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溴乙烷与氢氧化钠或氢氧化钾乙醇溶液反应的研究 总被引：1，自引：0，他引：1
20 0 0版高中化学第二册 (试验修订本·必修加选修 ) ,安排了溴乙烷的消去反应[1] :溴乙烷与强碱 (ＮａＯＨ或ＫＯＨ)的醇溶液共热 ,从分子中脱去ＨＢｒ,生成乙烯。而实际上 ,卤代烷的取代反应和消去反应的竞争是一个比较复杂的问题。不少大学有机化学教材在论述这一问题时 ,均明确指出 :卤代烷进行消去反应的活性顺序是 :3°ＲＸ >2°ＲＸ >1°ＲＸ ;没有支链的伯卤代烷 ,与强亲核试剂(如ＯＨ-、Ｃ2 Ｈ5Ｏ-等 )作用 ,主要起ＳＮ2反应 ,消去反应很少。那么 ,溴乙烷等直链伯卤代烷 ,与氢氧化钠或氢氧化钾醇溶液 (通常指乙醇溶液 )共热 ,究竟… 相似文献
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卤代烷就是烃分子中的氢原子被卤素取代的产物。卤代烷是一种速效灭火剂,这是众所周知的事实。常用的卤代烷灭火剂有1211[CF_2ClBr]1301[CF_3Br]、1202[CF_2Br_2]、2402[C_2F_3Br_2]等,由于卤代烷灭火剂效率高,又没有毒性,所以,自1930年卤代烷灭火剂问世以来,深受人们的欢迎。 相似文献
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发现和合成新的碳负离子化合物是当今有机化学研究的前沿.交换已知的三均三嗪分子中的C原子和N原子位置,得到分子式为C7N6H6的一种新化合物.它以C原子为中心,称为碳中心三均三嗪.新化合物分子呈草帽形,顶点为C原子,特点为:(1)中心C原子上聚集较多的负电荷,正电荷分布在草帽边沿,使本为中性的分子,中心C原子显示很强的负离子特性;(2)中心C原子的第一电离能很低,极易失去电子.作为潜在的格氏试剂,在金属化学合成及反应中具有广阔的应用前景.文章应用DFT理论,使用Gaussian09软件包,对该分子进行模拟计算,借助分子结构分析,论述该中性分子具有碳负离子性质起因. 相似文献
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一、选择题(每小题6分,共6 0分)1.已知y =f(x)是定义在R上的偶函数,当x>0时,f(x) =log2 (1 x) .那么,当x <0时,f(x) =( ) .(A)log2 (1 x) (B)log2 (1-x)(C)log2 (- 1 x) (D)log2 (- 1-x)2 .若p、q为实数,则函数f(x) =x3 px2 qx r( ) .(A)在(-∞, ∞)上是减函数(B)在(-∞, ∞)上是增函数(C)当p2 <3q时,在(-∞, ∞)上是增函数(D)当p2 >3q时,在(-∞, ∞)上是增函数3.已知α、β均为锐角,cos(α β) =- 45 .若设sinβ=x ,cosα=y ,则y与x的函数关系式为( ) .(A)y =- 45 1-x2 35 x (0 相似文献
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一、选择题(每小题6分,共36分)1.定义:A -B ={x|x∈A且x B} .若M ={x|1≤x≤2 0 0 2 ,x∈N } ,N ={y|2 ≤y≤2 0 0 3,y∈N } ,则N -M等于( ) .(A)M (B)N (C) { 1} (D) { 2 0 0 3}2 .函数f(x) =- (cosx)lg |x|的部分图像是( ) .图13.若不等式a b≤m 4a2 b2 对所有正实数a、b都成立,则m的最小值是( ) .(A) 2 (B) 2 (C) 2 3 4 (D) 44 .曲线2x2 -xy -y2 -x - 2y - 1=0和3x2 -4xy y2 - 3x y =0的交点有( )个.(A) 2 (B) 3 (C) 4 (D)无穷多5 .设0 相似文献
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范富成 《中学数学教学参考》1994,(7)
我们知道,高等数学中对三次函数极值是这样来求的: 设f(x)=x~3 px~2 qx r,则f′(x)=3x~2 2px q. 令f′(x)=0. ①当p~2>3q时,解得由成 当x由小到大经过x_1时,f′(x)由正变负,经过x_2时,f′(x)由负变正. ∴y极大=f(x_1),y极小=f(x_2). ②当P~2=3q时,解得x_1=x_2=-p/3,此时f′(x)≥0恒成立,x由小到大经过-p/3时,f′(x)不变号,故-p/3不是极值点。 相似文献
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陈应 《数学大世界(高中辅导)》2004,(12):26-30
一、课本例习题的改编题(一)数字的改编1.理(1)、文(1):已知集合M={x｜x2<4},N={x｜x2-2x-3<0},则集合M∩N=()A.{x｜x<-2}B.{x｜x>3}C.{x｜-1相似文献
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一、选择题1.设集合U={1,2,3,4,5},A={1,2,3},B={2,5},则A∩(CUB)=()(A){2}(B){2,3}(C){3}(D){1,3}2.已知集合M={x｜x=3m+1,m∈Z},N={y｜y=3n+2,n∈Z},若x0∈M,y0∈N,则x0y0与集合M,N的关系是()(A)x0y0∈M但x0y0N(B)x0y0∈N但x0y0M(C)x0y0M且x0y0N(D)x0y0∈M且x0y0∈N3.已知集合A={-1,2},B={x｜mx+1=0},若A∪B=A,则实数m的取值所成的集合是()(A)-1,12(B)-12,1(C)-1,0,12(D)-12,0,14.设P={3,4,5},Q={4,5,6,7},定义PQ={(a,b)｜a∈P,b∈Q},则PQ中元素的个数为()(A)7(B)10(C)12(D)205.设集合P=x｜｜x+12｜<12,Q={m｜x2-4m… 相似文献
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《海外英语》2007,(5):10-11
