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1.
对焙烧态镁铝水滑石吸附水溶液中溴离子进行了研究,考察了吸附时间、吸附液p H值和吸附温度对吸附量的影响,计算得到了有关动力学和热力学参数。结果表明:焙烧态镁铝水滑石对溴离子的吸附基本符合二级反应速率方程和Langmuir吸附等温式,500℃焙烧态水滑石(n Mg/n Al=4)的饱和吸附量达119.05mg·g-1。  相似文献   

2.
采用低过饱和共沉淀法合成了不同摩尔比的CuZnAl水滑石,XRD和TG-DTA分析表明它们晶形好,纯度高.以水滑石前体及其焙烧产物为吸附剂,研究其对甲基橙吸附性能的各种影响因素.结果表明:所有产品的吸附效果均很好,其中Cu/3Zn/Al水滑石焙烧产物的吸附效果最好,吸附的最佳条件为pH=5.00,温度为300℃,初始浓度为5.0×10-3mol/L,吸附剂用量为0.600g/L,吸附时间为70min,吸附率达到97.5%.  相似文献   

3.
本文研究了水滑石的复原与插层。采用水热法制备了镁铝碳酸根型水滑石(LDH,Mg/Al摩尔比为3)前体。前体经500℃焙烧4h得Mg-Al-O混合氧化物(LDO),将其分别加入到碳酸钠和烟酸的水溶液中,120℃水热处理12小时,所得产物经X射线衍射(XRD)、红外光谱(IR)等手段分析,确认为碳酸根型水滑石和烟酸柱撑水滑石。实验表明,焙烧后水滑石可以恢复为原来的层状结构,并获得了烟酸柱撑水滑石,其层间距由碳酸根型层间距0.77nm增加到0.807nm。  相似文献   

4.
类水滑石(Hydrotalcite-likecompound,HTLcs)是由二价和三价金属阳离子组成的具有水滑石层状晶体结构的混合金属氢氧化物。可用通式表示为[M2 1-xM3 x(OH)2]x [An-x/n]·mH2O,其中M2 是二价金属阳离子,可以有Mg2 ,Fe2 ,Co2 ,Ni2 ,Cu2 ,Zn2 ,Mn2 等;M3 是三价金属阳离子,可以有A  相似文献   

5.
本文研究铜镁铝水滑石(HTLCs)吸附红青莲染料废水的重复利用性。利用煅烧法对HTLCs进行再生,再生后重复利用其吸附红青莲染料废水,试验证明HTLCs是一种高效环保可重复利用的吸附剂。  相似文献   

6.
汽车行业减重的意识促进了镁合金的应用,其中Mg-Al-RE系镁合金的低成本化研究成功,使镁合金的使用领域拓宽。本文对Mg-4Al-4RE稀土耐热合金加入Si元素后的性能现状进行综述。采用硬度仪测试了合金材料热处理后的硬度,采用金相显微镜观察了试样的金相组织,结果表明:Mg-4Al-4RE合金由α-Mg相和Al11RE3组成,加入Si元素后合金由α-Mg相和Mg2Si相和Al11RE3相组成,经过热处理的Mg-4Al-4RE合金相转变为α-Mg相和Al2RE相;经过热处理的Mg-Al-RE-0.3Si相转变为α-Mg相、Mg2Si相和Al2RE相,合金中加入Si元素硬度增加。  相似文献   

7.
本文采用共沉淀法制备活性炭复合镍铝水滑石,考察加料方式产物合成的影响,同时对产物进行XRD和电化学测试实验。结果表明一步法得到的活性炭复合水滑石结晶度较好。为了研究水滑石材料的电化学性能,本文采用循环伏安技术考察了样品在6mol/L的Na OH的电解液中的电化学行为,实验结果显示活性炭复合镍铝水滑石有较好的电容性能。  相似文献   

