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1.
An experimental and model-based study of the effect of rich air/fuel ratios (AFRs) and temperature on the NOx slip of a lean NOx trap (LNT) was conducted in a lean-burn gasoline engine with an LNT after-treatment system. The emissions of the engine test bench and the inlet temperature of the LNT were used as the major inlet boundary conditions of the LNT. The engine periodically operated between a constant lean AFR of 23 with alterable rich AFRs of 10, 11, 12, 13, and 14. A decrease in the rich AFR of the engine strengthened the desorption atmosphere in the LNT, an effect closely related to the number of reductants, and further heightened the NOx desorption of the LNT, but with a penalty in fuel consumption. To eliminate that penalty, the inlet boundary conditions of the LNT were varied by adjusting the inlet temperature within a range between 200 ℃ and 400℃. An increase in inlet temperature heightened the NOx desorption of the LNT, and a NOx breakthrough occurred after the inlet tem- perature exceeded 390 ℃. To control NOx breakthrough, the inlet temperature can be adjusted to offset the strong desorption atmosphere in the LNT commonly created by a rich AFR.  相似文献   

2.
In this study, a porous inserted regenerative thermal oxidizer (PRTO) system was developed for a 125 kW industrial copper-melting furnace, due to its advantages of low NOr emissions and high radiant efficiency. Zirconium dioxide (ZrOz) ce- ramic foams were placed into the combustion zone of a regenerative thermal oxidizer (RTO). Different performance characteris- tics of the RTO and PRTO systems, including pressure drop, temperature distribution, emissions, and energy efficiency, were evaluated to study the effects of the porous inserts on non-premixed CH4 combustion. It was found that the PRTO system achieved a significant reduction in the NOx emission level and a fuel saving of approximately 30% compared to the RTO system. It is most suitable for a lean combustion process at an equivalence ratio 〈0.4 with NOx and CO emission levels within 0.002%~).003% and 0.001%q3.002%, respectively.  相似文献   

3.
This paper presents a method using a large steady-state engine operation data matrix to provide necessary information for successfully training a predictive network, while at the same time eliminating errors produced by the dispersive effects of the emissions measurement system. The steady-state training conditions of compound fuel allow for the correlation of time-averaged in-cylinder combustion variables to the engine-out NO x and HC emissions. The error back-propagation neural network (EBP) is then capable of learning the relationships between these variables and the measured gaseous emissions, and then interpolating between steady-state points in the matrix. This method for NO x method for NO x and HC has been proved highly successful.  相似文献   

4.
研究目的:预测机动车保有量;根据机动车污染特征,预测机动车污染物排放量;评估不同管理措施下机动车污染物的削减效果。创新要点:综合不同管理措施,整合评价多种管理措施并行条件下,机动车污染物排放量的削减情况。研究方法:通过长期能源替代计划(LEAP)模型对机动车保有量进行预测,相关排放因子采用校正的能源替代(AER)模型进行估算。最后设计四个情景模式,评估不同情景的减排效果,并与基础情景进行对比。重要结论:1.至2015年杭州市机动车将增长60.7%。2.淘汰超标机动车和提高机动车污染排放标准能有效控制CO和VOCs,而对NOx和PM的总量削减效果不明显。3.采用多种控制手段,如淘汰劣化超标机动车、提高机动车排放标准、提供低硫代燃油及引进能源替换型机动车将大大减少机动车污染物的排放量。  相似文献   

