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1.
采用电弧熔炼的方法制备了Dy（Co1-xMnx）2系列合金,并对其磁性和相变进行了研究.随着Mn含量的增加,晶格常数逐渐增大,同时居里温度逐渐提高.Mn的加入使相变类型从一级相变变为二级相变、使磁熵变大小有所降低.研究结果表明该系列合金在磁制冷领域有潜在应用价值. 相似文献
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《常熟理工学院学报》2016,(4)
采用电弧炉熔炼的方法制备了Mn_(50)Ni_(41-x)Cr_xSn_9合金铸锭.用X射线衍射、振动样品磁强计、综合物性测试系统对材料的结构、相变和磁热效应进行了研究.结果表明,由于价电子浓度的减小,Cr替代Ni使材料的马氏体转变温度降低.Cr的加入使马氏体转变伴随着较大的磁化强度的突变,从而表现出较大的低场磁熵变.Mn_(50)Ni_(41-x)Cr_xSn_9合金以其较大的低场磁热效应、可调的工作温区在磁制冷领域有着潜在的应用. 相似文献
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研究了Mn掺杂对Er(Co1-xMnx)2合金的晶体结构、相变类型和磁热效应的影响.随着Mn含量的增加,合金的晶体结构不变,但是晶格常数逐渐增加,同时居里温度逐渐升高.当x≤0.06时,样品的磁相变为一级相变,表现出较大的磁熵变;而x=0.08时,样品经历铁磁到顺磁的二级相变,磁热效应大大降低.在一级相变和二级相变的临界点x=0.06,样品具有较大的磁熵变,几乎没有磁滞现象.因此,将相变调控到一级相变和二级相变的临界点是优化磁热效应的一种有效方法. 相似文献
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采用电弧熔炼的方法制备了Mn_(50-x)Co_xNi_(40)Sn_(10)(x=0,2,4,6)材料的合金铸锭.用X射线衍射表征样品的晶体结构,用MPMS-3磁性测量系统测量样品的相变和磁热效应.结果表明,Co替代Mn导致马氏体转变温度升高,这是由于Co原子的价电子数多于Mn原子导致的.所有样品在马氏体转变伴随着较大的磁化强度的突变,从而表现出较大的低场磁熵变.Mn_(50-x)Co_xNi_(40)Sn_(10)(x=0,2,4,6)以其较大的低场磁热效应、可调的工作温区在磁制冷领域有着潜在的应用. 相似文献
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韩志达 《常熟理工学院学报》2009,23(10):19-22
采用电弧熔炼的方法制备了Ni43Mn46-xCoxSn1,系列铁磁形状记忆合金,并对其磁性和相变进行了研究．结果表明,由于价电子浓度的增加,Co替代Mn使材料马氏体转变温度迅速提高．Co的加入使合金的奥氏体居里温度迅速提高,而马氏体居里温度则略有降低．在马氏体相变附近,由于磁化强度的突变,合金表现出巨大的逆磁热效应,表明该系列合金在磁制冷领域有着潜在的应用价值． 相似文献
6.
采用溶胶凝胶法制备了系列Pr0.5Sr0.5MnO3纳米晶样品,用X射线衍射仪和扫描电子显微镜观察了材料的晶体结构和微结构,并用振动样品磁强计对其磁性和磁热效应进行了研究.结果表明,随着烧结温度的提高,材料颗粒尺寸也相应增大.当材料颗粒尺寸大于115nm时,材料表现出反铁磁到铁磁的一级相变和铁磁到顺磁的二级相变,而当颗粒尺寸小于115nm时,样品低温的反铁磁到铁磁相变消失,只剩下铁磁到顺磁一个相变.采用Maxell关系计算了材料在1T磁场下的磁熵变,在反铁磁到铁磁相变附近发现了正磁熵变,而在铁磁到顺磁相变附近具有负磁熵变. 相似文献
7.
