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1.
Pan  Chengcheng  Song  Yang  Jin  Weixian  Qin  Zhenbo  Song  Shizhe  Hu  Wenbin  Xia  Da-Hai 《天津大学学报(英文版)》2020,26(2):135-141
The purpose of this work was to enhance the corrosion resistance of the passive film on 304 stainless steel(SS) by chemical modification in alkaline phosphate–molybdate solutions. The 304 SS was passivated in both phosphate and phosphate–molybdate mixed solutions to investigate the effect of molybdate on its corrosion resistance. The experimental results indicated that the passive film showed better corrosion resistance in Cl--containing solutions after modification in phosphate–molybdate solutions than in phosphate-only solutions. Energy-dispersive spectroscopy analyses revealed that the passive film formed in phosphate–molybdate solutions contained Mo and P after modification, which is the reason for the enhanced corrosion resistance.  相似文献   

2.
Slip and deformation of concrete sandwich panels under uniformly distributed loads is concerned. The effect of slip on the deformation of concrete sandwich panels are studied,and the analytical expressions of slip and deformation for concrete sandwich panels is obtained. These formulae can describe the slip distribution and account for its effect on deformation. In order to restrict the bound of formula, the formula of crack moment is obtained. The results of theoretical calculation are compared with those of tests and finite element methods. The comparison shows that the results of theoretical calculation are in accord with those of tests and finite element methods. So the theoretical calculation can be used to calculate slip and deformation of concrete sandwich panels in practical projects.  相似文献   

3.
In view of the present situation of low cavitation performance of deep-sea mining slurry pump, the effect of solid phase on the cavitation performance of deep-sea mining pump is analyzed theoretically. The relationship between gas and liquid phases are established by cavitation nucleon theory and mass energy equation as well as solid phase and liquid phase, and then we explored the relationship between gas phase and solid phase. The results show that the critical bubble radius and solid-phase concentration flow rate during the cavitation can be related to the liquid pressure. Eq. (19) show that the larger the solid particle concentration and the solid phase flow, the earlier the cavitation will occur, and pump anti-cavitation performance will decline.  相似文献   

4.
The nonlinear analysis of reinforced concrete rectangular slabs undermonotonic transverse loads is performed by finite element method.The layered rectangu-lar element with 4 nodes and 20 degrees of freedom is developed,in whichbending-stretching coupling effect is taken into account.An orthotropic equivalentuniaxial stress-strain constitutive model of concrete is used.A program is worked out andused to calculate two reinforced concrete slabs.The results of calculation are in goodconformity with the corresponding test results.In addition,the influence of tension stif-fening effect of cracked concrete on the results of calculation is discussed.  相似文献   

5.
Numerical method is popular in analysing the blast wave propagation and interaction with structures.However,because of the extremely short duration of blast wave and energy trans-mission between different grids,the numerical results are sensitive to the finite element mesh size.Previous numerical simulations show that a mesh size acceptable to one blast scenario might not be proper for another case,even though the difference between the two scenarios is very small,indicating a simple numerical mesh size convergence test might not be enough to guarantee accu-rate numerical results.Therefore,both coarse mesh and fine mesh were used in different blast scenarios to investigate the mesh size effect on numerical results of blast wave propagation and interaction with structures.Based on the numerical results and their comparison with field test re-sults and the design charts in TM5-1300,a numerical modification method was proposed to correct the influence of the mesh size on the simulated results.It can be easily used to improve the accu-racy of the numerical results of blast wave propagation and blast loads on structures.  相似文献   

6.
Nd-rich phase plays an important role in the magnetic properties of sintered NdFeB alloy. The proportion of Nd-rich phase to all the other phases was calculated by using MATLAB 6.5 software. Especially, post-sintered alloy, post-high-temperature tempered alloy and post-high and low-temperature tempered alloy were analyzed. It was found that the proportion of Nd-rich phase in the three alloys based on SEM (scanning electron microscope) images was about 8.22%, 8.03% and 8.00%, respectively.  相似文献   

7.
The mechanism involving the effect of disorder/order transformation on the environmental embrittlement in gaseous H2 is summarized. It is shown that there is no hydrogen embrittlement in disordered state of Kurnakov type intermetallics in gaseous H2. However, the H2-induced environmental embrittlement for the ordered alloy having identical chemical composition becomes severer as the degree of the order increases. The results of testing on the ion gage turned on and off during tensile testing show that the more sensitive to H2-induced hydrogen embrittlement for ordered alloy than disordered one is attributed to the fact that atomic ordering may accelerate the kinetics of the catalytic reaction to produce more atomic hydrogen. The results on simultaneous hydrogen charging show that disordered alloys embrittled as hydrogen atoms are forced into the material implying that the embrittlement of ordered alloy in gaseous H2 is also due to the acceleration of the kinetics of catalytic reaction. The above suggestion was further verified by the adsorption tests of Ni3Fe intermetallics powder. It is shown that the amount of chemically adsorbed hydrogen in ordered state is significantly larger than that adsorbed by the disordered alloy, indicating that the more sensitive to H2-induced embrittlement in the ordered state of alloy is essentially due to the accelerated catalytic reaction.  相似文献   

