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1.
A novel in-situ electrochemical oxidation method was applied to the degradation of wastewater containing chlorophenol. Under oxygen sparging, the strong oxidant, hydrogen dioxide, could be in-situ generated through the reduction of oxygen on the surface of the cathode. The removal rate ofchlorophenol could be increased 149% when oxygen was induced in the electrochemical cell. The promotion factor was estimated to be about 82.63% according to the pseudo-first-order reaction rate constant (min-1). Important operating parameters such as current density, sparged oxygen rate were investigated.Higher sparged oxygen rate could improve the degradation of chlorophenol. To make full use of oxygen, however, sparged oxygen rate of 0.05 m3/h was adopted in this work. Oxidation-reduction potential could remarkably affect the generation of hydrogen peroxide. It was found that the removal rate of chlorophenol was not in direct proportion to the applied current density. The optimum current density was 3.5 mA/cm2 when initial chlorophenol concentration was 100 mg/L and sparged oxygen rate was 0.05 m3/h. 相似文献
2.
INTRODUCTION Chlorinated phenols compounds used widely in industry were intentionally or inadvertently released into environment in large quantities. These chlorin-ated aromatic compounds have strong resistance to physical, chemical and biological treatments and have been listed as a priority pollutant by the U.S. Envi-ronmental Protection Agency (Lin and Tseng, 1999). Wastewater containing chlorophenols has malodor-ous odor, high toxicity, bioaccumulation and car-cinogenic potential. … 相似文献
3.
以半导体材料二氧化钛为催化剂,对偶氮染料甲基橙溶液进行了电催化氧化降解实验;考察了催化剂量、槽电压、pH值、电解质浓度、反应时间等因素对处理效果的影响.实验结果表明:二氧化钛的催化效果显著,其色度和COD去除效果可比无催化剂时效果分别提高35%和28%;去除机制主要是电催化体系中产生的·OH对有机物的氧化、降解. 相似文献
4.
Boron-doped diamond (BDD) film electrodes using Ta as substrates were employed for anodic oxidation of salicylic acid (SA). The effects of operational variables including initial concentration,current density,temperature and pH were examined. The results showed that BDD films deposited on the Ta substrates had high electrocatalytic activity for SA degradation. There was little effect of pH on SA degradation. The current efficiency (CE) was found to be dependent mainly on the initial SA concentration,current density and temperature. Chemical oxygen demand (COD) was reduced from 830 mg/L to 42 mg/L under a current density of 200 A/m2 at 30 °C. 相似文献
5.
A one-dimensional column is set up to study the mass transfer during air sparging process for methyl tertiary butyl ether(MTBE) removal in saturated soil and groundwater, with the condition of different airflow and soil penetrability. It is shown that the removal rate of MTBE can reach 80%, 90% and 95% when airflow is 0.05 m3/h, 0.085 m3/h and 0.10 m3/h, respectively. Increasing airflow will help to increase the removal rate of dissolved MTBE, but eventually a threshold removal rate is reached, above which further increasing air injection rates does not increase the removal rate. Fine sand allows the injected air to travel in bubble form, while coarse sand and medium sand allow the injected air to travel in the form of discrete channels; the greater the soil grain size is, the more extensive the channel net work forms, which in turn leads to higher removal rate. A tailing effect of lingering residual contaminant concentrations occur within the fine sand. About 20% of MTBE cannot be removed. 相似文献
6.
研究电化学方法制备高铁酸钾,通过单因素实验确定最佳工艺条件为:电解液KOH浓度16 mol/L,电解时间为6 h,反应温度为65 ℃,阳极表观电流密度为50 A/m2,制得高铁酸钾的浓度可达5.72 mmol/L。对高铁酸钾强化电动修复技术去除土壤中的苯酚进行初探,结果表明该技术可以大幅度提高苯酚污染的修复效能,在反应120 h后,苯酚的去除率可达到90%以上,而且产生的Fe(OH)3固体无毒无害,不会对环境造成二次污染。 相似文献
7.
应用电化学法处理染料中间体生产排放的高盐度有机废水。考察了电极材料、电流密度、电解时间等因素对处理效果的影响。实验结果表明。该法能够有效地去除废水中的有机物，提高透明度，在电流密度0．015A／cm^2，槽电压8．4V，电解90min，CODcr和色度的去除率分别达到了65％和70％。本文亦对含盐染料配水进行了研究，对降解机理做了初步的探讨。 相似文献
8.
