共查询到20条相似文献，搜索用时 15 毫秒
1.
Thermodynamic systems with variable mass, like liquid/vapor equilibria and chemical reactions, are represented as networks having discrete elements and connections using bond graph symbols. The mass bond has special properties which are explained by entropy and volume stripping and indicate the reason why the derivative of the free enthalpy, not the internal energy, is the driving effort of chemical reactions. Chemical friction is represented by RS-fields that dissipate power which is different from the observed heat rate of chemical reactions. Different reticulations apply to reactions near and far from chemical equilibrium; their relation to experimental reaction kinetics and order of reaction is discussed. 相似文献
2.
The present investigation is concerned with the effects of thermal-diffusion and diffusion-thermo on an unsteady MHD free convection boundary layer flow with heat and mass transfer of an electrically conducting fluid over a stretching sheet in the presence of strong magnetic field with Hall current, thermal stratification, chemical reaction, heat generation, thermal radiation, Joule heating and viscous dissipation. The transformed nonlinear boundary layer equations are numerically solved by applying Keller-box method. The influence of various embedded flow parameters on the local skin friction, the local Nusselt number and the local Sherwood number has been carefully analyzed through graphs. It is found that the shear stress and the rate of mass transfer increase with an increasing of current density Jh while the reverse trend is observed on the rate of heat transfer. It is also found that the shear stress and the rate of heat transfer increase with an increasing of Sr , whereas the reverse trend is observed on the rate of mass transfer. Further, the shear stress and the rate of mass transfer increase with an increasing of Du while the reverse trend is seen on the rate of heat transfer. The numerical results are compared and found to be in good agreement with previously published results under special cases. 相似文献
3.
《Electronic Journal of Biotechnology》2014,17(6):329-333
BackgroundThe roots of chicory and the tubers of Jerusalem artichoke are used for the production of inulin. However, a quality of tubers and roots, i.e. the content of inulin, monosaccarides and disaccharides, depends on the activity of enzymes implicated in the metabolism of inulin. The knowledge on the changes of activities of inulin synthesizing and degrading enzymes is limited during plant sprouting, growth and dormancy. It happens due to complicated measurements of the product of enzymatic reaction in the presence of crude plant extract. Fructan exohydrolase (β-d-fructan fructohydrolase, FEH, EC 3.2.1.80) is an enzyme responsible for the hydrolysis of fructans in plants. For fructose as the reaction product measurement, a high-performance liquid chromatography is usually used. The aim of the study was to choose a simple and suitable method for FEH activity determination and the measurement of fructose in the presence of plant extracts.ResultsTwo chemical methods, i.e. copper(II)–neocuproine and 3,5-dinitrosalicylic acid, and the enzymatic one based on the reactions catalyzed by hexokinase, phosphoglucose isomerase and glucose-6-phosphate dehydrogenase were used. Enzymatic method was found to be suitable for FEH activity determination in plant extracts, and on the contrary to chemical methods no interference effects of compounds from crude plant extracts were observed.ConclusionEnzymatic method is applicable for the routine analysis and will allow performing the investigations without special equipment on the inulin degrading enzyme in biotechnologically important crops. 相似文献
4.
《Journal of The Franklin Institute》2019,356(18):11638-11667
This paper proposes a new image encryption method based on matrix semi-tensor product theory. Using Hyperchaotic Lorenz system to generate chaotic sequences, and then using this chaotic sequence to generate two fixed scrambling matrices. The plain image is scrambled by chaotic positioning sort scrambled method. Analogous to a chemical reaction, the plain image scrambled image is one of the reactant, then add a matrix which is related to the plain image information and extracted from the chaotic sequence (this matrix can be differ in size from the plain image matrix, different matrices can be intercepted and generated according to different plain image). This matrix is scrambled as another reactant, Apply the method of semi-tensor product to carry on the reaction (diffusion), finally get the product (encryption image). This method breaks the shackles of the traditional matrix operation and makes the reaction matrix have more forms. Compared with other experimental results, the proposed algorithm is more secure and available. 相似文献
5.
Models for chemical reaction kinetics typically assume well-mixed conditions, in which chemical compositions change in time but are uniform in space. In contrast, many biological and microfluidic systems of interest involve non-uniform flows where gradients in flow velocity dynamically alter the effective reaction volume. Here, we present a theoretical framework for characterizing multi-step reactions that occur when an enzyme or enzymatic substrate is released from a flat solid surface into a linear shear flow. Similarity solutions are developed for situations where the reactions are sufficiently slow compared to a convective time scale, allowing a regular perturbation approach to be employed. For the specific case of Michaelis-Menten reactions, we establish that the transversally averaged concentration of product scales with the distance x downstream as x(5/3). We generalize the analysis to n-step reactions, and we discuss the implications for designing new microfluidic kinetic assays to probe the effect of flow on biochemical processes. 相似文献
6.