5.
研究目的:建立2000-2020年中国氮氧化物排放清单,了解中国主要行业和省份氮氧化物的排放情况,为评估氮氧化物的环境影响和制定相关减排政策提供依据。创新要点:分析了中国主要省份产业结构对氮氧化物排放量的影响;根据不同情景分析,预测2020年中国氮氧化物的排放量。研究方法:1.基于自底向上法,根据不同类型化石燃料的氮氧化物排放因子,结合化石燃料消耗量,建立中国2000-2010年氮氧化物排放清单;2.基于IPAT方程,并以中国2000--2010年的国内生产总值增长数据和氮氧化物排放量为依据,分三种情景,分析2011-2020年中国能源消耗和氮氧化物排放趋势。重要结论:2010年中国氮氧化物的排放量约是2000年的两倍:自2009年起,中国氮氧化物总排放量超过,二氧化硫总排放量;主要由于产业结构和地区生产总值的不同,中国东部和西部氮氧化物排放量有明显差异;制造业、电力行业和交通运输业是中国氮氧化物的主要排放源,其中交通运输业氮氧化物排放量呈现逐年增长趋势;预计2020年中国氮氧化物排放量为19.7Mt。  相似文献   

6.
By the application of life cycle assessment(LCA) methodology, this paper estimates the environmental impacts of production and disposal of traction motors used in electric vehicles in China. The results show that the total energy use, the criteria emissions and the greenhouse gases(GHG) emissions of a traction motor production and disposal are about 2,899,MJ, 4.5,kg and 259.5,kg per motor, respectively. Among the regulated emissions, the SOxemission ranks first by total mass, followed by CO, PM10, NOx, PM2.5, and volatile organic compound(VOC). The motor material production stage accounts for most of the energy consumption and emissions, followed by the assembly stage and the end-of-life disposal stage. In this study, the environmental performance analysis is extended to the comparison between the use of secondary material and primary material for the material production stage. It is found that using 100% secondary material results in a 52.9% reduction in energy consumption, a 49.8% reduction in regulated emissions, and a 49.3% reduction in GHG emissions compared with the use of 100% primary material.  相似文献   

7.
In iron ore sintering, the granulation process is the first and an important step. As the fine particles adhere to the coarse coke particles, the NO x emission generated from coke combustion may be expected to be influenced by that adhering layer. In this study, the granule size distributions and adhering ratios were evaluated by a granulation model. Granulation experiments were also carried out to obtain the granule size distribution and adhering ratio. The influence of the adhering layer on NO x emissions from the combustion of S type granules was studied by tube furnace experiments. Conclusions include: (1) The adhering ratio predicted from the granulation model can be used as a qualitative index for the evaluation of NO x emission from coke combustion. (2) The influence of the adhering layer on NO x emissions was enhanced with increasing adhering layer thickness of S type granules, and the NO x reduction was enhanced at higher temperatures (around 1373 K), but weakened at lower temperatures (around 1173 K).  相似文献   

8.
In order to investigate the effects of methyl ester moiety on polycyclic aromatic hydrocarbons (PAHs) and NO x formation in biodiesel combustion, the combined models were developed based on detailed methyl butanoate (MB) oxidation model and n-butane model. Also, PAHs detailed reaction mechanism and NO x formation mechanism were added to the detailed models to form the combined models. The combined models were used to compare the combustion of n-butane and MB in a shock tube simulation to understand the effects of methyl ester moiety. The results indicated that compared with n-butane, the methyl ester moiety in MB leads to different reaction pathways, more CO and CO 2 formation and less formation of PAHs precursors such as ethylene and acetylene. In addition, a better chemical insight into the effects of methyl ester moiety on NO x formation was given, which will help to understand the combustion process of biodiesel.  相似文献   

9.
Optimizing the operation of coal-fired power plants to reduce nitrogen oxide (NO x ) emissions requires accurate modeling of the NO x emission process. The careful selection of input parameters not only forms the basis of accurate modeling, but can also be used to reduce the complexity of the model. The present study employs the least squares support vector machine-supervised learning method to model NO x emissions based on historical real time data obtained from a 1000-MW once-through boiler. The initial input parameters are determined by expert knowledge and operational experience, while the final input parameters are obtained by sensitivity analysis, where the variation in model accuracy for a given set of data is analyzed as one or several input parameters are successively omitted from the calculations, while retaining all other parameters. Here, model accuracy is evaluated according to the mean relative error (MRE). This process reduces the parameters required for NO x emission modeling from an initial number of 33 to 7, while the corresponding MRE is reduced from 3.09% to 2.23%. Moreover, a correlation of 0.9566 between predicted and measured values was obtained by applying the model with just these seven input parameters to a validation dataset. As such, the proposed method for selecting input parameters serves as a reference for related studies.  相似文献   