《滨州学院学报》2021,(2):85-88
通过在MnCo_(0.4)Ni_(0.6)Ge中引入Mn空位得到化合物Mn_(0.95)Co_(0.4)Ni_(0.6)Ge,实现了AFM(TiNiSi)-FM(TiNiSi)-FM(Ni2In)-PM(Ni2In)多级相变;195K时在样品中观察到了从TiNiSi到Ni_2In的结构相变;255K时在样品Mn_(0.95)Co_(0.4)Ni_(0.6)Ge中实现了由顺磁(Ni_2In结构)向铁磁(TiNiSi结构)的结构相变;并且发现在外加磁场30kOe左右时引发场致相变;在195K(ΔB=5T)时产生了-17.8J/(kg·K)的磁熵变(材料制冷能力)。 相似文献
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采用溶胶-凝胶法制备不同粒径的La缺位La0.9MnO3钙钛矿氧化物.用X射线衍射、扫描电子显微镜、振动样品磁强计对材料的晶体结构、微结构、磁性和磁热效应进行了研究.结果表明,不同温度下退火(700oC~1100oC)的样品均具有菱形钙钛矿结构.退火温度从700oC增加到1100oC,样品的平均晶粒大小从25 nm增加到1000 nm.随着晶粒大小的增加,材料在低温的饱和磁化强度逐渐增强,铁磁到顺磁的相变变得陡峭,从而使材料的磁熵变逐渐增加.当材料的晶粒尺寸大于500 nm时,材料的磁熵变趋于稳定(-2.7 J/kg·K). 相似文献
9.
《常熟理工学院学报》2017,(4)
采用电弧熔炼的方法制备了Ni_(43)Mn_(46)Sn_(11)-xGax(x=0,1,2)合金铸锭.用X射线衍射表征样品的晶体结构,用振动样品磁强计和综合物性测试系统测量样品的相变和磁热效应.结果表明,所有合金在室温下均为奥氏体立方结构,表明马氏体转变温度低于室温.Ga代替Sn导致马氏体转变温度升高,这是由于Ga的原子半径小于Sn,导致晶格变小.所有样品在马氏体转变伴随着较大的磁化强度的突变,从而表现出较大的低场磁熵变.Ni_(43)Mn_(46)Sn_(11)-xGax(x=0,1,2)以其较大的低场磁热效应、可调的工作温区在磁制冷领域有着潜在的应用. 相似文献
10.
利用电弧炉熔炼法分别制备了LaFe11.2Co0.7Si1.1B0.2,LaFe11.1Co0.8Si1.1B0.2和LaFe11Co0.9Si1.1B0.2化合物。磁性测量和计算得到该系列化合物的等温磁熵变,利用直接测量法测量该系列化合物在外加磁场为0-1.5T下的绝热温变。最后分别计算基于等温磁熵变和绝热温变的相对制冷能力。 相似文献
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《海外英语》2007,(5):10-11
Many college freshmen arrive woefully unprepared to do college work, and as disadvantaged populations continue to grow, the share of the American work force that has made it through college is expected to plummet. Many experts blame that educational failure not just on high schools but also on colleges. School & College, a special report by The Chronicle, looks at efforts to fix the system. What reforms would better prepare students for college? What should schools and colleges be doing differently? How should state and federal officials help? 相似文献
14.
罗艳萍 《读与写:教育教学刊》2008,5(6)
The communication of people partially is the communication of cultures. Culture has a direct effect on international commercial activities in all aspects. Different conceptions about time, space, equality, law and the like, lead people to deal with things in different ways. So to know cultures of the counterpart is to facil-itate our enterprises so as to have a smooth and successful communication in commercial activity. 相似文献
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《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love. 相似文献
16.
Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject. 相似文献
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Richard Denner 《海外英语》2007,(4):14-15
Rosco and I wait for the fishermen to return.I sit at a wooden bench near the store at Mt.Baker Resort and watch the clouds change shape. Rosco has my belt around his neck and an eight foot tow chain hooked to a tree. Dogs must be on a leash. Ducks and rabbits are loose. 相似文献
18.
Given a graph G,a subgraph C is called a clique of G if C is a complete subgraph of G maximal under inclusion and |C|≥2. A clique-transversal set S of G is a set of vertices of G such that S meets all cliques of G. The clique-transversal number, denoted as TC (G), is the minimum cardinality of a clique-transversal set in G. The clique-graph of G, denoted as K (G), is the graph obtained by taking the cliques of G as vertices, and two vertices are adjacent if and only if the corresponding cliques in G have nonempty intersection. Let F be a class of graphs G such that F={G|K(G) is a tree}. In this paper the graphs in F having independent clique-transversal sets are shown and thus TC (G)/|G|≤1/2 for all G ∈ F. 相似文献
19.
Sister Carrie is one of the most controversial characters in American literature.Thought as a "fallen woman" firstly,she was defined as a "new woman" by some critics later. However, by digging into the motivaton behind the whole process of Carrie's "success", the relationship between Carrie and her creator (the author), the social conditions of then American, it can be found that Carrie has never been free-standing on her thought and she has never found her real-sdf even after becoming a famous actress. In a society dominated by mass consumerism Carrie is only an adherent of her own desires. She also is a representative of all those country girls flooded into cities, a symbol and a sacrifice of the urbanization of America in a time countryside was overcome by cities. 相似文献