8.
贺刚 《中国科技信息》2009,(19):19-20,25
实验采用热处理、酸浸泡及酸热复合处理分别对天然沸石进行改性。运用X-射线粉末衍射(XRD)和热重一差热分析(TG-DTA)对改性沸石样进行了表征,发现酸浸泡将天然沸石由Ca型改性为Na型斜发沸石,热处理使沸石水脱去疏通了沸石的孔道结构。考察了各改性沸石样的除氟性能,并对其除氟机理进行了探讨。结果表明:酸热复合处理制得的改性沸石样静态除氟容量最佳,为0.294mg/g,约为天然沸石(O.032rag/g)的9倍,其动态除氟容量为0.089mg/g,除氟最佳州值为6~7,除氟容量随水样中氟离子质量浓度的增加而增加,对氟离子的吸附符合Freundlich吸附等温模式。  相似文献   

9.
本文通过气雾化法制备了Al0.45Mg0.5Li0.05合金,利用X射线粉末衍射(XRD)、电子扫描显微镜(SEM)和热重/差热综合分析(TG/DTA)等表征手段研究了Al0.45Mg0.5Li0.05合金粉在氧气气氛下的氧化性能。结果表明,通过雾化法制备得到的Al0.45Mg0.5Li0.05合金粉体表面光滑、球形度高。Li和Mg的添加降低了合金的初始氧化温度,合金分别在472℃和527℃出现放热峰。XRD和SEM测试结果表明,在合金氧化过程中,Li和Mg首先发生选择性氧化并带动合金中一部分Al发生低温氧化,在此过程中形成的具有多孔结构的中间产物,促进了氧气和颗粒中残余金属相的扩散和氧化,合金在1000℃完全氧化。  相似文献   

10.
采用煤渣静态吸附水中氟和砷.考察煤渣投加量、震荡时间、进水浓度和pH值对煤渣吸附性能的影响.实验结果表明,每100 mL污水较为合适的煤渣用量为6 g;煤渣对氟和砷的最佳吸附时间为3 h;对高氟水的吸附效果较好,对低氟水的去除效果相对较差;对高浓度及低浓度的砷均具有较好的吸附效果,去除率均达到95%以上;pH值对氟和砷的吸附影响不大.  相似文献   

11.
CAS should stick to the principle of rendering service to, and giving impetus for, the development of China's science enterprise by making S&T innovations, said CAS President LU Yongxiang. The CAS president made the remarks in a recent talk to communicate the gist of the winter session of the Party's Leading-member Group at CAS, which was held from 7 to 11 January in Beijing.  相似文献   

12.
This study examined how students who had no prior experience with videoconferencing would react to the use of videoconferencing as an instructional medium. Students enrolled in seven different courses completed a questionnaire at the beginning of the semester and again at the end of the semester. Students at the origination and remote sites did not differ in their reactions toward videoconferencing but there was a significant difference for gender. Women reacted less favorably to videoconferencing. Compared to the beginning of the semester, students reported significantly less positive attitudes toward taking a course through videoconferencing at the end of the semester. There were no significant differences in students' attitudes toward videoconferencing across courses at the beginning of the semester but there were significant differences across the courses at the end of the semester. The results suggest the need for better preparation for both students and instructors.  相似文献   

13.
With great care, Dr. ZHOU Zhonghe takes out a package wrapped by cotton tissue from a drawer and says: "This is the gem of our collections: the fossil of a bird that lived 125 million years ago!" Then, pointing at a tiny mound, he explains: "Look, this is the claw and that is the head. It was in the egg shell and ready to hatch ... The species fell into a family of waterside inhabitants."  相似文献   

14.
Ajoint study by Prof. ZHANG Zhibin from the CAS Institute of Zoology and his co-workers from Norway, US and Swiss have indicated that historical outbreaks of migratory locusts in China were associated with cold spells, suggesting that China's projected climate warming could decrease the pest's numbers. The study was published in Proceedings of theNational Academy of Sciences on 17 September, 2007.  相似文献   

