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1.
Using the velocity analyzer of Zartman with improved technique the combined velocity spectrum of Bi atoms and Bi2 molecules was obtained at 827°, 851°, 875°, 899°, 922°, 947° C. From the spectral distribution curves the relative abundance of Bi atoms and Bi2 molecules in the beams at the above temperatures could be determined to 1 per cent. The vapor pressure curve of Bi was obtained experimentally by the method of effusion and the values so obtained were combined with the degree of dissociation of the vapor as computed from the beams to give the heat of dissociation. The heat of dissociation was computed from the data, assuming the pressure to be given by the temperature of the crucible Tc. In calculating the heat of dissociation, the equilibrium temperature was taken as that of the slit chamber Ts which was 24° above Tc. The results of these calculations plotted with log10Kp as ordinates against 1Ts give a straight line whose slope yields the value of the heat of dissociation as 77,100±1200 calories. The curves for the distribution of velocities observed and computed on the assumption of a given ratio of Bi atoms to Bi2 molecules in the beam were compared in an attempt to test the law of distribution of velocities. On the high velocity side agreement in two curves was obtained within the limits of experimental accuracy. On the low velocity side important deviations were noted of such a sort that the observed curves below a velocity α2, (α is the most probable velocity) gave more molecules than the theory demanded. Other deviations were observed on some of the runs taken with a fourth slit in which a deficiency of molecules was observed between velocities of .75α and α2. This deviation was probably due to a warping of the fourth slit carriage due to heat. The nature of the variation at velocities less than α2 indicated the presence of molecules of greater mass than Bi2 in the beam and at the lower temperatures a distinct peak corresponding to Bi8 molecules was observed which were present to less than 2 per cent. The vapor pressure curve for Bi was determined by least square reduction of the observed points to be given by log10 P = ? 52.23 × 195.26T + 8.56 between 1100° and 1220° abs. It lies very close to the extrapolated curve given in the International Critical Tables.  相似文献   

2.
If T maps a convex domain DT into itself, and if {ωn} is a real sequence with range in (0, 1] then the recursive averaging process,
Xn+1=(1?omega;n) XnnnTxn, x0=ξ?DT
generates a sequence {x?n}; with range in DT. Under suitable conditions on DT, T and {ωn} the sequence {x?n} will converge in some sense to a fixed point of T. We prove that if DT is a closed convex subset of a complex Hilbert space H, if Tω = (1 ? ω) I + ωT is a strict contraction for some ω ? (0, 1], and if {ωn} satisfies the conditions,
ωn → 0
and
n=0ωn=∞
then, for arbitrary ξ ? DT, {x?n} converges strongly to (the unique) fixed point of T. We also prove that if DT and {ωn} satisfy the foregoing conditions, if T has at least one fixed point, and if Tω is non-expansive for some ω ? (0, 1], then for all ξ ? DT, {x?n} converges at least weakly to some fixed point of T. Finally, we apply these results to linear equations involving bounded normal operators and obtain an extension of the classical Neumann operator series.  相似文献   

3.
Based on theory of a previous paper, the writer has developed an equation of state for a system with a single type of transformation. This equation is of the form
h=A+Bv+Cp+Dpv?T(E+Fv+Gp+Hpv)
where h = ε + pv is the total heat, p the pressure, v the specific volume, T the temperature, and p, v, T are considered independent variables. A, B, C, etc., are constants for the system. The latent eat at constant (p, T) is given by
λp,T=(v2?v1)(?h?v)P,T= (v2?v1)[(B?TF)+p(D?TH)]
. These equations are checked with data on saturated and superheated ammonia, and the agreement is good to within a few tenths of a per cent. Also, checks with data on saturated and superheated steam show agreement within several per cent.  相似文献   