A Pr-doped TiO2-NTs/SnO2-Sb electrode was prepared by a simple method, cyclic voltammetry(CV). The methyl orange(MO)aqueous solution was selected as a simulated wastewater. The ordered microstructural TiO2-NTs substrate was synthesized by an electrochemical method to obtain large specific surface area and high space utilization. The phase structure, electrode surface morphology and electrochemical properties of electrodes were characterized by XRD, SEM and electrochemical technology, respectively. The results showed that praseodymium oxide was successfully doped into the SnO2-Sb film by CV method. Due to the doped Pr, the oxygen evolution potential increased from 2.25 V to 2.40 V. The degradation of MO was investigated by UV-vis. The C t /C 0 (φ) was studied as a function to obtain the optimal parameters, such as the amount of doped Pr, current density and initial dye concentration. In addition, the degradation process followed pseudo-first-order reaction kinetics and the rate constant was 0.099 3 min-1. The result indicated that the introduction of Pr reduced the formation of oxygen vacancies or enhanced the formation of adsorbed hydroxyl radical groups on the surface, thus leading to better activity and stability. 相似文献
9.
ZHANG Juan CHEN Xue-ming YAO Pei-dong CHEN Guo-hua 《浙江大学学报(A卷英文版)》2007,8(9):1457-1461
Boron-doped diamond （BDD） film electrodes using Ta as substrates were employed for anodic oxidation of salicylic acid （SA）. The effects of operational variables including initial concentration, current density, temperature and pH were examined. The results showed that BDD films deposited on the Ta substrates had high electrocatalytic activity for SA degradation. There was little effect ofpH on SA degradation. The current efficiency （CE） ,aas fbund to be dependent mainly on the initial SA concentration, current density and temperature. Chemical oxygen demand （COD） was reduced from 830 mg/L to 42 mg/L under a current density of200A/m^2 at 30℃. 相似文献
10.
Urban wastewater treatment techniques could not be applied to improve the pollutant removal efficiency,due to its characteristics of closed and quiescent conditions of the static lake water.In this study,natural zeolite and coal cinder were chosen as filler compounds of the ecological filter.Static and dynamic experiments were carried out to study the remediation efficiency.Experimental data show that removal efficiency of ammonia nitrogen （NH ＋ 4 -N） reaches 85% in both static and dynamic patterns and its removal efficiency reaches 97% when the recycling period is 1 h in dynamic condition.The maximum removal efficiency of nitrite nitrogen （NO-2 -N） reached 98%,and the removal efficiency of total nitrogen （TN） is a maximum of 84%.The final effluent concentration of total phosphorus （TP） is 0.079 mg/L.Effluent recycling could improve the nutrient （N,P） removal efficiently.Dissolved oxygen （DO） concentration could remain high with the water cycling.The filter works efficiently on regulating pH to the standard level of healthy water. 相似文献
11.
微生物燃料电池耦合人工湿地处理废水过程中的产电研究(英文) 总被引：2，自引：0，他引：2
构建了一种连续流无膜人工湿地-微生物燃料电池,其水力停留时间为 2 d. 系统以葡萄糖为基质启动2 ～ 3 d 后,在外接电阻为 1 kΩ时,其稳定输出电流密度高于 2 A /m3,同时,COD 去除率大于 90% . 比较了阴阳极间距为 10,20,30 和 40 cm 的系统. 当间距为 20 cm 时,系统的产电电压、库仑效率和能量密度皆最高,分别为 560 mV,0. 313% 和 0. 149 W /m3,且 COD 去除率也为最高,达到 94. 9%. 此外,各系统中的 DO最低浓度均出现在装置中部. 结果表明,COD 去除率越高,系统产能越高,因而库仑效率也越高. 人工湿地-微生物燃料电池系统作为一种低成本及环境友好的污水处理同步产电技术显示出实际应用潜力. 相似文献
12.
Lei Li Nai-yun Gao Yang Deng Juan-juan Yao Ke-jia Zhang Hai-jun Li Di-di Yin Hua-se Ou Jian-wei Guo 《浙江大学学报(A卷英文版)》2009,10(11):1660-1669
The degradation of Microcystin-LR （MC-LR） in water by hydrogen peroxide assisted ultraviolet （UV/H2O2） process was investigated in this paper. The UV/H2O2 process appeared to be effective in removal of the MC-LR. MC-LR decomposition was primarily ascribed to production of strong and nonselective oxidant-hydroxyl radicals within the system. The intensity of UV radiation, initial concentration of MC-LR, MC-LR purity, dosages of H2O2, the initial solution pH, and anions present in water, to some extent, influenced the degradation rate of MC-LR. A modified pseudo-first-order kinetic model was developed to predict the removal efficiency under different experimental conditions. 相似文献
13.
以实验室制备的羟基氧化铁（FeOOH）为催化剂催化臭氧氧化处理苯胺废水,对比催化臭氧氧化与单独臭氧降解苯胺的效率,实验结果表明,FeOOH催化臭氧氧化能加快对苯胺的降解速率,并且矿化程度高.说明FeOOH对臭氧氧化水中的苯胺具有明显的催化作用.探讨了氧气的进气流量、苯胺的初始浓度、水溶液的pH、催化剂的投加量等因素对催化氧化苯胺的影响.研究表明：氧气的进气流量为30L/h、初始浓度300mg/L时、pH值7.3、催化剂的投加量为2g/L、反应15min后,苯胺的去除率可达98.2%,COD的去除率可达70%.在催化体系中加入自由基捕获剂叔丁醇后,催化臭氧氧化反应明显受到抑制,间接证明了FeOOH催化臭氧氧化苯胺遵循自由基反应机理. 相似文献
14.
