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1.
采用1,4—丁二醇水溶液的高沸醇溶剂法,从松木、杉木、稻草等原料制备纤维素与木质素。使用上述材料,在70%—90%1,4—丁二醇水溶液中添加少量催化荆、并在190℃-220℃条件下蒸煮1—3小时的方法制得纤维素和木质素。高沸醇法制得的纤维素可用于造纸,纤维素的聚合度在一定范围内可以调节。不溶于水的高沸醇(HBS)木质素则可以通过加水沉淀的方法,从反应后的液体混合物中分离。HBs木质素具有较高的反应活性,通过进一步改性,还有更多潜在的应用价值。回收的高沸醇溶剂,可作为制浆溶剂循环使用。高沸醇溶剂法是一种适用于从木材、草木秸秆类原料剞备纤维素与木质素,且具有节能、环保等众多优点的好方法。  相似文献   

2.
采用1,4—丁二醇水溶液为溶剂的高沸醇溶剂法,从稻草中制备纤维素与木质素。在1,4—丁二醇水溶液中添加少量助剂、并在190℃—220℃条件下蒸煮1—3小时的方法制得纸浆和木质素。制得的纸浆可用于造纸。不溶于水的高沸醇(HBS)木质素则可以通过加水沉淀的方法,从反应后的液体混合物中分离。HBS木质素具有较高的反应活性,通过进一步改性,还有更多潜在的应用价值。回收的高沸醇溶剂,可作为制浆溶剂循环使用。  相似文献   

3.
高沸醇木质素甲氧基含量测定   总被引:5,自引:0,他引:5  
不同方法制备得到的木质素产品,元素组成及官能团含量是不同的。高沸醇溶剂法制备得到的高沸醇(HBS)木质素与传统木质素相比,其理化性质有很大不同,元素及官能团也有很大差别。甲氧基是其中的一个重要体现。从测定HBS木质素的甲氧基含量可知,其值较磨木木质素小,但高于木质素磺酸钙。说明与传统木质素相比,HBS木质素的官能团保持较好。  相似文献   

4.
利用木质素灰分测定的方法,对高沸溶剂(HBS)法提取的木质素灰分与吉林独山子公司提供的木质素磺酸盐进行测定,结果表明本方法制备HBS木质素质量更好.  相似文献   

5.
利用木质素灰分测定的方法,对高沸溶剂(HBS)法提取的木质素灰分与吉林独山子公司提供的木质素磺酸盐进行测定,结果表明本方法制备HBS木质素质量更好。  相似文献   

6.
HBS木质素的制备方法及其性质   总被引:1,自引:0,他引:1  
1 .前言 :木质素是一种无定形带芳香的网状聚合物 ,在自然界中的含量仅次于纤维素。在自然界中含有木质素大约 3× 1 0 1 1 吨 ,而每年生成的木质素约 2× 1 0 1 0 吨。[1 ] 木质素结构相当复杂 ,在木材中木质素、纤维素和半纤维素相互渗透 ,形成交互贯通的网状结构 ,用普通的方法难以把木质素从这个网络中分离出来。近年来 ,许多研究者正致力于造纸厂黑液中木质素的分离和应用。高沸醇溶剂 (HBS)法是纸浆制备的新工艺 ,具有无污染、节能等特点。[2 ] 本文介绍了用高沸醇溶剂法从松木和杉木中获得木质素的制备方法及其产品性质。2 .结果…  相似文献   

7.
利用高沸醇木质素和甘油合成松香改性树脂,测定改性树脂的软化点、酸值、DSC-TGA曲线,并与原料松香进行比较.实验结果表明高沸醇木质素可以替代部分甘油改性松香树脂,松香的软化点、酸值、粘度以及耐热稳定性通过高沸醇木质素的改性得到改善.结果还表明用高沸醇木质素制备松香改性树脂比木质素磺酸钙改性效果更好.  相似文献   

