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1.
The ASTM D6819-02e3 standard for testing the accelerated ageing of paper, published in 2002, recommends using closed glass vials in order to keep the degradation products in contact with the paper and thus permitting a better simulation of the natural ageing conditions inside closed books. In the present study, the actual conditions and their stability inside closed vessels have been evaluated. The necessity of assuring a very high sealing performance (tightness) of the systems in order to avoid leakage of water vapour is the main drawback of this ageing method. Systematic studies presented in this publication tried to monitor this tightness and have provided data that helped to answer the question of what circumstances could lead to achieving its improvement. Both gravimetric monitoring of water content in vials and “in situ” IR measurements of the aged paper humidity have been applied for this purpose. As a result, better sealing materials (gaskets and caps) than those recommended by the ASTM standard, have been found. Additionally, application of a dynamometric spanner for closing the vials is recommended, as this is a guarantee of reasonably high and recurring tightness of the systems used in tests. Nevertheless, the systematic, linear with time, loss of moisture for all used vials was observed. A 9% loss of the initial moisture content in samples of the aged paper was observed for the tested conditions (14 days at 90 °C). Therefore, it seems that including some kind of gravimetric control for ageing tests performed in closed vessels is of essential importance.Kinetic studies of accelerated ageing in both closed and open systems, as monitored by DP and breaking length measurements, unexpectedly show that no statistically meaningful difference of degradation rates can be observed. On the other hand, the pH and whiteness index values reveal a meaningful difference between the rates of ageing in these systems, thus confirming the basic assumption of the ASTM test concerning the interaction of paper degradation products with the paper itself.  相似文献   

2.
3D reconstructions of small objects are more and more frequently employed in several disciplines such as medicine, archaeology, restoration of cultural heritage, forensics, etc. The capability of performing accurate analyses directly on a three-dimensional surface allows for a significant improvement in the accuracy of the measurements, which are otherwise performed on 2D images acquired through a microscope. In this work we present a new methodology for the 3D reconstruction of small sized objects based on a multi-view passive stereo technique applied on a sequence of macro images. The resolving power of macro lenses makes them ideal for photogrammetric applications, but the very small depth of field is their biggest limit. Our approach solves this issue by using an image fusion algorithm to extend the depth of field of the images used in the photogrammetric process. The paper aims to overcome the problems related to the use of macro lenses in photogrammetry, showing how it is possible to retrieve the camera calibration parameters of the sharp images by using an open source Structure from Motion software. Our approach has been tested on two case studies, on objects with a bounding box diagonal ranging from 13.5 mm to 41 mm. The accuracy analysis, performed on certified gauge blocks, demonstrates that the experimental setup returns a 3D model with an accuracy that can reach the 0.05% of the bounding box diagonal.  相似文献   

3.
At the instigation of the Musée du Louvre's Department of Egyptian Antiquities, an intensive programme to study black bronze has been carried out at the Centre de Recherche et de Restauration des Musées de France. Systematic research has been undertaken on the museum's collection to identify objects that might have an intentional black patina.The same experimental protocol has been applied to all the objects, alllowing this study to be one of the most important coherent investigation on this type of bronze decoration. It involves the use of non-invasive analytical methods in order to obtain the maximum amount of information possible about the chemical nature and structure of the surface layer. The protocol makes it possible to compare objects and to propose an interpretation of how this decorative technique evolved during the Egyptian period.Based on previous stylistic investigations (by J. Cooney, 1966) and personal observation, sixteen objects dating from the Middle Kingdom to the Late Period were selected. Thanks to elemental analyses, twelve of them were identified as being intentionally patinated. Only ten of these could be described as hmty-km, because the base patinated alloy contains small amounts of gold and/or silver and the black patina is made up mainly of cuprous oxide Cu2O (cuprite). Among the four other objects, one patina is very close to the black bronze patina, but contains neither gold nor silver. Three other pieces have an unusual patina. A lack of other comparable examples makes it very difficult to determine whether the patinas are of ancient origin.  相似文献   