4.
This report presents the results from a study of mathematical models relating to the usage of information systems. For each of four models, the papers developed during the study provide three types of analyses: reviews of the literature relevant to the model, analytical studies, and tests of the models with data drawn from specific operational situations. (1) The Cobb-Douglas model: x0 = ax1bx2(1?b).This classic production model, normally interpreted as applying to the relationship between production, labor, and capital, is applied to a number of information related contexts. These include specifically the performance of libraries, both public and academic, and the use of information resources by the nation's industry. The results confirm not only the utility of the Cobb-Douglas model in evaluation of the use of information resources, but demonstrate the extent to which those resources currently are being used at significantly less than optimum levels. (2) Mixture of Poissons:
χ0 = i=0nij=0p njemj(mj)′/i!
where x0 is the usage and (nj,mj),j = 0 to p, are the p + 1 components of the distribution. This model of heterogeneity is applied to the usage of library materials and of thesaurus terms. In each case, both the applicability and the analytical value of the model are demonstrated. (3) Inverse effects of distance: x = a e?md if c(d) = rdx = ad?m if c(d) = r log(d).These two models reflect different inverse effects of distance, the choice depending upon the cost of transportation. If the cost,c(d), is linear, the usage is inverse exponential; if logarithmic, the usage is inverse power. The literature that discusses the relationship between usage of facilities and the distance from them is reviewed. The models are tested with data from the usage of the Los Angeles Public Library, both Central Library and branches, based on a survey of 3662 users. (4) Weighted entropy:
S(x1,x2,...,xn)= -i=1n r(xiP(xi)log(p(xi)).
This generalization of the “entropy measure of information” is designed to accommodate the effects of “relevancy”, as measured by r(x), upon the performance of information retrieval systems. The relevant literature is reviewed and the application to retrieval systems is considered.  相似文献   

5.
The paper describes the phenomena associated with the reflection of a sharply defined beam of hydrogen atoms from a crystal of LiF. Of primary interest is the fact that the atoms show interference effects in agreement with the wave mechanics theory and plane grating diffraction patterns are photographed. Evidence of the thermal agitation of the surface ions is obtained from the diffuse reflection with surrounds the specular beam.The Schrödinger wave equation for the motion of a free particle of mass m is
2ψ ? 4πmih?t = 0 (I)
. The solution of this equation corresponding to the kinetic energy mv22 is
ψ = Ae2πi(vt?σxx?σyy?σxz), (2)
where
v  mv22and σ mvh
. The motion of such a particle should have the characteristics of a plane wave of frequency ν and wave-length λ = 1σ. The experiments of various investigators1 have shown the validity of the wave theory of the motion of the free electron and have given values of the wave-length in agreement with the theory.The free motion of atoms, ions and molecules should likewise have wave characteristics. In the case of the hydrogen atom, as the simplest example, the complete wave equation may be written in the form
Im2 x,y,zψ + Iμ2η,μζψ ?2μ?ψmh2η2 + μ2 + ζ2
? 4πih?t = 0, (3)
where x, y, z, are the coördinates of the center of mass of the atom and ξ, η, ζ the coördinates of the electron with respect to the center of mass. If m? and m+ are the masses of electron and proton, m and μ have the significance
m = m? + m+and Iμ = Im? + Im+
. Equation (3) is solved by
ψ = U1(x,y,z) U2(η, ν ζ) ?2πiEth
, where E may have a continuous set of values and represents the total energy. U1 and U2 must satisfy the equations
12U1 + 2mβU1h2 = 0, (4)
and
22U2 + 2μh2 (α ? μ?mη2 + ν2 + ζ2)U2 = 0 (5)
, where
α + β + E
.  相似文献   

6.
The removal of mercury from dilute solutions of mercuric nitrate by mercuric sulfide is indicative of an adsorption process. The relation of log xm vs. log C shows that the Freundlich adsorption isotherm exists.At higher concentrations of mercuric nitrate a reaction takes place with the mercuric sulfide forming a compound of the possible formula 2HgS·Hg(NO3)2 mercuric nitratodisulfide.  相似文献   

7.
Given the linear system x = Ax - bu, y = cTx, it is shown that, for a certain non-quadratic cost functional, the optimal control is given by uopt(x) = h(cTx), where the function h(y) must satisfy the conditions ky2?h(y)y>0 for y≠0, h(0) = 0 and existence of h-1 everywhere. The linear system considered must satisfy the Popov condition 1/k + (1 +?ωβ) G(?ω)>0 for all ω, G(s) being the y(s)/u(s) transfer function.  相似文献   