Many college freshmen arrive woefully unprepared to do college work, and as disadvantaged populations continue to grow, the share of the American work force that has made it through college is expected to plummet. Many experts blame that educational failure not just on high schools but also on colleges. School & College, a special report by The Chronicle, looks at efforts to fix the system. What reforms would better prepare students for college? What should schools and colleges be doing differently? How should state and federal officials help? 相似文献
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罗艳萍 《读与写:教育教学刊》2008,5(6)
The communication of people partially is the communication of cultures. Culture has a direct effect on international commercial activities in all aspects. Different conceptions about time, space, equality, law and the like, lead people to deal with things in different ways. So to know cultures of the counterpart is to facil-itate our enterprises so as to have a smooth and successful communication in commercial activity. 相似文献
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《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love. 相似文献
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Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject. 相似文献
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Sister Carrie is one of the most controversial characters in American literature.Thought as a "fallen woman" firstly,she was defined as a "new woman" by some critics later. However, by digging into the motivaton behind the whole process of Carrie's "success", the relationship between Carrie and her creator (the author), the social conditions of then American, it can be found that Carrie has never been free-standing on her thought and she has never found her real-sdf even after becoming a famous actress. In a society dominated by mass consumerism Carrie is only an adherent of her own desires. She also is a representative of all those country girls flooded into cities, a symbol and a sacrifice of the urbanization of America in a time countryside was overcome by cities. 相似文献
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RUZBEHANI Mohsen 《重庆大学学报(英文版)》2004,3(1):20-25
1.IntroductionOne-cyclecontrolmethod,whichwasproposedaboutonedecadeago[1],hasbecomeanattractivemethodinspecialfieldssuchaspowerfactorcorrection[2-6],switchingamplifiers[7,8],etc.Themainideaofthiscontrollerisbasedonintegrationofdiodevoltageinone-cycleandforcesittobeexactlyequaltothereferencevalue.Themainadvantageofthiscontrollerisitsrealtimeabilitytorejectthevariationofinputvoltage[1].Despitethisgreatability,ithasnogoodperformancesinrejectingofloaddisturbanceandfollowingreferencecommands.Espec… 相似文献
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Richard Denner 《海外英语》2007,(4):14-15
Rosco and I wait for the fishermen to return.I sit at a wooden bench near the store at Mt.Baker Resort and watch the clouds change shape. Rosco has my belt around his neck and an eight foot tow chain hooked to a tree. Dogs must be on a leash. Ducks and rabbits are loose. 相似文献