4.
Pollutants and their potential degradation of paintings have been measured for the first time in microclimate frames (mc-frames), which are used to protect paintings. The pollutants that were measured include both inorganic pollutants, which originate mainly from external sources, and organic pollutants from mainly internal sources. Those originating from the outdoors enter rooms and subsequently mc-frames at a rate depending on the ventilation rates (air exchange rates) of the mc-frames. The concentration of gaseous pollutants emitted within the mc-frames will depend on net emission rates of the materials used to make the mc-frames, their design, and their ventilation rates. In the EU PROPAINT project measurements of gaseous air pollutants and climatic conditions were performed at various locations both inside and outside different state-of-the-art mc-frames. Diffusive passive pollution gas samplers were used together with different types of dosimeters. Results show that the dosimeters respond to either the photo-oxidizing conditions or the level of volatile organic acids in the environments both in the museums and within the mc-frames. Two dosimeters, the Early Warning Organic (EWO) made from a synthetic polymer and the Resin Mastic coated Piezo electric Quartz Crystals (RM-PQC) respond to photo-oxidation and showed higher values outside than inside the mc-frames. Two other dosimeters, the Glass Slide Dosimeter (GSD) and the Lead coated Piezo electric Quartz Crystals (L-PQC) respond to volatile organic acids and yielded higher values inside than outside the mc-frames. This study emphasizes the need for further work to determine environmental damage functions for paintings, in particular for the effects of organic acids. Such information is essential for the evaluation of the protective effects of mc-frames for paintings. The use of mc-frames is increasing and it is very important to know that this protective measure does not introduce new risks.  相似文献   

5.
The Minerva of Arezzo is an ancient bronze statue located at the Museo Archeologico in Florence and currently under repair at the Restoration Centre of the Soprintendenza Archeologica of the Tuscany Region. We assembled a complete three-dimensional (3D) digital model of the Minerva before the restoration started. More 3D models will be produced to keep track of the variations that occurred during the restoration process, up to the final acquisition of the form of the restored artwork. The modelling of the Minerva will be the focal point of an ambitious “Minerva Project” that involves the integration of data from other sources in a 3D digital model of the object. Besides this, the project is aimed at showing how 3D techniques can be used to design useful and easily manageable new tools for the diagnostics of archaeological objects. 3D measurements have been realized by means of a high-resolution laser scanner developed at National Institute for Applied Optics (INOA). The instrument is composed of commercial low-cost components in order to be competitive with the very expensive commercial devices. Besides this, our scanner is supported by an efficient and flexible software developed by Consiglio Nazionale delle Ricerche (CNR) that supports all the post-processing phases of a 3D scanning session (range data alignment, merge and simplification).  相似文献   

6.
张益 《文化交流》2014,(2):61-64
近日,在浙南颇有名望的民办瑞安叶茂钱收藏馆在整理旧藏时,发现了井冈山革命时期的三大包红色文物,为中共党史、工农红军军事史及苏维埃历史研究提供了非常重要的实物资料。  相似文献   

7.
This paper describes the ground-penetrating radar (GPR) survey carried out on the Roman theatre of Sagunto (Valencia, Spain) following recent restoration work in 1991. The structure has been substantially altered a number of times: it was remodelled during the Roman and Moorish periods, partially destroyed during the Peninsular War (1808–1814) and the Carlist War (1833–1839), and extensively modified during the 1930s and 1950s. Major reconstruction work was carried out in 1991 to convert the building into a working theatre. The GPR survey was performed to detect the possible effects of the 1991 remodelling on the historical remains and to identify the point of contact between the present-day modifications and the Roman remains. We took several on-site measurements of the wave velocity in the different materials in known areas to determine as accurately as possible the depth of the contact point. The velocity was calculated by measuring the depth in these areas and the two-way travel time of the wave. The measurements were taken from the walls and the tiers as the thicknesses of the materials were known in these areas. The recorded values were compared with the velocities reported by other authors and with the information from diffraction hyperbolas recorded in the radar data, which are caused by small objects inserted in the medium. We used these velocities to determine the exact point of contact between the Roman remains and the materials used in later restorations. The contact points cause the reflections that can be seen in the GPR data. The results also reveal considerable variations in the surface of the Roman tiers, which can be attributed to partial erosion in these areas caused mainly by water.  相似文献   