为了快速培养出能同时去除生活污水中化学需氧量(COD)和氮的微氧颗粒污泥,采用膨胀颗粒污泥床(EGSB)反应器接种污水处理厂剩余污泥,研究了微氧颗粒污泥的培养过程以及稳定运行条件下供氧量对处理效果和污泥性能的影响。结果表明,水力停留时间(HRT)为6h,微氧颗粒污泥的成功培养仅需1个月;供氧速率在2.83.2gO2/d,COD,NH3-N和总氮(TN)的去除率最高分别可达91%,85%和81%,脱氮速率达1.7gN/d,出水水质最佳;成熟的微氧颗粒污泥粒径集中在0.453.2gO2/d,COD,NH3-N和总氮(TN)的去除率最高分别可达91%,85%和81%,脱氮速率达1.7gN/d,出水水质最佳;成熟的微氧颗粒污泥粒径集中在0.452mm,当供氧速率低于2.3gO2/d时,颗粒污泥结构致密,供氧速率在2.32mm,当供氧速率低于2.3gO2/d时,颗粒污泥结构致密,供氧速率在2.33.2gO2/d时,污泥性能稳定,供氧速率增加到3.2gO2/d时,污泥沉降性能下降,并出现颗粒解体和丝状菌生长优势。 相似文献
15.
A novel fluidized electrochemical reactor that integrated advanced electrochemical oxidation with activated carbon (AC) fluidization in a single cell was developed to model pollutant p-nitrophenol (PNP) abatement. AC fluidization could enhance COD removal by 22%-30%. In such a combined process, synergetic effects on PNP and COD removal was found, with their removal rate being enhanced by 137.8% and 97.8%, respectively. AC could be electrochemically regenerated and reused, indicating the combined process would be promising for treatment of biorefractory organic pollutants. 相似文献
16.
A novel fluidized electrochemical reactor that integrated advanced electrochemical oxidation with activated carbon (AC) fluidization in a single cell was developed to model pollutant p-nitrophenol (PNP) abatement. AC fluidization could enhance COD removal by 22%-30%. In such a combined process, synergetic effects on PNP and COD removal was found, with their removal rate being enhanced by 137.8% and 97.8%, respectively. AC could be electrochemically regen erated and reused, indicating the combined process would be promising for treatment of biorefractory organic pollutants. 相似文献
17.
丙烯菊酯农药的微生物生物修复作用研究 总被引：3，自引：0，他引：3
通过富集驯化培养,获得了降解丙烯菊酯的混合微生物．研究结果表明,该混合微生物发挥最优降解力的温度是35℃,pH为7．0,培养时间为72h．丙烯菊酯降解速度和混合培养微生物生长速度对外加碳源有较强的依赖性．在培养液中添加1g／L葡萄糖时,72h丙烯菊酯去除率可达76％;而采用丙烯菊酯作为培养菌生长的唯一碳源、氮源和能源时,72h丙烯菊酯去除率为55％． 相似文献
18.
19.
A novel fluidized electrochemical reactor that integrated advanced electrochemical oxidation with activated carbon (AC) fluidization
in a single cell was developed to model pollutant p-nitrophenol (PNP) abatement. AC fluidization could enhance COD removal by 22%–30%. In such a combined process, synergetic
effects on PNP and COD removal was found, with their removal rate being enhanced by 137.8% and 97.8%, respectively. AC could
be electrochemically regenerated and reused, indicating the combined process would be promising for treatment of biorefractory
organic pollutants.
Project (No. 20306027) supported by the National Natural Science Foundation of China 相似文献
20.
使用消石灰与炼锗煤渣混合物作为PRB材料,进行原位处理铀水冶尾矿酸性渗滤水的可行性实验研究.研究显示了PRB材料中和酸性渗滤水的效果很好,单位立方厘米的比例分别为1∶3、1∶4、1∶6的消石灰与炼锗煤渣混合物可以中和pH值为2.94的渗滤水体积分别为2.23L、1.66L、1.34L;并且对U的去除有明显的效果,pH大于6时,穿透水中金属U的浓度都小于0.1mg/L;pH大于7时,则穿透水中金属U的浓度大部分小于0.05mg/L;实验过程中混合物的渗透性只有1∶3的降低,其它二种却没有影响.利用消石灰与炼锗煤渣混合物中和铀水冶尾矿酸性渗出水是可行的. 相似文献