10.
Aiming to reduce fuel consumption and emissions of a dual-clutch hybrid electric vehicle during cold start, multi- objective optimization for fuel consumption and HC/CO emission from a TWC (three-way catalytic converter) outlet is presented in this paper. DP (dynamic programming) considering dual-state variables is proposed based on the Belhnan optimality principle. Both the battery SOC (state of charge) and the temperature of TWC monolith are considered in the algorithm simultaneously. In this way the global optimal control strategy and the Pareto optimal solution of multi-objective function are derived. Simulation results show that the proposed method is able to promote the TWC light-off significantly by decreasing the engine's load and improving exhaust temperature from the outlet of the engine, in comparison with original DP considering the single battery SOC. Compared to the results achieved by rule-based control strategy, fuel economy and emission of TWC outlet for cold start are optimized comprehensively. Each indicator of Pareto solution set shows the significant improvement.  相似文献   

11.
研究目的:为改善实际工程结构在不确定性条件下的多性能指标,提供一种高效的区间多目标优化方法。创新要点:建立一个目标和约束均为区间不确定性参数函数的区间约束多目标优化模型,提出并实现基于径向基函数、区间分析和非支配排序遗传算法(NSGA-II)的区间多目标优化算法。研究方法:首先,利用区间序关系将每个区间目标转换为同时优化其中点和半径的确定性双目标,利用区间可能度法将区间约束转换为确定性约束,并在此基础上,利用加权法和罚函数法将每个区间目标的约束优化问题转换为相应的无约束优化问题;然后,利用拉丁超立方实验设计和有限元分析构建预测各待优化结构性能指标值的径向基函数;最后,将径向基函数、区间分析法与NSGA-II相结合,快速求出转换后确定性无约束多目标优化问题的所有Pareto最优解,并通过考虑材料不确定性的高速压力机滑块机构设计实例验证该方法的有效性。重要结论:目标和约束均为不确定性参数函数的区间多目标优化模型能有效反映实际工程中同时改善结构多性能指标的需求。基于径向基函数、区间分析和NSGA-II相结合的区间多目标优化算法将传统区间优化模型求解中的嵌套优化过程简化为单层遗传优化过程,大大提高了求解效率,并可获得多目标优化问题的所有Pareto最优解。  相似文献   

12.
LNG发动机与传统柴油发动机公交大巴道路排放对比研究   总被引:1,自引:0,他引:1  
利用GPS和BOSCH尾气分析仪,对深圳市传统柴油发动机公交大巴和LNG发动机的公交大巴分别进行实际行驶工况下的排放测试,通过分析,LNG公交大巴相对于传统柴油发动机公交大巴在颗粒物具有明显的优势,但LNG公交大巴的HC排放值平均为125×10-6,高于传统柴油发动机公交大巴的HC排放值,NOx排放值也明显高于传统柴油发动机公交大巴,因此需要重点减少LNG公交大巴的HC和NOx排放.  相似文献   

13.
Solid oxide fuel cells(SOFCs) offer high energy conversion,low noise,low pollutant emission,and low processing cost.Despite many advantages,SOFCs face a major challenge in competing with other types of fuel cells because of their high operating temperature.The necessity to reduce the operational temperature of SOFCs has led to the development of research into the materials and fabrication technology of fuel cells.The use of composite cathodes significantly reduces the cathode polarization resistance and expands the triple phase boundary area available for oxygen reduction.Powder preparation and composite cathode fabrication also affect the overall performance of composite cathodes and fuel cells.Among many types of cathode materials,lanthanum-based materials such as lanthanum strontium cobalt ferrite(La1-xSrxCo1-yFeyO3- have recently been discovered to offer great compatibility with ceria-based electrolytes in performing as composite cathode materials for intermediate-to low-temperature SOFCs(IT-LTSOFCs).This paper reviews various ceria-based composite cathodes for IT-LTSOFCs and focuses on the aspects of progress and challenges in materials technology.  相似文献   