8.
This paper deals with the relations between the sociality of cultural economies and the cultural objects traded in them. It argues that the study of cultural economies must work up new methodologies that can account for both. The paper suggests the concept of the ‘mediator’ as a way of highlighting how cultural objects and sociality are co-constituted. The ‘mediator’ is formulated as a methodological tool for by-passing the academic divide between cultural-aesthetic objects and their social contexts.  相似文献   

9.
Since 2004 an international research group of Wood Technologists has been given by the Louvre Museum the task of analysing the hygro-mechanical state of the Poplar (Populus alba L.) panel on which Leonardo da Vinci painted his “Mona Lisa”, namely verifying the appropriateness of the thermo-hygrometric conditions in its exhibiting showcase, where the microclimate is actively controlled, and assessing the potential consequences of any hypothetical fluctuation. In order to acquire data about the mechanical behaviour of the panel, and to feed and calibrate appropriate simulation models, the team has not only set up a continuous monitoring by means of automatic equipment, but has also performed manual measurements on the occasion of the annual openings of the showcase where the masterpiece is conserved and exhibited. This paper reports about techniques used for estimating the forces acting between the wooden panel and its frame (the châssis-cadre), and their location, such data being of primary importance for evaluating the panel's internal stresses. The contact forces have been calculated on the basis of the local contact pressures, imprinted on a pressure-sensitive foil as a range of saturation values of the colour developed in the contact areas. The forces calculated as above have also been compared with the contact forces between the panel's back face and the crossbeams pressing it against the châssis-cadre, which have been measured by means of a load cell. As could be expected, the results from so different techniques do not strictly coincide; however the agreement is fairly good.  相似文献   

10.
An investigation has been undertaken at St Andrew’s church, Walpole St Andrew, Norfolk, to establish the underlying causes of the observed stone decay to the upper parts of the six stone piers. The stone decay was first recorded in the early 1930s. The salt-contaminated masonry within the church has been shown to undergo severe salt decay during the summer, with little damage occurring over the winter months. The south aisle piers have been shown to decay 2.5 times faster than the north aisle piers. Although crystallization–hydration cycles have been identified, the rate of decay is at its greatest when the cycling is relatively infrequent. This was not the expected trend. Furthermore, it has been shown that during extended periods where the ambient relative humidity is less than 75%, the rate of decay reaches a maximum. It is the length of this ‘drying’ period that apparently has the greatest influence on the rate of decay and could explain the significant difference in the rate of decay between the south and north aisle piers. The results have serious implications for passive conservation, where it is often recommended to lower the ambient relative humidity to well below the equilibrium relative humidity of the salt contaminant, to avoid crystallization–hydration cycles. Since, at the time of building, the church was situated on the coast, it is possible that the sodium chloride contamination occurred during the building process (1440–1520), particularly since the area was prone to sea-flooding at this time. Alternatively, the salt could have been applied as a treatment during the general restoration of 1897. Whatever the source of the salt, it seems likely that the ambient environment was changed by the insertion of a sealed floor in 1897, which could account for the onset of the salt decay.  相似文献   

11.
We survey more than twenty studies estimating rates of return of investments in single art objects and whole collections and evaluate the various approaches to art price movements taken so far. The majority of the estimates find lower returns for investments in art objects than for investments in financial assets. However, most existing analyses are restricted to auction data and neglect transactions cost and taxation. They partly focus on mechanistic calculations and disregard the distinguishing institutional and behavioral characteristics of art markets. We look into the possibilities to capture and empirically estimate psychic returns from owning art.  相似文献   