8.
The wide-shallow composite bucket foundation(WSCBF) is a new type of offshore wind power foundation that can be built on land and rapidly installed offshore, there by effectively reducing the construction time and costs of offshore wind power foundation. In this study, the horizontal bearing capacity is calculated by finite element simulation and compared with test results to verify the validity of results. In this process, the vertical load and bending load are respectively calculated by the finite element simulation. Under the vertical load effect, the bucket foundation and the soil inside are regarded as a whole, and the corresponding buckling failure mode is obtained. The ultimate vertical bearing capacity is calculated using empirical and theoretical formulas; the theoretical formula is also revised by finite element results. Under bending load, the rotational center of the composite bucket foundation(in a region close to the bucket bottom) gradually moves from the left of the central axis(reverse to loading direction) to the nearby compartment boards along the loading direction. The H–M envelope line shows a linear relationship, and it is determined that the vertical and bending ultimate bearing capacities can be improved by an appropriate vertical load.  相似文献   

9.
In this paper, numerical method is used to study the strain rate effect on masonry materials. A typical unit of masonry is selected to serve as a representative volume element (RVE). Numerical model of RVE is established with detailed distinctive modeling of brick and mortar with their respective dynamic material properties obtained from laboratory tests. The behavior of brick and mortar are characterized by a dynamic damage model that accounts for rate-sensitive and pressuredependent properties of masonry materials. Dynamic loads of different loading rates are applied to RVE. The equivalent homogenized uniaxial compressive strength, threshold strain and elastic modulus in three directions of the masonry are derived from the simulated responses of the RVE. The strain rate effect on the masonry material with clay brick and mortar, such as the dynamic increase factor (DIF) of the ultimate strength and elastic modulus as a function of strain rate are derived from the numerical results.  相似文献   

10.
The most dominant error source for microwave ranging is the frequency instability of the oscillator that generates the carrier phase signal. The oscillator noise is very difficult to filter due to its extremely low frequency. A dual transponder carrier ranging method can effectively minimize the oscillator noise by combing the reference phase and the to-and-fro measurement phase from the same single oscillator. This method does not require an accurate time tagging system, since it extracts phases on the same satellite. This paper analyzes the dual transponder carrier ranging system by simulation of the phase measurements with comprehensive error models. Both frequency domain and time domain noise transfer characteristics were simulated to compare them with dual one-way ranging. The simulation results in the two domains conformed to each other and demonstrated that a high level of accuracy can also be achieved by use of the dual transponder carder ranging system, with relatively simple instruments.  相似文献   

11.
基于L9(34)正交试验,本文对过共晶Al-20Si合金进行变质处理。通过直观和方差分析,确定最佳的变质工艺参数。结果表明:正交试验最佳的工艺参数为A2B2C1D2,变质工艺参数为0.04%的P添加量,0.6%的RE混合稀土添加量,20 min的变质时间以及780℃的变质温度,此时初生Si相转变为规则的六边形,平均尺寸为24.84μm,共晶硅相细化明显;因素A (P添加量)对变质效果有显著影响,B、C、D因素(分别为RE混合稀土添加量、变质时间和变质温度)对变质效果有一定的影响作用,各因素的影响程度分别为P添加量>RE混合稀土添加量>变质温度>变质时间。  相似文献   

12.
变质剂变质处理过共晶铝硅合金研究概况   总被引:1,自引:0,他引:1  
综述了变质剂变质处理对过共晶Al-Si合金组织与性能改善方面的研究概况。指出复合变质仍将是低硅过共晶铝硅合金性能改善的有效手段及发展趋势。  相似文献   

13.
借助SEM与XRD分析手段,对自制的AlTiCCeP(含2%P)中间合金进行物相分析,并以Al-30%Si合金为变质对象,探讨其对初晶硅的变质效果与变质机理。结果发现:AlTiCCeP中间合金组织中含有TiC、AlP、TiAl3和Ti2Al20Ce等物相,当AlTiCCeP的添加量(以磷的实际添加量计算)为Al-30%Si合金质量的0.15%时,对初晶硅变质效果显著,平均尺寸约为28μm,优于商用Cu-P中间合金。  相似文献   