8.
The solution of the differential equation y″ + 2Ry′ + n2y = E cos pt is written in a new form which clearly exhibits many important facts thus far overlooked by theoretical and experimental investigators. Writing s = n ? p, and Δn = n ? √n2 ? R2, it is found: (a) When s ≠ Δn, there are “beats,” and the first “beat” maximum is greater than any later maximum while the first “beat” minimum is less than any later “beat” minimum. The “beat” frequency is (s ? Δn). (b) When n2 ? p2 = R2, there are no “beats,” and the resultant amplitude grows monotonically from zero to the amplitude of the forced vibration, (c) At resonance, when n = p, we still have maxima which occur with a frequency Δn in a damped system. (d) The absence of “beats” is neither a sufficient nor a necessary condition for resonance in a damped system.In the experimental investigation the upper extremity of a simple pendulum was moved in simple harmonic motion and photographic records obtained of the motion of the pendulum bob. Different degrees of damping were used, ranging from very small to critical.The experimental results are in excellent agreement with theory.  相似文献   

9.
In an alternating current servomechanism, the error is proportional to the modulation envelope of a modulated-carrier error signal. It is shown in part I that for stability and fidelity of the servo, it is highly desirable that the effect of the controller includes a proportional-derivative action on the modulation envelope. This action may be obtained with various forms of RC networks, including the parallel “T,” bridge “T,” and Wien Bridge forms.This part contains detailed design procedures and tables of values for the various types of proportional-derivative networks. Several forms of parallel “T” networks arise from the fact that there are five independent time constants in the network, while in order to realize the desired transfer characteristic it is necessary to impose only four conditions. It is indicated how the remaining degree of freedom may be used to obtain the most suitable input and output impedances for the source and load impedances with which the parallel “T” is to be used. The derivations for the parallel “T” formulae are given in an Appendix.Tolerance requirements on the components of parallel “T” and bridge “T” networks are derived. If ±1 per cent components are used at 60 cycles, the resonant frequency will lie between 56.4 and 63.6 cycles, and the notch width (rejection band width) will be within ±0.99 cps. of the correct value. In order to guarantee that the phase shift at 60 cycles is within ±10°, the percentage deviation of each part must be less than (9.0Tdω0), where ω0 is the carrier angular frequency, Td the derivative time constant.  相似文献   

10.
It is well known that the wave mechanical ψ equation leads to the conclusion that the centroid of the wave mechanical electron should move according to the classical electrodynamic equation of motion in which, however, the terms representing what is commonly called radiation reaction are absent. If v is the velocity of the electron, the classical rate of change of momentum is mddt{v(I ? v2c2)12}. The equation of motion including radiation reaction terms may be regarded as obtainable by replacing this quantity by one obtained by operating upon it with the operator P?1
P={I?α1kddt + α2ddt(kddt)?·}?
where α1, α2, etc., are constants and k = (I ? v2c2)?12. The main purpose of the paper is to show that if there be any relativistically invariant ψ equation which leads to the classical equation of motion without radiation reaction terms, then by replacing the vector and scalar potentials U and ? in that equation by P(U) and P(?), a relativistically invariant equation of motion will be obtained including the radiation reaction terms, provided that the ddt in P be now regarded as ??t + u · grad, where u is the velocity of the wave mechanical density distribution at a point. The purpose is to use the power to produce the equation of motion as a criterion for suggesting the proper modification of the ψ equation to apply in those cases where, on the classical theory, the electron would suffer great acceleration, as in ionization by rapidly moving corpuscles.  相似文献   