Mayo Dyer Hersey 《Journal of The Franklin Institute》1935,220(3):305-331
The modern understanding of lubrication is based on the equations of the hydrodynamic theory. These equations, as has been seen, describe the performance of a bearing in terms of the actual film viscosity but, of course, this depends on the temperature of the film, which in general is unknown. We have next to consider whether there is any way of calculating or predicting the steady running temperature of a bearing.It is not commonly realized that there is a rational solution for this problem.The solution depends both on the rate of generating heat by friction, and on the rate of heat transfer from the bearing to its surroundings. 相似文献
7.
The present study concentrates to make a complete thermal analysis on a rectangular fin with its primary surface by taking into consideration of radiation heat exchange with the surrounding along with the convective mode of heat transfer. The one side of the primary surface is heated by a fluid with high temperature which may be required to dissipate heat quickly by a fin array system. To analyze an actual case study, the thermal conductivity of the fin material and convective heat transfer coefficient over the surface are treated as a variable and they are as a function of the local fin surface temperature. With the aforementioned condition, the energy equations for both the fin and primary surface become nonlinear. The decomposition method is suggested to solve these highly nonlinear equations to obtain a closed form temperature distribution. The result of temperature distribution determined by the present analysis is compared with that of the numerical values. With the adaptation of the simplified case, the present method is also compared with the exactly closed form results. From both of these comparisons, an exact matching of results is found. The fin performances, namely, fin efficiency, surface efficiency and augmentation factor are evaluated for a wide range of thermogeometric parameters. 相似文献
8.
A microfabricated calorimeter (μ-calorimeter) with an enclosed reaction chamber is presented. The 3D micromachined reaction chamber is capable of analyzing liquid samples with volume of 200 nl. The thin film low-stress silicon nitride membrane is used to reduce thermal mass of the calorimeter and increase the sensitivity of system. The μ-calorimeter has been designed to perform DC and AC calorimetry, thermal wave analysis, and differential scanning calorimetry. The μ-calorimeter fabricated with an integrated heater and a temperature sensor on opposite sides of the reaction chamber allows to perform thermal diffusivity and specific heat measurements on liquid samples with same device. Measurement results for diffusivity and heat capacitance using time delay method and thermal wave analysis are presented. 相似文献
9.
原油主要化学成分对原油平均分子量的影响 总被引：1，自引：0，他引：1
原油平均分子量是原油一项重要的综合评价指标,它反映原油多方面理化性质。原油平均分子量取决于原油化学成分。这里用采用大量分析数据,用散点法初步研究了原油各类化学成分对原油平均分子量的影响,发现各成分的影响情况各有特点。对于深入研究原油理化性质及原油评价具有重要意义。 相似文献
10.
Controlled electroporation of the plasma membrane in microfluidic devices for single cell analysis 总被引：1，自引：0，他引：1
Chemical cytometry on a single cell level is of interest to various biological fields ranging from cancer to stem cell research. The impact chemical cytometry can exert in these fields depends on the dimensionality of the retrievable analytes content. To this point, the number of different analytes identifiable and additionally their subcellular localization is of interest. To address this, we present an electroporation based approach for selective lysis of only the plasma membrane, which permits analysis of the dissolved cytoplasm, while reducing contributions from the nucleus and membrane bound fractions of the cell analytes. The use of 100 μs long pulse and a well defined DC electric field gradient of ∼4.5 kV·cm−1 generated by 3D electrodes initiates release of a cytoplasm marker in ≪1 s, while retaining nuclear fluorescence markers. 相似文献
11.
Droplet microfluidics is a powerful method used to characterize chemical reactions at high throughput. Often detection is performed via in-line optical readout, which puts high demands on the detection system or makes detection of low concentration substrates challenging. Here, we have developed a droplet acoustofluidic chip for time-controlled reactions that can be combined with off-line optical readout. The principle of the platform is demonstrated by the enzymatic conversion of fluorescein diphosphate to fluorescein by alkaline phosphatase. The novelty of this work is that the time of the enzymatic reaction is controlled by physically removing the enzymes from the droplets instead of using chemical inhibitors. This is advantageous as inhibitors could potentially interact with the readout. Droplets containing substrate were generated on the chip, and enzyme-coupled microbeads were added into the droplets via pico-injection. The reaction starts as soon as the enzyme/bead complexes are added, and the reaction is stopped when the microbeads are removed from the droplets at a channel bifurcation. The encapsulated microbeads were focused in the droplets by acoustophoresis during the split, leaving the product in the side daughter droplet to be collected for the analysis (without beads). The time of the reaction was controlled by using different outlets, positioned at different lengths from the pico-injector. The enzymatic conversion could be measured with fluorescence readout in a separate PDMS based assay chip. We show the ability to perform time-controlled enzymatic assays in droplet microfluidics coupled to an off-line optical readout, without the need of enzyme inhibitors. 相似文献
12.