14.
利用电弧炉熔炼法制备了LaFe11Co0.9Si1.1B0.2化合物.扫描电镜和能量色散谱仪分析得该化合物主相为NaZn13相,还含有少量的富镧相和富铁相.X-射线衍射仪测量发现,该化合物在居里温度附近的衍射峰随着温度的升高向大角度偏移,分析软件分析并计算得到该化合物在居里温度附近具有明显的负膨胀现象.  相似文献   

15.
UHV/CVD生长SiGe/Si材料分析及应用研究   总被引:1,自引:1,他引:0  
以Si2H6和GeH4为生长气源,采用UHV/CVD系统在Si(100)衬底上生长了Sil—xGex合金和Sil—xGex/Si多量子阱结构。采用X射线双晶衍射仪、扫描电子显微镜和原子力显微镜等仪器设备对样品的组份、界面和表面形貌等晶体质量进行了研究。SiGe合金中Si和Ge摩尔分数的比值随着Si2H6和GeH4流量比的增加按比例线性增加,比例因子为2.57。生长的Si0.88Ge0.12合金样品的界面清晰,表面平整,平均粗糙度仅为0.4nm,位错密度低于104/cm2。六周期Si0.88Ge0.12/Si多量子阱的X射线双晶衍射摇摆曲线中存在多级卫星峰和Pendellosung条纹。这些结果表明SiGe合金和SiGe/Si多量子阱均具有很好的晶体质量。  相似文献   

16.
利用金相显微技术和示差扫描量热法研究了合金成分对Ni-Fe-Ga铁磁形状记忆合金马氏体相变的影响,用X射线衍射方法分析了马氏体的结构类型.研究发现,Ni代替Fe显著提高合金的马氏体相变温度,每1%Ni可以使合金马氏体相变温度提高约40 K.X射线衍射表明Ni73.5-yFeyGa26.5合金773K真空退火后都只出现4M型晶体结构的马氏体.  相似文献   

17.
用光学显微镜和扫描电镜(SEM)观察Al-Si合金中硅相形貌在固溶过程中的变化, 并研究了此变化对合金力学性能和断裂行为的影响. 结果表明: 固溶初期 (250 min), 硅相发生缩颈、钝化、溶断并伴随长大; 在固溶中期(250~400 min), 其形貌没有发生显著变化, 仅球化程度更高; 600 min后, 硅相的长大是受扩散控制的粗化过程, 且符合LSW粗化模型; 同时由于出现棱角小面及搭接特征使硅相形貌有所恶化. 定量金相测量及回归分析说明硅相的形貌对合金的力学性能和断裂行为有显著影响.  相似文献   

18.
通过反应挤出制备了高密度聚乙烯/聚酰胺6/蒙脱土(HDPE/PA 6/MMT)复合材料,研究了MMT在HDPE/PA 6共混物中的分散和分布情况,及其对共混物相态结构的影响。从XRD和TEM的结果中可以看出,有机化蒙脱土(OMMT)选择性地分布在PA 6相内以及两相的界面上,钠基蒙脱土(Na+MMT)则主要分布在PA 6相内;大部分OMMT得到较好的剥离或插层,而Na+MMT出现明显的团聚。FE-SEM分析结果表明,增大MMT的含量会导致PA 6的相态尺寸变大,粒径分布变宽。流变分析结果表明,由于OMMT部分分布于两相界面处,从而增强了界面结合,对共混物起到了增容作用。  相似文献   

19.
通过添加过量的稀土元素La,得到La1.2Fe13-xSix系列化合物在1100摄氏度下短时间退火后形成稳定的Na Zn1 3型结构相。分析还表明该系列化合物在Si含量较少时,含有少量的α-Fe相和富镧相。磁性测量表明居里温度随着Si含量的增加由183K近线性的增加到214K,热滞随着Si含量的增加而减小。在各自的居里温度附近观察到由磁场引起的变磁转变特性,且随着Si含量的增加而减弱。磁熵变的最大值随着Si含量的增加而减少。  相似文献   

20.
低温胁迫下镧对水稻种子萌发的影响   总被引:3,自引:0,他引:3  
以水稻(Oryza sativa)种子为实验材料,研究了不同浓度稀土元素镧浸种对水稻种子低温萌发的影响。结果表明:15℃低温胁迫抑制水稻种子的萌发,浸种期用硝酸镧处理能够提高种子的抗逆性。低浓度((50~250)×10-6mol/L)硝酸镧浸种能提高水稻种子发芽率、发芽势、呼吸速率和过氧化氢酶活性,提高种子抗寒能力,实验发现用硝酸镧处理种子萌发以250×10-6mol/L浓度为最佳,低温胁迫下,发芽率提高9.67%,呼吸速率提高56.25%,过氧化氢酶活性提高1.73%。350×10-6mol/L以上高浓度对水稻种子的萌发无明显影响。  相似文献   

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