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1.
研究了大气条件下Ni-21.3%Cu-3.5%C合金在450℃、600℃和750℃的氧化动力学。采用环境扫描电子显微镜(ESEM)、X-射线(XRD)和能谱仪(EDS)分析氧化膜形貌、结构和化学成分。研究表明:Ni-21.3%Cu-3.5%C舍金氧化动力学曲线不是抛物线与直线的简单叠加,而是具有其它多种形式。合金的氧化过程包括Ni、Cu的氧化增重和石墨氧化失重,但以石墨氧化失重为主。氧化膜为双层结构:内层为薄而致密的CuO层,外层为厚而均匀的NiO膜层。当球状石墨严重氧化形成凹坑后,金属氧化物很容易在坑壁上长成“冰晶状”。750℃氧化16h时膜厚约3.3μm。  相似文献   

2.
采用原子吸收分光光度计,分别测试经机械抛光和高温氧化后的NiTi合金样品在人体生理模拟液中镍离子的释放速度,结果表明NiTi合金表面氧化膜的形成可以有效地减少镍离子的溶出。  相似文献   

3.
用磁控溅射方法在Si衬底上制备了一系列NiO、Ta、Co的薄膜与多层膜,利用掠入射X射线散射方法研究了不同生长顺序的薄膜的表面、界面结构与形态,结果表明各层的沉积次序会影响各层的形态,尤其是SiO2层的厚度、质量密度等,对各层之间的界面粗糙度也会产生很大影响。进而研究了自旋阀结构的多层膜的界面形态和粗糙度,这对于解释含NiO的Co/Cu/Co基自旋阀的磁电阻提升提供了结构依据。  相似文献   

4.
文章按文献所述方法合成了酞菁镍粉体,制备了酞菁镍膜电板,用循环伏安法研究了酞菁镍的电化学性质;在0.1mol/L KCl 0.0lmol/L K3[Fe(CN)6]的溶液中,酞菁镍膜电板上可以进行可逆的电荷传递,并对氧还原有明显的抑制作用。  相似文献   

5.
本文主要采用XRD手段,研究了用镍盐浸渍过的Zr(OH)_4经过高温焙烧后所得ZrO_2晶型变化情况。结果表明镍盐的存在明显地抑制了四方ZrO_2向单斜ZrO_2转化过程。这种抑制作用是由于镍盐分解出的NiO单层分散在载体ZrO_2颗粒表面,防止了ZrO_2颗粒的进一步长大和颗粒间的烧结,从而避免了伴随的晶相转变。用XRD相定量法测得400℃,450℃,500℃焙烧后的样品中NiO在ZrO_2载体表面的分散量分别为0.101gNiO/100m~2ZrO_2,0.085gNiO/100m~2ZrO_2和0.068gNiO/100m~2ZrO_2。这些测定值均小于按密置单层模型计算出的理论分散阈值0.183gNiO/100m~2ZrO_2。比表面的测定结果表明:镍盐含量为0.10gNiO/gZrO_2时,样品的比表面最大,并且明显大于同样条件下所得的纯ZrO_2的比表面。  相似文献   

6.
采用射频反应磁控溅射氧化铪钯的方法,在硅衬底成功制备了高介电HfOxNy薄膜.利用原子力显微镜,研究氮的掺入对薄膜表面形貌的影响,结果表明,N的掺杂改善了HfO2薄膜的表面形貌,同时抑制了高温退火过程中表面粗糙度的增加;通过椭圆偏振仪对薄膜的光学特性的研究表明,随退火温度的升高,薄膜的折射率和消光系数都呈上升趋势.  相似文献   

7.
该文针对目前含尿素废水高温水解处理的成本和能耗问题,进行了NiO薄膜制备及电催化分解尿素的综合性教学实验设计。通过控制条件采用水热法,在导电玻璃FTO基底上生长了多孔道网络微结构NiO薄膜,研究了水热时间、煅烧温度、添加表面活性剂等制备条件对NiO薄膜电催化分解尿素性能的影响。对NiO薄膜进行XRD、XPS、SEM、TEM等组成、形貌表征,以及CV、LSV、Tafel曲线、EIS等电化学测试,结果表明:在最优水热12 h,300℃煅烧,添加结构导向剂EDTA条件下,制备的NiO薄膜电极与现有文献报道的镍泡沫电极材料相比,尿素电催化分解起始电位由0.60 V降低为0.36 V。  相似文献   