11.
The resistance coefficient of a body moving in a fluid depends on Reynolds Number R, Mach Number M and the parameter gLU2, which is customarily neglected in view of small weight of the air. Here L denotes a characteristic length; U denotes the body's speed of translation. The author points that dimensional deduction of this parameter does not limit it to the acceleration of gravity, and that the resistance coefficient is affected by the general acceleration to which the air is subjected. Evaluation of the acceleration of the air flowing about spheres puts this parameter in the form LR, where the characteristic length L is interpreted as the mean free molecular path. Large and small spheres were found to have widely different values of the pressure coefficient Δpq for the same Reynolds Number or Mach Number. Here Δp denotes the difference in pressure between front stagnation point and the rear portion of the sphere, and q denotes the dynamic pressure. The plot of Δpq against the parameter LR removes this confusion. The low values of Δpq are found to be associated with LR below a certain critical value, and high values of Δpq with LR above the critical value, which apparently indicates the condition under which the flow separation takes place. Attention is called to the effect of air pressure on the separation as shown by the parameter LR, and its possible bearing on the drag in high altitude flying.  相似文献   

12.
Capabilities of the resonance flourescence technique are discussed. Specific reference is given to the study of ground state dipole and electric quadrople transitions below about 5 MeV in 206Pb, 207Pb, 208Pb and 209Bi. It is suggested that many of the states observed in 207Pb and 209Bi arise from the weak-coupling of a p12 neutron hole or an h92 proton to collective levels of 208Pb.  相似文献   

13.
14.
In this paper we attempt to obtain approximate solutions of improved accuracy for a class of differential equations of the form
d2ydx2+εμ(x)dydx2cy = 0
, where ε is a real parameter less than unity, ωc is a positive real constant of order unity and μ(x) is a singular function of x in the region of interest. It does not appear to be possible to find a general analytic expression for the error estimate of the approximate solution. For the case μ(x) = x?2, however, it is shown that the approximate solution is accurate to 0(ε2), as x → 0? from negative values, by comparing it with the numerically integrated solution. For the same case, the approximate solution is orders of magnitude more accurate than Poincaré's first-order perturbation solution, which is accurate to 0(ε2ln|x||x|) as x → 0?. This work arose in search of analytic solutions to a linearized form of the restricted three-body problem.  相似文献   

15.
16.
This paper is a continuation of a previous paper published in this JOURNAL. The basic idea in the two papers is to enlarge the assemblage of thermodynamic states by including the so-called “metastable” states. Considering a system, in one or two phases, which has a single type of transformation, the writer develops an equation of state of the form η = a + by + cp + dpv + (e + fv + gp + hpv) In T, where p, v, T are three independent variables, and a, b, c, etc. are constants.The latent heat at p, T = constant is λP,T = I (v2 -v1) [b+db+(f+hp) InT), which is derived from the equation of state.The available thermodynamic data on ammonia and steam are used to check these equations. It is found that within the saturated region the agreement is quite satis factory, whereas for the superheated region the agreement is not so good.  相似文献   

17.
Let X=x1,x2,…,xnX=x1,x2,,xn be a sequence of non-decreasing integer values. Storing a compressed representation of X that supports access and search is a problem that occurs in many domains. The most common solution to this problem uses a linear list and encodes the differences between consecutive values with encodings that favor small numbers. This solution includes additional information (i.e. samples) to support efficient searching on the encoded values. We introduce a completely different alternative that achieves compression by encoding the differences in a search tree. Our proposal has many applications, such as the representation of posting lists, geographic data, sparse bitmaps, and compressed suffix arrays, to name just a few. The structure is practical and we provide an experimental evaluation to show that it is competitive with the existing techniques.  相似文献   

