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1.
Slate has been used for centuries as a building material, and many historical buildings and monuments use slate in roofs and structures. When slate roofs must be totally or partially replaced, the structural and aesthetic integrity of the building as a whole must be guaranteed, based on both international criteria for restoration, and on current local legislation regarding historical buildings. For selection of the most appropriate type of slate to use in the restoration of historical slate roofing, we propose the following steps: a) study of the roof's state, b) spectrophotometric determination of the texture and colour of the original slate, c) petrographic study and determination of the weatherability of the replacement slate, and d) location of the original slate quarry area. With all these data it is possible to choose the most suitable type of commercial slate for replacing the original slate. Thus, even in the absence of historical information, with this four-stage process a replacement slate for building restoration can still be selected on clear and justifiable grounds. The present article uses this methodology to examine two case studies of roofing slate restoration.  相似文献   

2.
The paper presents our results concerning a complex investigation by reflectance spectroscopy (RS) and Electron Paramagnetic Resonance (EPR) of the defects induced by gamma irradiation in 22 different historical pigments. Gamma irradiation is used to destroy microflora and insects which are involved in biodeterioration processes of art works such as paintings. At the same time, it can induce defects i.e. color centers which are likely to modify the original painting colors by altering the embedded pigments. Accordingly, RS was used to quantify, by means of CIELAB color space, the contribution of irradiation defects to the pigments color changes, while EPR spectroscopy, in view of paramagnetic properties of color centers, was used to confirm their presence after irradiation. Our investigations showed that, excepting marble dust whose color alteration was still observable after 3 months, color changes induced by irradiation in all other pigments disappeared after about 30–40 days. In addition, RS as well as EPR measurements suggest that color changes are related to irradiation color centers, this finding being confirmed by the coincidence, within experimental uncertainties, of the half-life time color changes as obtained by these methods.  相似文献   

3.
Salt crystallization is a major cause of damage in porous materials such as stone, brick and ceramics. The paper reports results of an analytical study on tiles of glazed ceramics that are seriously damaged by acetate salt crystallization. Measurements of the ionic composition of the salt mixture in the tiles and in the efflorescences were carried out. Based on the available information on the phase equilibria in the system comprising of the main constituents chloride, nitrate, acetate, calcium and sodium, the crystallization pathways of the various solid phases are traced. It is shown that a combination of qualitative XRD analysis of the phases present in the efflorescences together with a quantitative determination of the ionic composition is sufficient for the quantitative analysis of major crystalline species in the efflorescences, i.e. Ca3(CH3COO)3Cl(NO3)2 · 7H2O, thecotrichite, and NaCl, halite. The concentrations of these salts are obtained from a solution of the mass balance by least squares analysis. Their formation from the salt mixtures present in the tiles that are subject to acetic acid vapor attack is consistent with the solubility diagram of the above mentioned quinary system. Finally, the possibilities of preventive conservation of salt contaminated ceramics in typical museum environments are discussed.  相似文献   

4.
Piperno, a Late Quaternary magmatic rock cropping out on the eastern side of the Campi Flegrei (Italy), is probably the most important building stone of Naples, used over a time-span from at least the Roman age until the beginning of the 20th century. Despite its wide diffusion in the monumental architecture of Naples, very little is known about this rock, as regards its technical features, as well as the geological aspects. This paper aims at providing a first overall contribution towards a rediscovery of this long-time-used material, in view of careful restoration works, which nowadays at Naples only take into account the proper geological features of the stone in a few peculiar cases. Thus, it seems of extreme importance to understand the basic parameters of Piperno and, above all, its response to weathering agents. Main mineralogical, petrographical and engineering–geological properties are presented here for the first time, with specific reference to two sampling areas, located at Pianura and Soccavo, in the western sector of the Neapolitan urban area. As far as many of its physico–mechanical features are concerned, Piperno extends over a wide range of values, which allow different varieties of the rock to be identified. This preliminary result is seemingly in accordance with data from old historical literature, which stated the existence of six horizons in the Piperno formation.  相似文献   

