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1.
We studied the decomposition of two haloacetic acids （HAAs）, dichloroacetic acid （DCAA） and trichloroacetic acid （TCAA）, in water by single oxidants ozone （O3） and ultraviolet radiation （UV） and the advanced oxidation processes （AOPs） constituted by the combinations of O3/UV, H2O2/UV, O3/H2O2, and O3/H2O2/UV. The concentrations of HAAs were analyzed at specified time intervals to track their decomposition. Except for O3 and UV, the four combined oxidation processes remarkably enhance the decomposition of DCAA and TCAA owing to the generated very reactive hydroxyl radicals. The fastest decomposition process is O3/H2O2/UV, closely followed by O3/UV. DCAA is much easier to decompose than＇ TCAA. The kinetics of HAA decomposition by O3/UV can be described well by a pseudo first-order reaction model under a constant initial dissolved O3 concentration and fixed UV radiation. Humic acids and HCO3 in the reaction system both decrease the decomposition rate constants for DCAA and TCAA. The amount of H2O2 accumulates in the presence of humic acids in the O3/UV process.  相似文献   

2.
本研究采实验设计方式,初步筛选重要三卤甲烷（Trihalomethane,THM）形成控制参数,包括溴离子、加氯量/有机物、温度及反应时间,并配合净水厂实际操作状况,进行参数范围设定,再利用统计软件比较各参数对THM物种形成之影响。研究结果显示含氯较高之THM物种（氯仿及二氯-溴仿）,主要受溴离子及温度影响,其中溴离子属负效应,温度则属正效应,当低溴离子浓度存在时,其生成含氯较高之THM物种高于低溴离子浓度者。至于二溴-氯仿之形成主要受溴离子及温度影响,但两参数均属正效应。在溴仿形成之控制参数与另三种THM物种不同,主要受溴离子及加氯量/有机物含量影响,前者属正效应,后者则属负效应,当高溴离子浓度存在时,高加氯量/有机物之比值者,其生成之溴仿,小于低加氯量/有机物比值者。  相似文献   

3.
This paper presents a method to calibrate pipe roughness coefficient (i.e., Manning n-factor) with genetic algorithm (GA) under multiple loading conditions. Due to the old pipe age as well as deleting valves and blends in the skeleton of distribution network, most of the pipes in hydraulic model of practical water distribution system (WDS) are rough. The commonly used Hazen-Williams C-factor is therefore replaced by Manning n-factor in calibrating WDS hydraulic model. Adjustment to GA is designed, and the program efficiency is improved. A case study shows that the adjustment can save 60% of the total runtime. About 90% of the relative differences between simulated and observed pressures at monitoring locations are lower than 3%, which suggests that the proposed adjustment to the calibration is efficient and effective.  相似文献   

4.
The efficiency of chlorine and chloramines disinfection on biofilm development in a simulated drinking water distribution system was investigated by using heterotrophic bacterial spread plate technique. The experiments were carried out with four annular reactors （ARs） with stainless steel （SS） or copper （Cu） material slides. The results showed that there were fewer bacteria attached to Cu slides without a disinfectant compared with those attached to SS slides. When the water was disinfected with chloramines, the heterotrophic plate counts （HPCs） on the biofilm attached to the Cu slides were significantly lower （by 3.46 log CFU/cm^2） than those attached to the SS slides. Likewise, the biofilm HPC numbers on the Cu slides were slightly lower （by 1.19 log CFU/cm^2） than those on the SS slides disinfected with chlorine. In a quasi-steady state, the HPC levels on Cu slides can be reduced to 3.0 log CFU/cm^2 with chlorine and to about 0.9 log CFU/cm^2 with chloramines. The addition of chloramines resulted in a more efficient reduction of biofilm heterotrophic bacteria than did chlorine. We concluded that the chlorine and chloramines levels usually employed in water distribution system were not sufficient to prevent the growth and development of microbial biofilm. The combination of copper pipe slides and chloramines as the disinfectant was the most efficient combination to bring about diminished bacterial levels.  相似文献   

5.
当传统的3P词汇教学模式受到抨击后,新的词汇教学理念纷纷涌现,但高职学生并未因此而从如何记忆词汇的困惑中解放出来。笔者在多年的词汇教学中,通过研究学生课堂学习和自主学习词汇的过程和结果,总结出了一些适合高职学生的词汇教学方法。  相似文献   

6.
随着氯碱企业氯气干燥工艺的改进,设备和下游涉氯产品对水份要求的提高,,大部分氯碱厂液氯含水量都能达到400mg／L以下,有些厂能达到50mg／L以下。无水高氯酸镁是吸水性较强又不和氯气反应的干燥剂,气体通过高氯酸镁的剩余湿度低至O．0002mg／L,吸水后成为三水过氯酸镁,可用于液氯中微量水分的测定。  相似文献   

