 1, 9 with the other micrographs and idiograms).A. flaviflora with the karyotype 3C also differs from the other species in a series of gross morphological characters: the species is of a yellow and campanulate corolla.      3.  The species with caespitose leaves (A. caespitosa and A. omeiensis) have essentially the same karyotype, which is rather different from those of the species with scattered leaves. There are two pairs of small sm chromosomes (arm ratio ≥1.90) in the former karyotype (Tables 1 and 3), but all the small chromosomes are m or sm with arm ratio <1.80 in the latter karyotypes.  相似文献   

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本文基于产业演化及创业合成相关理论,从新兴产业创业合成的宏观、中观、微观方面的影响因素切入,在文献分析的基础上运用德尔菲法确立了由宏观经济、市场规模、行政制度、科技金融、产业集聚、技术创新、人力资本、资金资本、资源整合9个维度共23个指标构成的新兴产业创业合成能力评价体系。基于网络层次分析法建立新兴产业创业合成能力评价模型,确定各指标权重,其中产业集聚区规模、协同创新、知识产权、市场成长性等二级评价指标权重较高。依据各指标的重要性为政府提升新兴产业创业合成能力及新兴产业内企业发展提出对策建议。  相似文献   

18.
《普罗米修斯》2012,30(2):359-367
Export of manufactured goods will play a large role in the economic future of Australia, and manufacturing will be closely linked (in markets and investment) with the Pacific rim countries. Strategies for development are proposed, recognising the need for improvement in cultural outlook, technological credibility, research and development, and education and skill development at all levels.  相似文献   

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