5.
This paper describes a scientific approach aimed at studying the ancient part of Palazzo d’Accursio (Bologna, Italy), a masonry building which is part of the Italian cultural heritage. Laser scanning and the inspection of digital images are used to detect traces of restoration works and other interesting features related to both architectural marks and natural or anthropic events. One of the main elements of the method is the analysis of residual maps, obtained by computing the differences between the point coordinates of the façade and reference fit planes. The obtained results, based on both radiometric and geometrical analysis, are used to provide a reasonable hypothesis as to the original configuration of the studied building, while taking into account the available historical information about the constructive phases of the building.  相似文献   

6.
The ‘Cotto Variegato’ are tiles used in Lombardy, between the XVII and XIX centuries as flooring for several historical buildings. Tiles are produced by the processing of two compositionally distinct clays. The main stylistic character of these tiles is a banded texture producing a veined aspect, in which white and red bands are also folded. The artefacts were hand crafted using two clayey raw materials of different composition, that are only partially mixed before the firing. The colour differences are produced during the firing. In all samples white and red portions are always composed of Ca-rich and Ca-poor clay, respectively. The multi-layered texture was obtained by a multiple folding and pressing process of the mixture. The interference of fold limbs with the tile surface gives the ‘variegato’ style to tiles. The paper explains how basic petrological knowledge can be applied to the study of ceramic artefacts in order to define provenance of the raw material, firing technology and how ancient craftsmen transformed the natural clayey materials into floor tiles. The methodological approach is that commonly applied to the study of the rocks and consists of textural analyses, at a different observational scale, combined with X-ray powder diffraction, X-ray fluorescence and microprobe analyses.  相似文献   

7.
Limestone and marble, still frequently used as building materials are especially vulnerable to the destructive effects of efflorescence. The effect of interaction between five different calcareous stones and corrosive atmospheres has been investigated. A novel technique of stone degradation analysis has been used where thin sections of fresh stone materials were exposed in a corrosion chamber under controlled conditions (temperature, relative humidity (RH), SO2 and NO2 concentration). Following 1-week’s exposure; observations of the initial crystallisation were studied by light microscopy, scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX) and X-ray diffraction (XRD). The results obtained from the surface analysis clearly showed sulphation of the samples and formation of gypsum. Observations of the initial corrosion indicated differences in the location of efflorescence and its shape among and within the samples. The mineralogy, grain shape and size, mineral defects and existence of cracks and pores, all influenced the substrate’s reactivity. The most vulnerable areas and the places where the corrosion started on the calcitic stones were the triple grain junctions followed by grain boundaries, and on the dolomitic marble cracks and pores.  相似文献   

8.
The application of a new class of organogels as cleaning tools for painted surfaces is described. It combines some of the most attractive features of cleaning liquids and normal gels while diminishing the deleterious characteristics of both. Thus, the ‘latent’ gellant, polyethyleneimine (PEI), reacts with CO2 at room temperature in solutions of several organic liquids to produce an ammonium carbamate form (PEICO2). This charged species organizes itself into 3D polymer networks which immobilize the liquids as gels. The properties of the original solution (i.e. a free-flowing liquid) are re-established immediately after addition of a small amount of a weak acid which displaces the CO2 molecules and makes the PEI chains positively charged. The visual changes are substantiated by rheological analyses. Results from analytical tests to determine the utility of these gels as cleaning tools for painted surfaces of historical and artistic interest, have been obtained from contact angle and FTIR measurements as well as visual comparisons of the surfaces before and after application of the gels. The analyses indicate that the PEICO2-based organogels were very effective in removing different surface patinas from painted supports. A surface layer of dammar was completely removed from a test canvas with oil paint, an aged painting from the XIX century, and a XV century oil-on-wood panel attributed to Mariotto di Cristoforo. Finally, a surface acrylic polymeric resin (used in a restoration performed during the 1960s) was also successfully removed from Renaissance wall paintings decorating the Santa Maria della Scala Sacristy in Siena, Italy. The isothermally rheoreversible gel approach described in this work represents a new, highly versatile, and very efficient method for removing aged surface patinas from works of art.  相似文献   