14.
研究目的:比较牛血清蛋白和腐殖酸对Al2O3、SiO2和TiO2三种纳米颗粒团聚与沉降行为的影响,并讨论其影响机制。创新要点:纳米颗粒团聚物直径的增大能引起其沉降速度的加快,但小的水动力学直径并不一定导致低的沉降速度,说明团聚直径不是决定纳米颗粒沉降的唯一因素。研究方法:通过透射电镜观察纳米颗粒团聚物的形态;采用动态光散射技术研究纳米颗粒的团聚动力学;最后通过测量悬浊液的光学吸收来研究纳米颗粒的沉降动力学。重要结论:牛血清蛋白处理降低了三种纳米颗粒在NaCl和CaCl2中的水动力学直径,原因是牛血清蛋白的球状结构能够引起颗粒间的空间位阻斥力。腐殖酸处理导致纳米颗粒的水动力学直径在NaCl中最小,而在CaCl2中最大(图4),原因是腐殖酸能通过钙的配位作用彼此连接,从而促进了纳米颗粒的团聚。牛血清蛋白减缓了纳米颗粒的沉降;然而腐殖酸在CaCl2中明显加大了纳米颗粒的沉降速度(图5),与其水动力学直径的增大一致。腐殖酸处理的纳米颗粒在NaCl中水动力学直径最小,但沉降速度却不是最低。  相似文献   

15.
INTRODUCTION On-road vehicles are responsible for a signifi-cant and rapidly increasing portion of the air pollution in the urban areas of China due to rapid growth of motor vehicle population. The State Environmental Protection Administration (SEPA) of China has identified motor vehicles emissions as the major source of urban air pollution in China (SEPA, 2004). As of 2004, on-road vehicles were estimated to con-tribute over 50% of the nitrogen oxides (NOx) to large city’s emissi…  相似文献   

16.
Experimental study on homogeneous charge compression ignition (HCCI) combustion process was carried out on a single-cylinder direct injection diesel engine fueled with dimethyl ether(DME). The influence of inert gas CO2 on the ignition and combustion process was investigated. The research results indicate that because of the high cetanc number of DME, the stable HCCI operating range is quite narrow while the engine has a high compression ratio. The HCCI operating range can be largely extended when the inert gas is inducted into the charging air. HCCI combustion of DME presents remarkable characteristic of two-stage combustion process. As the concentration of inert gas increases, the ignition timing of the first combustion stage delays,the peak heat release rate decreases, and the combustion duration extends. Inducting inert gas into charging air cannot make the combustion and heat release of DME occur at a perfect crank angle position. Therefore, to obtain HCCI operation for the fuel with high cetane number,other methods such as reducing engine compression ratio should be adopted. Emission results show that under HCCI operation, a nearly zero NOx emission can be obtained with no smoke emissions. But the HC and CO emissions are high, and beth rise with the increase of the concentration of inert gases.  相似文献   

17.
This work investigates the effects of exhaust gas recirculation (EGR) and operation parameters including engine speed, equivalence ratio, coolant-out temperature, and intake charge temperature on the basic characteristics of a single-cylinder homogeneous charge compression ignition (HCCI) engine powered with reformulated iso-octane fuels. The running range of iso-octane HCCI engine can be expanded to lower temperature and more load by adding di-tertiary butyl peroxide (DTBP) in the fuel. The combustion timing advances with the increase of DTBP concentrations, coolant temperature and equivalence ratio. The effects of EGR on the combustion and emissions are remarkable when the EGR rate is higher than 25%, and the combustion phase is sharply postponed and the UHC and CO emissions deteriorate. The intake charge temperature has a moderate effect on combustion and emissions when it is lower than 35°C; but the combustion timing advances, the combustion duration shortens, and sometimes it leads to knock combustion when the intake charge temperature increases to above 35°C.  相似文献   