12.
A number of software solutions based on the Structure-From-Motion (SFM) and Dense Multi-View 3D Reconstruction (DMVR) algorithms have been made recently available. They allow the production of high quality 3D models by using unordered image collections that depict a scene or an object from different viewpoints. In this work, we question the quality of the data produced by a commercial SFM-DMVR software. An Ottoman monument located in the region of Xanthi, Greece has been selected as a case study. We attempted to quantify the quality of the SFM-DMVR data in relation to the data produced by a Time-of-Flight terrestrial 3D range scanner. We have implemented a number of comparisons between different parts of the monument in order to assess the mesh deviations and the reconstruction's accuracy. In order to further ensure the validity of our evaluation phase, we performed additional distance measurements between feature points on the monument's surface by using a total station and empirical measurements. The applicability of the SFM-DMVR method was questioned by creating a complete 3D digital replica of the monument.  相似文献   

13.
A substantial recent literature has examined insurance as a mechanism for economizing uncertain but potentially catastrophic events. Less attention has been paid to how insurantial techniques for economizing catastrophe have been deployed as political technologies. Focusing on discussions of US flood policy in the 1960s, the present article examines how insurance was used to forge new articulations and accommodations between political government and processes of rationalization. On the one hand, insurance provided a technical solution to problems that had long confronted US policy-makers: How to reduce losses from floods? How to fully compensate individuals who suffered losses? On the other hand, insurance was a device for reshaping the aims and objects of government, and for reframing questions that are more frequently situated at the level of political philosophy: What are the respective responsibilities of individual citizens and government in providing security? What tradeoffs must be made between the provision of security and economic rationality? What values are relevant in orienting public policy? In examining these issues, the article raises questions about standard narratives about the changing relations among risk, responsibility, and security in recent decades, particularly as they relate to neoliberalism.  相似文献   

14.
In this paper, the threat posed to cultural heritage by landslides and avalanches is analysed for two communities (Ushguli and Mulakhi) in the Upper Svaneti region in Georgia. The vulnerability of 60 cultural heritage objects has been evaluated through a conservation calculation based on an existing methodology using a State of Conservation Index (SCIx), which served as an input in a Spatial Multicriteria Evaluation (SMCE). Factors that are considered important for the occurrence of landslides (slope, landcover, lithology and drainage density) and snow avalanches (slope, insolation, slope curvature and landcover) have been used to generate a susceptibility map. A qualitative risk assessment was carried out by combining susceptible areas and cultural heritage objects. As there were very limited historical data available on the occurrence of landslides and snow avalanches, a combination of local and expert knowledge has been used to extract information on both cultural heritage and natural hazards. Existing management plans were also analysed to evaluate how natural hazards could be incorporated. Finally, some recommendations are given related to the analysis of the impact of natural hazards on cultural heritage in Georgia.  相似文献   

15.
Papermaking has a special place in the cultural heritage of China. Papers made from different types of plant fibers were, and are still used for particular applications. Bamboo paper is a handmade paper that has been traditionally used for book printing and restoration of ancient paper objects since antiquity in China, whereas Xuan paper, the subject of recent previous study, is used for traditional Chinese calligraphy and painting. Following our previous approach on Xuan paper, four modern Bamboo papers manufactured using traditional or chemically-facilitated techniques were artificially aged by UVA radiation and changes to their optical properties were evaluated by reflectance and 3D-fluorescence spectroscopies. Paper samples produced by different methods displayed different fluorescence spectra and UVA photolysis of paper resulted in decreases in the fluorescence intensities and reflectance values, manifested as differing photoyellowing of the papers. Assays of reactive oxygen species, ROS, revealed that papers made by chemically-assisted pulping methods generally produce more hydrogen peroxide or superoxide radicals than those made by traditional methods, which correlates with their relative yellowing rates. Different spatial distributions of calcium and chlorine were also observed by SEM/EDS analysis in the chemically-manufactured papers, probably arising from the specific pulping and/or bleaching chemicals used in their manufacture.  相似文献   