9.
The Minerva of Arezzo is an ancient bronze statue located at the Museo Archeologico in Florence and currently under repair at the Restoration Centre of the Soprintendenza Archeologica of the Tuscany Region. We assembled a complete three-dimensional (3D) digital model of the Minerva before the restoration started. More 3D models will be produced to keep track of the variations that occurred during the restoration process, up to the final acquisition of the form of the restored artwork. The modelling of the Minerva will be the focal point of an ambitious “Minerva Project” that involves the integration of data from other sources in a 3D digital model of the object. Besides this, the project is aimed at showing how 3D techniques can be used to design useful and easily manageable new tools for the diagnostics of archaeological objects. 3D measurements have been realized by means of a high-resolution laser scanner developed at National Institute for Applied Optics (INOA). The instrument is composed of commercial low-cost components in order to be competitive with the very expensive commercial devices. Besides this, our scanner is supported by an efficient and flexible software developed by Consiglio Nazionale delle Ricerche (CNR) that supports all the post-processing phases of a 3D scanning session (range data alignment, merge and simplification).  相似文献   

10.
The scientific approach to the restoration and monitoring of mural paintings, at S. Girolamo Chapel – SS. Annunziata Church in Florence, is reported as a fruitful example of the synergic collaboration between restorers and scientists in the planning and development of conservative interventions. Before restoration, the painting technique and the state of preservation of the pictorial cycle have been investigated firstly by close examination of the painted surfaces and then by optical and/or SEM-EDS microscopy and μFT-IR spectroscopy on appropriately selected samples. In particular, the original constituent materials and those belonging to subsequent restorations were characterized together with those originating from decay processes. In this mural painting cycle, a peculiar “fresco” technique has been used although an auxiliary binder for pigment distemper has been also employed. The use of this technique, sometimes in an improper way together with uncorrected restoration interventions, are the main responsible of the unsatisfactory state of conservation of many painted areas. Preliminary conservation trials and scientific studies were carried out to design the most convenient restoration intervention and to verify the correctness and non-invasive of the necessary operations. Special attention was devoted to cleaning procedures, continuously monitored by a physico-chemical methodology, mainly based on microinvasive, microscopic and spectroscopic investigations, to evaluate the efficiency, advantages and drawbacks of the proposed cleaning procedures and define the most appropriate ones. Finally, specific decay markers have been recognized, by a comparison of the results obtained from the detached samples with those deriving from artificially aged models, to be used for a correct future monitoring and maintenance of the wall paintings.  相似文献   

11.
Three-dimensional (3D) digital preservation aims at generating 3D models of objects that have cultural or scientific value. It allows realistic visualization of objects through virtual museums or scientific applications, and the restoration of the preserved object in case of natural wear or accidents. This work contributes to this research area by presenting a method to improve color texture quality of 3D models obtained from color and depth images of a laser scanner. Although this device offers precise depth information, the resulting color information is still poor and limits the generation of realistic textures. Our approach is to capture photographs of the object with a high-resolution digital camera and use them to generate a new color texture for the 3D model. Our work proposes a practical technique, easy to replicate, to generate high quality textures for 3D models from photographs. The method is composed by three main steps: (1) calibration of the image acquisition devices; (2) data acquisition; and (3) texture generation. In this paper, we detail our color texture generation method and apply it on the digital preservation of many artworks made by native Brazilians (indians) from the Wauja and Karaja communities. These indigenous communities are acknowledged as great ceramic artists, each bearing their own main themes, using a very rich symbolism in their paintings. Their artworks represent important aspects of the native South American culture and their digital preservation is motivated by three main reasons: (1) their fragility; (2) the paintings loose their original appearance with time; and (3) the possibility of extinction of these communities. We present several results of preserved artworks with enhanced quality realistic texture maps. Also, we present a methodology to analyze the quality and accuracy of texture maps. The resulting 3D models can be visualized through a tool we developed to support the virtual exhibit of 3D preserved heritage.  相似文献   

12.
Principal Component Analysis (PCA) was applied on colour measurements performed on outdoor bronze patinas and protective coating systems on bronze coupons in order to monitor natural weathering and cleaning effects. PCA chemometric technique is shown to be a powerful tool to analyse the large measurement data set which is needed to characterise these kinds of system. The results are compared with previous work where the CIELAB L*a*b space was used, in order to spot the advantages and disadvantages of both techniques and how they can complete each other in order to set up a workflow when dealing with large datasets of colour measurements. As previously stated, quicker colour variations in the early stage of natural weathering of bronze coupons are characterised, which is mainly due to lightness reduction. PCA analysis helps to visualise the different behaviour upon cleaning procedure of different monument patinas and colour difference reduction due to cleaning. It gives the advantage in a first screening phase to possibly highlight the presence of outliers, check the level of noise in the spectra, and select the variables which carry more information. Its integration in a workflow for colour measurement can help in speeding up the process of later analysing data with the well-established CIELAB system.  相似文献   