18.
Air pollution has become the predominant environmental problem caused by rapid industrialization and urbanization in China. In this study, measurements of the concentrations of PM2.5, PM10, SO2, NO2, CO, and O3 at six monitoring stations in Baotou, China were used to investigate the characteristics of heavy haze pollution in Dec. 12–25, 2013. Source locations of PM2.5 in Baotou were identified using satellite remote sensing data, an air mass trajectory model, and a conditional probability function (CPF). The results showed that the average concentrations of PM2.5 and PM10 were (113.8±84.0) μg/m3 and (211.1±149.2) μg/m3, respectively. The similar trends in temporal variation of the air pollutants PM2.5, PM10, SO2, NO2, and CO suggested they may share common sources. The results of satellite observations and backward trajectories supported the hypothesis that the pollutants causing the haze event originated mainly from local anthropogenic sources. According to the CPF analysis, low-speed winds from the south and southwest, upwind industrial emissions, and the northern mountains were mainly responsible for the formation of haze in Baotou. The study provides some insights to help governments optimize industrial layouts for improving air quality in the future.  相似文献   

19.
研究目的:二氧化钛(TiO2)纳米颗粒已经广泛应用于化妆品、防晒霜、涂料和牙膏等。这些纳米颗粒性质非常稳定,能在废水和生物固体中转移和分散。现有研究表明,TiO2纳米颗粒对动物正常生理活动具有毒性等负面作用。但是,它们对植物是否具有毒性特别是是否会产生植物基因毒性至今尚不清楚。因此,本文使用随机扩增多态性DNA技术研究TiO2纳米颗粒是否对西葫芦具有基因毒性,为TiO2纳米颗粒排放进入环境后的潜在植物毒性风险评价提供依据。 创新要点:首次发现了TiO2纳米颗粒对西葫芦具有基因毒性。 重要结论:采用随机扩增多态性DNA技术,发现TiO2纳米颗粒污染处理的西葫芦样品与未处理样品的基因组DNA图谱相比,不仅在谱带强度有明显差异,而且存在谱带消失和新谱带产生现象,表明TiO2纳米颗粒对西葫芦具有基因毒性。  相似文献   

20.
Thin-walled spread foundations are used in coastal projects where the soil strength is relatively low. Developing a predictive model of bearing capacity for this kind of foundation is of interest due to the fact that the famous bearing capacity equations are proposed for conventional footings. Many studies underlined the applicability of artificial neural networks (ANNs) in predicting the bearing capacity of foundations. However, the majority of these models are built using conventional ANNs, which suffer from slow rate of learning as well as getting trapped in local minima. Moreover, they are mainly developed for conventional footings. The prime objective of this study is to propose an improved ANN-based predictive model of bearing capacity for thin-walled shallow foundations. In this regard, a relatively large dataset comprising 145 recorded cases of related footing load tests was compiled from the literature. The dataset includes bearing capacity (Qu), friction angle, unit weight of sand, footing width, and thin-wall length to footing width ratio (Lw/B). Apart from Qu, other parameters were set as model inputs. To enhance the diversity of the data, four more related laboratory footing load tests were conducted on the Johor Bahru sand, and results were added to the dataset. Experimental findings suggest an almost 0.5 times increase in the bearing capacity in loose and dense sands when Lw/B is increased from 0.5 to 1.12. Overall, findings show the feasibility of the ANN-based predictive model improved with particle swarm optimization (PSO). The correlation coefficient was 0.98 for testing data, suggesting that the model serves as a reliable tool in predicting the bearing capacity.  相似文献   

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