7.
Dried ground leaves ofPsidium guajava L. (guava) were extracted by water and aqueous ethyl alcohol 50% (1∶10) ratio, and the total phenolic content in the extracts was determined spectrophotometrically according to Folin-Ciocalteu's phenol method and calculated as gallic acid equivalent (GAE). Remarkably high total phenolic content 575.3±15.5 and 511.6±6.2 mg of GAE/g of dried weight material (for ethanol guava leaf extracts and water guava leaf extracts, respectively) were obtained. The antioxidant activity of lyophilized extracts was determined at ambient temperature by means of a 2,2-diphenyl-1-picrylhydryzyl (DPPH') colorimetry with detection scheme at 515 nm. The activity was evaluated by the decrease in absorbance as the result of DPPH' color change from purple to yellow. The higher the sample concentration used, the stronger was the free radical-scavenging effect. The results obtained showed that ascorbic acid was a substantially more powerful antioxidant than the extracts from guava leaf. On the other hand, the commercial guava leaf extracts and ethanol guava leaf extracts showed almost the same antioxidant power whereas water guava leaf extracts showed lower antioxidant activity. The parameter EC50 and the time needed to reach the steady state to EC50 concentration (T EC 50) affected the antiradical capacity of the sample. The antioxidant efficiency (AE) has been shown to be a more adequate parameter for selecting antioxidants than the widely used EC50. This study revealed that guava leaf extracts comprise effective potential source of natural antioxidants.  相似文献   

8.
为消除氯碱工业盐酸生产过程中游离氯超标带来的危害,提升盐酸生产质量,探讨盐酸中游离氯含量的控制及分析方法,并进行准确度、精密度试验。结果表明:合理控制氯氢压力波动、氯氢配比、喷射泵抽力等,可有效控制盐酸中游离氯的含量;运用碘量法分析游离氯的含量,简单快捷,重现性较好,能为工艺控制提供准确的参考依据。  相似文献   

9.
The formation of brominated trihalomethanes （THMs-Br） which is proved more carcinogenic than their chlorinated analogues reported was very different at various water qualities. This study was performed to assess the effects of water quality parameters （bromide concentration, pH value and ammonia concentration）, chlorination conditions （chlorine dose, reaction time） and ratios of Br^-/DOC and Br^-/Cl2 consumption on the formation and distribution of THMs-Br in chlorination. The results showed good correlation between the bromine incorporation factor （BIF） n（Br） and Br^-/Cl2 consumption ratio. The formation of total THM （TTHM） was found to＇ decrease with increasing ammonia concentration but to increase with bromide concentration and pH value. The n（Br） trends were significantly affected by the presence of bromide concentration. The effects on the molar yields of THMs were more strongly influenced by bromide concentration and dissolved organic carbon （DOC） concentration than pH value and natural organic matter （NOM） source. High Br^-/DOC and Br^-/Cl2 favor the formation of THMs-Br over chlorinated THMs （THMs-Cl）. The experimental data including the main parameters such as bromide, DOC, ammonia, pH and reaction time were used for developing the predictive model for THMs-Br.  相似文献   

10.
The differential evolution (DE) algorithm has been received increasing attention in terms of optimizing the design for the water distribution systems (WDSs). This paper aims to carry out a comprehensive performance comparison between the new emerged DE algorithm and the most popular algorithm??the genetic algorithm (GA). A total of six benchmark WDS case studies were used with the number of decision variables ranging from 8 to 454. A preliminary sensitivity analysis was performed to select the most effective parameter values for both algorithms to enable the fair comparison. It is observed from the results that the DE algorithm consistently outperforms the GA in terms of both efficiency and the solution quality for each case study. Additionally, the DE algorithm was also compared with the previously published optimization algorithms based on the results for those six case studies, indicating that the DE exhibits comparable performance with other algorithms. It can be concluded that the DE is a newly promising optimization algorithm in the design of WDSs.  相似文献   