13.
With the aim of identifying new water dispersed polymers for textile conservation, the structure and properties of three commercial polyacrylates and one commercial polyvinylacetate were analysed. The characteristics of these materials, not previously used in the conservation and restoration fields, were compared with that shown by Primal AC33 and Mowilith DMC2 and SDM5, widely used as consolidating or adhesive agents of ancient textiles. To achieve a thorough characterisation of each polymer, molecular, thermal, structural and mechanical investigation techniques were applied on film samples, obtained from polymer water dispersions through water casting at room temperature and/or compression moulding. The photo-oxidative resistance of these materials was also assessed by artificial weathering of water cast films and by measuring the Yellowing Index (YI) as a function of the exposure time under xenon-arc lamp. Collected data were used to appropriately compare the performances shown by these polymers when applied on artefacts consisting of natural fibres. In particular it was found that, among the products not previously used in the conservation and restoration fields, a high potential for carrying out treatments on textiles is shown by the samples commercialised with the trade names of Acrilem RP6005 and Acrilem 30WA. These products, in fact, exhibit properties that make them suitable as substitutes for Primal AC33 and Mowilith DMC2 and SDM5, respectively, depending upon conservation needs. It was very interesting to note that Acrilem 30WA, also after aging, shows YI values lower than that shown by Mowilith DMC2 and SDM5.  相似文献   

14.
2008年岁末隆冬，我第4次踏上访问杭州的旅程。记得1965年春我首次来杭，这座充满江南风情的城市就给我留下美好而难忘的印象。那时西子湖畔桃红柳绿，各大庙宇和名胜古迹均向游人开放，供人们自由观览。那时居民的住宅大都是粉墙黛瓦，很少看到高楼大厦。  相似文献   

15.
The study of the interaction between silica glass and saturated Ca(OH)2 solutions can be a useful approach to resolve the problem of the adhesion between lime-sand mortar and clay bricks. Since it is reasonable that the silica–calcium hydroxide system well simulates a brick–mortar system, experimental observations concerning the interaction of silica glass and this strong basic solution should be of value for the comprehension of the chemical reactions that could take place at the mortar–brick interface, maybe affecting the adhesion between the two building materials. We demonstrated the effects of saturated Ca(OH)2 solutions on commercial pure silica glass (fused silica) and on silica films obtained via a sol–gel process by means of dip-coating. Silica samples were dipped in the solutions at different temperatures (room temperature, 60 and 80 °C) and at different time intervals (1 and 21 h) and then they were analysed by means of surface techniques: X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS) and atomic force microscopy (AFM). It has been shown that Ca(OH)2 reacts with the silica glass network. The experimental results clearly show a very different behaviour of sol–gel silica with respect to fused silica, probably because of their different nanostructure. Many problems concerning the interaction of silica and Ca(OH)2 are still to be solved, but the results of this research strengthen the idea that adhesion between lime-sand mortar and clay bricks is caused not only by carbonation of calcium hydroxide contained in the mortar, but even by some chemical reactions involving the brick constituents and calcium hydroxide itself. The final products, calcium silicates, may induce a chemical continuity between lime-sand mortar and clay bricks.  相似文献   

16.
Multivariate statistics is a well-known and invaluable tool in archaeological science but its use is limited in monument restoration. The aim of this work is to demonstrate the effectiveness of Principal Component Analysis (PCA) on the characterization, technology and weathering condition investigation of building materials from historical monuments.Towards this aim, three examples are given:The first one is a provenance and technology investigation of the Aghia Sophia (Istanbul, Turkey) bricks, some of which had to be replaced due to weathering, during recent restoration works. It was proved by PCA that the original clay, used for the construction of the bricks, is not similar to the clay of other contemporary constructions in Istanbul but presents high similarity to the raw material of the bricks from a contemporary church in the island of Rhodes (Dodecanese, Greece). Additionally, the technology of the bricks was studied by mercury intrusion porosimetry, strength tests and Scanning Electron Microscopy. The use of PCA gives a very comprehensive way to present the difference in the technology of the dome bricks.The second presents a classification of mortars from medieval (Byzantine) monasteries, based on their microstructural characteristics (porosity, reverse hydraulicity ratio) and strength measurements. The PCA grouping gives an illustrative diagram depicting the correlation between mortar syntheses and resulting characteristics.The third case shows an example of the correlation between environmental pollution data and data from the weathering layers of marble surfaces (patina composition, orientation of the monument surface, etc.).  相似文献   