16.
In the cultural heritage area, it is of fundamental importance to characterize and classify the conservation state of the materials constituting ancient monuments, in order to study and monitor their decay. Generally, the decay diagnosis is provided by “naked eye” analysis done by expert scientists “walking around” the artifact and recording the conservation state of each individual element they observe. In this paper, a color image segmentation approach, based on histogram threshold and edge detection techniques is presented, to extract degradation regions, characterized by holes or cavities, from color images of stone-materials. The goal is to provide an aid to the decay diagnosis by segmenting degraded regions from color images, computing quantitative data, such as the area and perimeter of the extracted zones, and processing qualitative information, such as various levels of depth detected into the same zones. Since color is a powerful tool in the distinction between objects, a segmentation technique based on color, instead of intensity only, has been used to provide a clearer discrimination between regions. The study case concerns the impressive remains of the Roman Theatre in the city of Aosta (Italy). In particular, we have processed and analyzed some color images of the theatre puddingstones, acquired by a camera.  相似文献   

17.
The possibility to use laser radiation to clean historical objects has been established for several years. A complex case and widely met problem are polychromes. They react (chemically as also physically) very sensitively towards laser radiation. In this study, the reaction of pigments was investigated in dependency on the incident wavelength (Nd:YAG, λ = 1064, 532, 355, 266 nm) and energy density. The chemical and also the physical interactions were investigated. In this work, the following analytical methods were utilised: differential thermal analysis (DTA), colour measurements (CIE-L*a*b*), X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDX). It turned out that the colour change of the pigments can have different origins: they can for instance be induced by laser induced oxidation, reduction or phase changing. Most of the pigments show reactions at very low energy densities (H < 100 mJ cm–2). Overall the fundamental wavelength of the Nd:YAG-laser (λ = 1064 nm) proved to be most suitable, whereas λ = 355 nm shows most influence on the colour change.  相似文献   

18.
In recent years the control and monitoring of works of art has gained more and more importance. In particular, works partially or totally realized with wood, such as polychrome sculptures, painted panels or Crucifixes, are highly sensitive and delicate and thus need a particular attention. The wooden support is, in fact, an essential element for the stability of pictorial layers: the color lies on a preparation, which in turn, is anchored to the wood. Wrong conservation methods, i.e. in an environmental climate that is not controlled, or intrinsic mechanical stresses, can warp such structures, and the effects can be irreversible and destructive to the painted layer. The use of fiber Bragg grating (FBG) sensors for the quasi-distributed, in situ measurement and continuous monitoring of deformations in painted wood panel is proposed. In order to demonstrate the applicability of FBG sensors to painted wood panels, a wooden support, made using the same 15th–16th century techniques, was prepared in the Opificio laboratories. A number of Bragg grating sensors were affixed in several critical points, on the back and front sides and on the strengthening cross-beams, in order to detect deformations in the panel dependent on the variations in the environmental relative humidity (RH). Measurements during the removal of the cross-beams are also reported. The results of measurements have shown the applicability of FBG sensors for the continuous in situ monitoring of valuable wooden objects and works of art.  相似文献   

19.
Recent research, concerning the application of high-frequency cold plasma in restoration and preservation of the cultural heritage, has included the objects derived from organic materials, which are highly sensitive to microclimate factors. Historical photographs made on paper base and covered with various emulsions belong to this category of heritage objects, and make the purpose of the present study. Plasma treatment was used to enhance the aesthetic aspect of the photographs by a cleaning treatment involving either physical and/or chemical etching, which did not cause major physicochemical changes on the plasma-treated surface. The photographs before and after plasma treatments were analysed by optical and atomic force microscopy, scanning electron microscopy with energy-dispersive X-ray microanalysis, Fourier transform infrared spectroscopy, colour, gloss and contact angle measurements.  相似文献   

20.
This paper presents a detailed analysis of the measured data on the indoor air of an historical building: tezone 105 of the Arsenale in Venice. During one year of measurements, the indoor air temperature and the air humidity have been collected: the probes have been placed in different sites in order to provide total control of the microclimate. The status of the internal walls has been checked by means of the measurement of the surface temperatures by different sets of thermal resistances. The data collected point out the water wall imbibition and the high thermal capacity of the building envelope.The collected information could be used for the design of the thermal system.  相似文献   

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