11.
Removal of cyclops in pre-oxidizing cooperation water treatment process   总被引：1，自引：0，他引：1  
Zooplankton cyclops propagates profusely in waterbody, cannot be effectively inactivated by conventional disinfec- tion process, and becomes a troublesome drinking water treatment problem. In this work, the qualitative and quantitative ex- perimental studies were carried out on inactivation of zooplankton cyclops using oxidants, such as chlorine (Cl2), chlorine dioxide (ClO2), ozone (O3), hydrogen peroxide (H2O2), ozone/hydrogen peroxide (O3/H2O2), chloramines (Cl2-NH3) and potassium permanganate (KMnO4). The influences of various factors include different oxidant dosages, organic substance contents and pH values. The results showed that currently available oxidants used all might inactivate cyclops in some extent. According to the experimental results, chlorine dioxide, ozone, ozone/hydrogen peroxide and chloramines can be selected as effective oxidants for inactivating cyclops because of their strong inactivation abilities. Then the synergic removal effects on cyclops with ozone, ozone/hydrogen peroxide pre-oxidation followed by conventional water treatment processes were investigated. The results showed that ozone and ozone/hydrogen peroxide pre-oxidation can inactivate cyclops effectively, which then can be removed thoroughly by conventional water treatment processes. Cyclops cannot appear in water after filtration with 1.65 mg/L of ozone and 6 mg/L of hydrogen peroxide, with the inactivation rate being 62% before conventional water treatment processes. Cyclops cannot appear in water after filtration with 1.8 mg/L of ozone, with the inactivation rate being 50% before conventional water treatment processes. For different oxidants, when removal rate was the best, the inactivation rate was not the same. These results may pro- vide reference and model for actual waterworks.  相似文献   

12.
研究目的：在生产高度集约化体系下,研究节水灌溉措施及锌肥对水稻产量及锌积累量的影响。创新要点：目前关于干湿交替能否对水稻增产仍存在争议,对锌含量及生物有效性也鲜有报道。因此,针对这些问题,本文系统地研究影响水稻产量及品质的两大限制性因素,即锌肥和灌溉方式对稻米锌生物有效性的影响。研究方法：采用盆钵试验模拟大田锌肥及水分管理方式,两种基因型、两种锌肥种类、两种水分管理,三个重复控制误差。利用电感耦合等离子体质谱（ICP-MS）测定微量元素锌含量,以精米中植酸含量表征锌生物有效性。重要结论：干湿交替在增加了稻米产量、锌含量及积累量方面效果显著。干湿交替结合土施硫酸锌肥可以作为水稻生产体系中获得高产、高锌、高生物有效性的农艺措施。  相似文献   

13.
Objective:To investigate the amounts of extractable organic nitrogen(EON),and the relationships between EON and total extractable nitrogen(TEN),especially the amino acids(AAs) adsorbed by soils,and a series of other hydrolyzed soil nitrogen indices in typical land use soil types from southeast China.Under traditional agricultural planting conditions,the functions of EON,especially AAs in the rhizosphere and in bulk soil zones were also investigated.Methods:Pot experiments were conducted using plants of pakchoi(Brassica chinensis L.) and rice(Oryza sativa L.).In the rhizosphere and bulk soil zone studies,organic nitrogen components were extracted with either distilled water,0.5 mol/L K2SO4or acid hydrolysis.Results:K2SO4-EON constituted more than 30% of TEN pools.K2SO4-extractable AAs accounted for 25% of EON pools and nearly 10% of TEN pools in rhizosphere soils.Overall,both K2SO4-EON and extractable AAs contents had positive correlations with TEN pools.Conclusions:EON represented a major component of TEN pools in garden and paddy soils under traditional planting conditions.Although only a small proportion of the EON was present in the form of water-extractable and K2SO4-extractable AAs,the release of AAs from soil exchangeable sites might be an important source of organic nitrogen(N) for plant growth.Our findings suggest that the content of most organic forms of N was significantly greater in rhizosphere than in bulk soil zone samples.However,it was also apparent that the TEN pool content was lower in rhizosphere than in bulk soil samples without added N.  相似文献   

14.
Orthogonal method was adopted to optimize the preozonation process and to minimize the bromate formation. Factors such as contact time, pH and ammonia concentration were investigated by orthogonal experiments to understand the interaction of various operation conditions on the formation of bromate and other disinfection byproducts （DBPs）. Results showed that pH had the most significant influence on the minimization of bromate formation. The factors influencing the formation ofbromate were in order ofpH 〉 contact time 〉 ammonia concentration. For the formation of trihalomethanes （THMs） and haloacetic acids （HAAs）, however, contact time significantly influenced their formation potential. In the practical preozonation process of waterworks, it is appropriate to set preozonation contact time to be 20 min. In order to minimize the formation of bromate, pH value of the raw water should be adjusted to 6.0, and a certain concentration of ammonia could be added into the water to strengthen the minimization effect when the concentration of bromide in the raw water is higher than that in the experimental water.  相似文献   