8.
利用磁控溅射法制备了AgNbFeB纳米微晶薄膜材料,对其结构和磁谱特征进行了分析和研究,发现该纳米微晶薄膜用作高频材料是很理想的。  相似文献   

9.
用热重分析(TGA)研究了Co-40Cr合金及其离子注钇样品在1 000℃空气中的恒温氧化动力学规律.用扫描电镜(SEM)对不同样品表面Cr2O3氧化膜的形貌进行了观测.用声发射(AE)方法对合金表面氧化膜在恒温生长阶段和空冷阶段的开裂与剥落进行了实时监测,根据相应的氧化膜开裂模型,对声发射信号在时域和数域上的分布情况进行了分析.结果表明离子注钇降低了Co-40Cr合金的恒温氧化速率,并提高了合金表面Cr2O3氧化膜的抗开裂和抗剥落性能.离子注钇提高合金抗氧化性能的主要原因在于钇细化了合金表面Cr2O3氧化膜的晶粒,提高了氧化膜的高温塑性和蠕变能力,并且显著降低了Cr2O3/Co-40Cr界面缺陷的数量和大小.  相似文献   

10.
碳纤维增强陶瓷基复合材料(CFRCMCs)具有良好的高温力学性能和热性能,是航空航天领域非常理想的热结构材料.但CFRCMCs中的碳纤维极易发生氧化,因此CFRCMCs的氧化防护问题一直是CFRCMCs研究的热点.文章对碳纤维改性、基体抗氧化技术、界面层抗氧化技术和表面涂层技术这四种CFRCMCs的抗氧化技术及其原理进行了评述,分析了各类抗氧化技术的特点并对其发展趋势进行了展望.  相似文献   

11.
The communication of people partially is the communication of cultures. Culture has a direct effect on international commercial activities in all aspects. Different conceptions about time, space, equality, law and the like, lead people to deal with things in different ways. So to know cultures of the counterpart is to facil-itate our enterprises so as to have a smooth and successful communication in commercial activity.  相似文献   

12.
风的曲线     
Rosco and I wait for the fishermen to return.I sit at a wooden bench near the store at Mt.Baker Resort and watch the clouds change shape. Rosco has my belt around his neck and an eight foot tow chain hooked to a tree. Dogs must be on a leash. Ducks and rabbits are loose.  相似文献   

13.
汉字倒说     
汉字的六书,《说文》对“转注”一类,语焉不详。后世学者提及转注,也仅限于许慎所举出的例字。《汉字例说》一文,作者从转注的角度综合考虑,对部分现代常用字作了分析,跟传统的解释有所不同。希望能抛砖引玉,互相切磋,以推进学术研究。  相似文献   

14.
Given a graph G,a subgraph C is called a clique of G if C is a complete subgraph of G maximal under inclusion and |C|≥2. A clique-transversal set S of G is a set of vertices of G such that S meets all cliques of G. The clique-transversal number, denoted as TC (G), is the minimum cardinality of a clique-transversal set in G. The clique-graph of G, denoted as K (G), is the graph obtained by taking the cliques of G as vertices, and two vertices are adjacent if and only if the corresponding cliques in G have nonempty intersection. Let F be a class of graphs G such that F={G|K(G) is a tree}. In this paper the graphs in F having independent clique-transversal sets are shown and thus TC (G)/|G|≤1/2 for all G ∈ F.  相似文献   

15.
《海外英语》2007,(5):44-45
It is worthy of noting that, whilst Crookston Castle witnessed the earlier and happier portion of Mary's variegated life,  相似文献   

16.
一、吃和喝吃苹果 eat an apple, 吃药 take medicine,吃糖 have some sweets,吃饭 have one's meals,吃馆子 dine out,吃惊 be surprised/  相似文献   

17.
《海外英语》2007,(5):10-11
Many college freshmen arrive woefully unprepared to do college work, and as disadvantaged populations continue to grow, the share of the American work force that has made it through college is expected to plummet. Many experts blame that educational failure not just on high schools but also on colleges. School & College, a special report by The Chronicle, looks at efforts to fix the system. What reforms would better prepare students for college? What should schools and colleges be doing differently? How should state and federal officials help?  相似文献   

18.
Different nations have different social cultures, and the social culture of every nation is developing with the development of the nation, language is greatly influenced by social culture, which enables language to possess national and historical characteristics. Word is the smallest, independent, meaningful linguistic unit of language. It can well reflect the national and historical characteristics. From synchronic aspect, the social and cultural influence on word meaning is mainly embodied in conceptual and associative meanings of word. The incorrespondence of word meaning is a phenomenon that exists in both conceptual and associative meanings of word among different languages. From diachronic aspect, the development of social culture causes some changes of word meaning to some extent. Therefore, social culture plays a key role in vocabulary learning and mastery of a language.  相似文献   

19.
钱生钱!     
我们绝大部分人都同意一件事情——我们喜欢金钱。但是你对金钱的喜欢之情足够到让你创立一份事业么?.财富通常被人忽视,主要在于人们不能真正了  相似文献   

20.
《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love.  相似文献   

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