15.
A computer-mediated group is a complex entity whose members exchange many types of information via multiple means of communication in pursuit of goals specific to their environment. Over time, they coordinate technical features of media with locally enacted use to achieve a viable working arrangement. To explore this complex interaction, a case study is presented of the social networks of interactions and media use among members of a class of computer-supported distance learners. Results show how group structures associated with project teams dominated who communicated with whom, about what, and via which media over the term, and how media came to occupy their own communication niches: Webboard for diffuse class-wide communication; Internet Relay Chat more to named others but still for general communication across the class; and e-mail primarily for intrateam communication. Face-to-face interaction, occurring only during a short on-campus session, appears to have had a catalytic effect on social and emotional exchanges. Results suggest the need to structure exchanges to balance class-wide sharing of ideas with subgroup interactions that facilitate project completion, and to provide media that support these two modes of interaction.  相似文献   

16.
Electronic data interchange (EDI) provides means for interorganizational communication, creates network externalities, requires an advanced information technology (IT) infrastructure, and relies on standards. In the diffusion of such innovations, institutional involvement is imperative. Such institutions contain governmental agencies, national and global standardization organizations, local government, and nonprofit private organizations like industry associations. The last type of organizations we call intermediating institutions. They intermediate or coordinate ("inscribe") the activities of a group of would-be adopters. Unfortunately, little is known of how these organizations shape the EDI diffusion trajectory. In this article we examine one specific type of intermediating organizations?industry associations?and how they advanced the EDI diffusion process in the grocery sectors of Hong Kong, Denmark and Finland. We identify six institutional measures, placed into a matrix formed by the mode of involvement (influence vs. regulation) and the type of diffusion force (supply push vs. demand pull), that can be mobilized to further the EDI diffusion. Industry associations were found to be active users of all these measures to varying degrees. Their role was critical especially in knowledge building, knowledge deployment, and standard setting. Furthermore, institutional involvement varied due to policy and cultural contingencies and power dependencies.  相似文献   

17.
The increasing prospects of digital piracy has prompted the perceived need by electronic publishers to adopt technical systems of protection, and governments to reform their copyright laws. This article is a preliminary study of the management of intellectual property by electronic publishers, defined as those involved in the production of online databases, and CD-ROMs. It focuses on three main issues: (1) how electronic publishers view the increasing threat of piracy; (2) the methods of protection employed to protect intellectual property in digital format; and (3) the importance of technological protection of intellectual property in electronic publications. The analysis is based on a sample of 23 UK electronic publishers. The interviews revealed an interesting assortment of protection methods and did not show that technological protection was a preferred way. Instead, the means of protection, in addition to copyright law, comprised niche markets, pricing, trust, bad publicity, and nontechnical and technical means.  相似文献   

18.
Long-standing conflict between domain name registrants and trademark holders prompted the Internet Corporation for Assigned Names and Numbers (ICANN) to create a global, mandatory arbitration procedure known as the Uniform Dispute Resolution Policy (UDRP). The UDRP has been used in 2166 cases involving 3938 domain names as of 1 November 2000. The policy gives the initiator of a complaint, generally a trademark holder, the right to choose which ICANN-accredited dispute resolution service provider (RSP) will handle the case. During the preparation of the UDRP,some feared that complainant selection would lead to "forum shopping" that might bias the results. This article performs a statistical assessment of the forum-shopping thesis and finds support for it. There are statistically significant differences in the various RSPs' propensity to take away names from defendants; there are also major differences in the number of cases brought to each RSP. RSPs who take away names have the larger share of cases. The study examines other variables that might explain differences in market share, such as price, the plaintiff's nationality, or the time taken to decide a case. It finds that nationality and time also are correlated with market share. The study concludes that shopping for a favorable outcome is an important factor in the UDRP.  相似文献   

19.
Prof. Raymond C.K. Chen, a neuropsychologist with the CAS Institute of Psychology, has made novel progress in his studies of schizophrenia. His work has been reported by a recent issue of Behavioural Neurology.  相似文献   

20.
Prof. SUN Changpu from the CAS Institute of Theoretical Physics and coworkers from University of Basel in Switzerland have worked out a way --at least in theory --to split a beam of molecules according to their chirality. The technique involves passing the molecules through three different laser beams and is similar to the famous Stern-Gerlach effect, whereby a beam of atoms passing through a magnetic field is split in two according to the atoms' spin states (Phys. Rev. Lett. 99 130403).  相似文献   

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