15.
Visual dynamic simulation and optimization of Zhangjiuhe diversion project   总被引：1，自引：0，他引：1  
With the aim of visualizing the real-time simulation calculation of water delivery system (WDS), a structural drawing-oriented (SDO) simulation technique was presented, and applied to Zhangjiuhe Diversion Project, which is a long-distance water delivery system constructed for drawing water from the Zhangjiuhe River to Kunming city. Taking SIMULINK software as simulating platform, the technique established a visual dynamic simulation model for the system. The simulation procedure of the system was simplified, and the efficiency of modeling was also enhanced according to the modularization and reutilization of the simulation program. Furthermore, a selfoptimization model was presented. Based on the digital simulation models, the on line controlled optimization link was added, and the input data can be continually optimized according to the feedback information of simulating output. The system was thus optimized automatically. Built upon MATLAB software, simulation optimization of the Zhangjiuhe Diversion Project was achieved, which provides a new way for the research of optimal operation of WDS.  相似文献   

16.
The changes of kernel nutritive components and seed vigor in F1 seeds of sh 2 sweet corn during seed development stage were investigated and the relationships between them were analyzed by time series regression (TSR) analysis. The results show that total soluble sugar and reducing sugar contents gradually declined, while starch and soluble protein contents increased throughout the seed development stages. Germination percentage, energy of germination, germination index and vigor index gradually increased along with seed development and reached the highest levels at 38 d after pollination (DAP). The TSR showed that, during 14 to 42 DAP, total soluble sugar content was independent of the vigor parameters determined in present experiment, while the reducing sugar content had a significant effect on seed vigor. TSR equations between seed reducing sugar and seed vigor were also developed. There were negative correlations between the seed reducing sugar content and the germination percentage, energy of germination, germination index and vigor index, respectively. It is suggested that the seed germination, energy of germination, germination index and vigor index could be predicted by the content of reducing sugar in sweet corn seeds during seed development stages. Project supported by the National Natural Science Foundation of China (No. 30370911) and Education Department of Zhejiang Province, China (No. 20070147)  相似文献   

17.
A two-stage method is developed to solve a new class of multi-storage tank multi-source （MTMS） systems. In the first stage, the optimal storage policy of each tank is determined according to the electricity tariff, and the ground-level storage tank is modeled as a node. In the second stage, the genetic algorithm, combined with a repairing scheme, is applied to solve the pump scheduling problem. The objective of the pump scheduling problem is to ensure that the required volume is adequately provided by the pumps while minimizing the operation cost （energy cost and treatment cost）. The decision variables are the settings of the pumps and speed ratio of variable-speed pumps at time steps of the total operational time horizon. A mixed coding methodology is developed according to the characteristics of the decision variables. Daily operation cost savings of approximately 11% are obtained by application of the proposed method to a pressure zone of S. Y. water distribution system （WDS）, China.  相似文献   

18.
We evaluated several different pre-oxidation treatments, namely the introduction of either potassium permanganate （KMnO4）, chlorine （Cl2）, or both to remove manganese （Mn） from the Qiantang River source water. Our results showed that Mn removal percentages were 12.7%, 71.0%, 17.4% and 58.7% when none of the oxidants, KMnO4 only, Cl2 only, or both oxidants were added, respectively. Furthermore, a field study showed that when the available Mn concentration in the source water was 0.14 mg/L, it could be reduced to less than 0.05 mg/L when a solution of KMnO4 （0.47 mg/L） was added as the oxidant.  相似文献   

19.
BaFe12O19 powders with nanocrystaUine sizes were produced by sol-gel auto-combustion method. The precursors were prepared under the molar ratios of citric acid to the metal nitrate of 0.5, 1.0 and 1.5. Appropriate ethylene diamine （C2H8N2） was added in order to adjust pH of 7. The ions distribution of citric acid at different pH explains the effect of citric acid in the starting solution. The XRD patterns of the as-burnt powders and annealing powders show different phases for different citric acid content. In addition, the lattice constants （a, c） derived from X-ray diffraction pattern were changed from 0.58881 nm to 0.58997 nm and 2.32057 nm to 2.32296 nm respectively. The data from VSM indicated that the powder with high citric acid content took on good magnetic properties. Pure single BaFe12O19 of the specific maximum magnetization M（1 T）≈ 49.73 Am^2/kg, the specific remanent magnetization Mr ≈ 30.77 Am^2/kg and the coercive force He≈ 467 kA/m was produced when the molar ratios of citric acid to the metal nitrate was 1.5.  相似文献   

20.
原油中的氯分为有机氯和无机氯两种形态。在原油加工过程中,原油中的无机氯和有机氯水解生成大量的HCl,在水存在时具有强腐蚀性,它给加工装置的防腐蚀工作和安全生产带来了很大的压力。文章针对常减压蒸馏装置塔顶氯离子偏高的实际问题,对试用TLV-1原油氯转移剂的过程进行分析,对试验效果进行总结和讨论。  相似文献   

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