8.
传统的造纸方法主要是亚硫酸盐或碱煮法制浆,用高沸醇溶剂制浆在国内外还没有产业化,研究论也很少。为了能够满足高沸醇溶剂法制浆中试要求,必须进行有关热量计算。本通过丁二醇的比热估算,利用实验室相关数据,算出反应需热量,求得换热器面积。为中试提供了有关参数。  相似文献   

9.
以苯酚为液化试剂,对高沸醇木质素分别在加热和热酸催化条件下进行酚化,制备得到100%液化效率和很好流动性的高沸醇木质素液化产物。采用红外光谱、核磁共振和热重分析方法对液化前后木质素进行了分析测试,结果表明液化后的高沸醇木质素羟值和反应活性显著提高;木质素分子在酚化条件下发生降解并通过酚化产生了新的具有不同取代基的苯环结构。  相似文献   

10.
本文对顺酐加氢制1,4-丁二醇反应提出了在一根色谱柱上对原料及产物进行全分析的气相色谱分析方法。该法设备简单,操作简便,快速可靠,用于科研和生产均取得满意结果。  相似文献   

11.
《海外英语》2007,(5):44-45
It is worthy of noting that, whilst Crookston Castle witnessed the earlier and happier portion of Mary's variegated life,  相似文献   

12.
《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love.  相似文献   

13.
王菲 《华章》2007,(12):273-273
Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject.  相似文献   

14.
裴水妹 《华章》2007,(11):196
Sister Carrie is one of the most controversial characters in American literature.Thought as a "fallen woman" firstly,she was defined as a "new woman" by some critics later. However, by digging into the motivaton behind the whole process of Carrie's "success", the relationship between Carrie and her creator (the author), the social conditions of then American, it can be found that Carrie has never been free-standing on her thought and she has never found her real-sdf even after becoming a famous actress. In a society dominated by mass consumerism Carrie is only an adherent of her own desires. She also is a representative of all those country girls flooded into cities, a symbol and a sacrifice of the urbanization of America in a time countryside was overcome by cities.  相似文献   

15.
16.
1.IntroductionOne-cyclecontrolmethod,whichwasproposedaboutonedecadeago[1],hasbecomeanattractivemethodinspecialfieldssuchaspowerfactorcorrection[2-6],switchingamplifiers[7,8],etc.Themainideaofthiscontrollerisbasedonintegrationofdiodevoltageinone-cycleandforcesittobeexactlyequaltothereferencevalue.Themainadvantageofthiscontrollerisitsrealtimeabilitytorejectthevariationofinputvoltage[1].Despitethisgreatability,ithasnogoodperformancesinrejectingofloaddisturbanceandfollowingreferencecommands.Espec…  相似文献   

17.
Today, Sunday morning, I sit thinking and typing at my computer. My thoughts are in my homeland, India and my body is in China. The body is here and mind there for a good reason. Mr. Hu is president and I am resident and both are in each other's countries (what a difference the absence of one small letter makes!). Mr. Hu will return in a few days and I will stay on longer.  相似文献   

18.
STORIES     
正A One day a pig went to the stable(马棚)to see his good friend,an oldhorse,and was going to stay there forthenight.Night came and it was time forsleep.The pig went into the straw heap(稻草堆)and lay comfortably.A longtime passed,but the horse was stillstanding there and did not move.Thepig asked the horse why he did not go tosleep."Standing like this is the begin-ning ofsleeping,"answered the horse.  相似文献   

19.
正1.Any fool can count the seeds in an apple.Only God can count all the apples in one seed.2.Happy families are all alike;every unhappy family is unhappy in its own way.3.Memories are the key not to the past,but to the future.4.Sometimes in the dark you see what you want to see.5.There is a great difference between  相似文献   

20.
正Scope and Policy The Journal of Chongqing University-English Edition(JCQU-E)is a peerreviewed journal publishing research articles in multiple disciplines of science and technology,covering civil and environmental engineering,chemical engineering,biotechnology,mechanical and electrical engineering,computer and data processing,mining,metallurgy,materials science,and interdisciplines thereof.  相似文献   

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