18.
19.
This paper gives a general review of the Theory of Nonlinear Systems. In 1960, the author presented a paper “Theory of Nonlinear Control” at the First IFAC Congress at Moscow. Professor Norbert Wiener, who attended this Congress, drew attention to his work on the synthesis and analysis of nonlinear systems in terms of Hermitian polynomials in the Laguerre coefficients of the past of the input.Wiener's original idea was to use white noise as a probe on any nonlinear system. Applying this input to a Laguerre network gives u1, u2,…, us, and then to a Hermite polynomial generator gives V(α)'s. Applying the same input to the actual nonlinear system gives output c(t). Putting c(t) and V(α)'s through a product averaging device, we get c(t)V(α) = Aαs2, where the upper bar denotes time average and Aα's can be considered as characteristic coefficients of the nonlinear system. A desired output z(itt) may replace c(itt) to get a new set of Aα's.The Volterra functional method suggested by Wiener in 1942 has been greatlydeveloped from 1955 to the present. The method involves a multi-dimensional convolution integral with multi- dimensional kernels. The associated multi-dimensional transforms are given by Y.H. Ku and A.A. Wolf (J. Franklin Inst., Vol. 281, pp. 9–26, 1966). Wiener extended the Volterra functionals by forming an orthogonal set of functionals known as G-functionals, using Gaussian white noise as input. Volterra kernels and Wiener kernels can be correlated and form the characteristic functions of nonlinear systems.From an extension of the linear system to the nonlinear system, the input-output crosscorrelation φxy can be shown to be equal to the convolution of system impulse response h1 with the autocorrelation φxx. Using the white noise as input, where its power density spectrum is a constant, say, A, the crosscorrelation is given by φxy(σ) = Ah1(σ), while the autocorrelation is φxx(τ) = Au(τ). This extension forms the basis of an optimum method for nonlinear system identification. Measurement of kernels can be made through proper circuitry.Parallel to the Volterra series and the Wiener series, another series based on Taylor-Cauchy transforms developed since 1959 are given for comparison. The Taylor-Cauchy transform method can be applied in the analysis of simultaneous nonlinear systems. It is noted that the Volterra functional method and the Taylor-Cauchy transform method give identical final results.A selected Bibliography is appended not only to include other aspects of nonlinear system theory but also to show the wide application of nonlinear system characterization and identification to problems in biology, ecology, physiology, cybernetics, control theory, socio- economic systems, etc.  相似文献   

20.
Present Status of the Problem.—The scattering of X-rays is one of the outstanding problems of electromagnetic radiation which has not been solved satisfactorily. All theories (based on classical electrodynamics) presented thus far do not explain either the diminution in the scattering coefficient, or the observed asymmetry in the scattering, or both. Among such theories we may mention:J. J. Thompson's Theory.—Assuming that the scattering is done by a point electron, and making use of certain additional hypotheses, Thomson showed that the scattering coefficient of any substance is given by
σ=8πNpe43m2c4
and that the intensity of the scattered radiation is given by
Iθ=Ie4(I+cos2θ)2r2m2c4
where N is the number of atoms per c.c., p the number of electrons per atom, e the electronic charge, m the electronic mass, c the velocity of light, Iθ the intensity of the scattered radiation at an angle θ between the incident beam and the radius vector joining the centre of the electron and the point P distant r from the electron, and I is the intensity of the incident beam. This theory explains neither the asymmetry nor the decrease in the coefficient of scattering.Schott's Theory.—Among other things, the assumption is here made that the atom consists of coaxal rings of electron. The electrons in each ring are spaced at equal intervals and revolve with a uniform angular velocity, which, however, may be different for different rings. This theory fails to explain the observed diminution in the scattering coefficient.Debye's Theory.—In its essentials, Debye's theory has the same merits and demerits as that of Schott. Debye assumes that all the electrons in an atom are arranged in a single ring, and that they are spaced at equal intervals. This theory (and also Schott's theory) explains the asymmetry and the “excess scattering,” but is altogether unable to explain the diminution in the scattering coefficient.Modification of the Classical Theory.—The present paper presents a discussion of the possibility of modifying the classical theory (that of J. J. Thomson) so as to account for the decrease in the scattering coefficient as well as the dissymmetry. By assuming that the electron is made up of a number of parts—for simplicity, of two parts—it has been found possible to account for the diminution in the scattering coefficient without, at the same time, explaining the observed asymmetry. To accomplish both objects is what was aimed at in the combination of the present work with that of Debye. In this research the goal has not been perfection between predicted and observed results, but rather to discuss some possible modifications of the classical theory and their consequences.  相似文献   

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