In this article, the authors present the fabrication of an enzyme-entrapped alginate hollow fiber using a microfluidic device. Further use of enzyme-entrapped alginate hollow fibers as a biocatalytic microchemical reactor for chemical synthesis is also deliberated in this article. To ensure that there is no enzyme leaching from the fiber, fiber surfaces were coated with chitosan. To confine the mobility of reactants and products within the porous hollow fibers the entire fibers were embedded into a transparent polydimethylsiloxane (PDMS) matrix which also works as a support matrix. A vanadium-containing bromoperoxidase enzyme isolated from Corallina confusa was used as a model enzyme to demonstrate the use of these alginate hollow-fiber reactors in bromo-oxidation of phenol red to bromophenol blue at different dye flow rates. Stability of the entrapped enzyme at different temperatures and the effect of the chitosan coating on the reaction conversion were also studied. It was observed that molecules as big as 27 kDa can be retained in the matrix after coating with chitosan while molecules with molecular-weight of around 378 Da can still diffuse in and out of the matrix. The kinetic conversion rate in this microfluidic bioreactor was more than 41-fold faster when compared with the standard test-tube procedure. 相似文献
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14.
A control-oriented dynamic model of proton exchange membrane fuel cells (PEMFCs) has been developed in this paper. It aims to generate system dynamics with real-time performance for the micro-chip controller design. A unified bond graph approach was employed that integrates physical and chemical domains in the fuel cell operation, including fluid dynamics, heat transfer, and electrochemistry effects. In this paper, two major bond graphs, one for thermofluids, the other for the electrochemical system, were constructed. They are inter-connected to interpret the highly nonlinear transport and reaction system dynamics. The nonlinear simulation on a personal computer (PC) is about four times faster than the realistic operation. A step response test shows that the start-up time of an example PEMFC is about 5 s from ambient conditions. Further frequency-response test in the operation region shows that the bandwidth is near 2 rad/s. 相似文献
15.
In this paper, we present a new method for solving unsteady heat conduction problems, which is based on a time–space boundary residual method with heat polynomials. More specifically, it employs an integral least squares criterion for the initial and boundary residuals so as to determine the unknown coefficients in a trial expansion of heat polynomials. Though it treats only one-dimensional cases, the present approach shows a good applicability for such heat conduction problems. 相似文献
16.
Robert Fugmann Günter Kusemann Jakob Hermann Winter 《Information processing & management》1979,15(6):303-323
The possibilities and limitations of chemical reaction names as the basis for retrieving literature dealing with reaction types are briefly reviewed, as well as the capability of a mere substructure search in a file of reactants and products. It is demonstrated that reaction indexing ideally should be based on the identification of the reaction sites of the molecules involved, as well as on the representation of various kinds of relations between these reactive centers. The GREMAS reaction indexing of IDC is discussed as an example. Before a chemist can request information on reaction types that appear promising for a certain target molecule, he must be aware of their existence. The task of computer-assisted synthesis design is to submit suggestions of conceivable synthetic pathways to a target structure and so to alert the chemist to syntheses of which he had not yet been aware. The “reverse retrieval” technique is demonstrated to constitute a fundamental principle for this kind of information supply. If sufficiently developed and assisted by an effective system for the documentation and classification of reaction types, it can provide suggestions for syntheses at a considerable efficiency without requiring completion by additional principles. The IDC system of (Sub-) Structure search seems to be able to serve this purpose too, due to its flexibility, economics, and precision. The reverse retrieval offers solutions to a number of problems hitherto unresolved in information science. 相似文献
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本文对秦始皇兵马俑博物馆室内采集的长短期降尘、大气悬浮颗粒物和彩绘漆层进行了SEM-EDX研究，在大气悬浮颗粒、短期和长期降尘中，含硫颗粒的粒径分别为0.9～22.8μm、1.0～29.0μm和1.2～37.7μm，多为石膏与粘土或石英以内部混合的状态存在。降尘中的附着型絮状硫酸钙多于大气悬浮颗粒物中，显示降尘和大气中的二氧化硫发生了累进的化学反应。彩绘漆层表面的坑和裂隙附近观察到原位生长的硫酸钙晶体，显示漆层材料或降尘颗粒物与大气二氧化硫之间的酸化学反应，可能是彩绘漆层表面受侵蚀形成微小坑和裂隙的原因之一。 相似文献
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龙勇 《科技成果管理与研究》2011,(9):48-50
SCR工艺是目前火电厂的主要采用的烟气脱硝技术,催化剂是SCR脱硝工艺的重点内容,催化剂性能直接关系到脱硝效率。文章简述了SCR脱硝技术的概念及原理,分析了影响SCR法脱硝效率的主要因素,并针对影响因素提出了一些控制措施。 相似文献