17.
Conserving architectural heritage usually requires a multidisciplinary approach involving a variety of professionals and organizations. Since the evaluation of the state of conservation of historical buildings using destructive techniques should be avoided to prevent the integrity of the cultural heritage, the development of non-destructive and non-contact techniques is very important. InfraRed (IR) thermography is a non-destructive powerful tool for fast and accurate building diagnostics. In the investigation of historical structures, where a restoration or conservation treatment can cause irreversible damage to the structure, it is considered to be of most importance. A campaign of thermographic surveys were conducted on a large part of the historical cultural heritage of L’Aquila and its surroundings. In this paper we present the results of the study for the Church of Santa Maria ad Cryptas (XIII century), one of the most ancient buildings in the surroundings of L’Aquila and one of the best examples of Gothic art in Abruzzo, with the aim to evaluate the correspondence between the damage induced by the earthquake and the previous thermographic results, in order to validate the effectiveness of thermography and its role in preventive diagnosis.  相似文献   

18.
The use of numerical simulation methods for the Cultural Heritage is of increasing importance for the analysis, conservation, restoration and appreciation of works of art. This is particularly important when their preservation and planned maintenance is the primary aim. Today museums, and particularly historical buildings converted to museums, should be considered as places where precious artefacts should have first-rate protection and conservation. It is a question of solving the compromise between protection, conservation and comfort for works of art and/or visitors, with the consequence that preservation and planned maintenance criteria must prevail over use requirements. Refurbishment and conservation of a building, and requirements for visitor presence and works of art need different thermo-physical indoor parameter values. The present paper concerns the thermal and air velocity analysis of the Salone dei Duecento (the Hall of the Two Hundred of the Palazzo Vecchio (Old Palace)) in Florence. In this paper an appropriate transient 3D model by Computational Fluid Dynamics (CFD) software based on the finite element method (FEM) was used. Variations and interaction between indoor and outdoor microclimatic conditions, and thermo-physical behaviour of the building connected to lighting, visitor presence and cooling–heating fan coils system were considered. The 3D modelling method provided by the present paper can be applied to several situations where there is interaction between outdoor and indoor climate variations and the building structure. It can be very useful for defining measures to preserve tapestries, understanding deterioration processes, and developing new conservation techniques and strategies for care and exhibition.  相似文献   

19.
The Church of the Maddalena was built between 1763 and 1778 by Tommaso Temanza. The building has a central plan and is surmounted by a copper-covered brick masonry dome. The conservation work conducted on the façade has highlighted the superb quality workmanship of the Istrian stone surfaces, which feature extremely fine grain, perfectly regular tooth-chiselling. This finish has led, however, to very specific conditions of decay and laser treatment provided appreciably better results than traditional chemical and mechanical methods. In addition to laser, however, other methods of cleaning were used in order to find the best response to each of the various situations encountered. Indeed it should be emphasized that in restoration it is often appropriate to exploit the potential of several systems, combining their action on the basis of careful preliminary analyses.  相似文献   

20.
Drawing on the existing research on the socio-economic impact of cultural heritage on local and regional development, the author's aim is to further the scientific discourse in two ways. Firstly, she focuses on the economic and social significance of private investors as important actors implementing heritage restoration projects. Although these initiatives are often primarily commercial in character, they may nonetheless exert a strong, broadly positive influence on local and regional development processes, especially if a cluster of such projects develops within a relatively small area richly endowed with a specific type of heritage. Secondly, she provides empirical evidence from Central and Eastern Europe, a region little explored to date by studies of this type. Accordingly, the article examines the specific context of post-1989 private heritage-oriented investments in historic palace and garden residences in the region of Lower Silesia in Poland, a heritage previously unwanted, ethnically and ideologically dissonant, but nowadays being rediscovered to an increasing extent.  相似文献   

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