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1.
This paper deals with the comparative evaluation of different procedures of salt extraction designed for archaeological ceramics from submarine burial environments. The experimental work was carried out on a particular type of late-Roman cooking ware finds (Pantellerian ware) found in a shipwreck near the shoreline of the Island of Pantelleria (Sicily). The studied ceramic test-pieces were first recognised in terms of bulk characteristics (mineralogy, petrography and chemistry). SEM-EDS observation allowed verification of the presence of various secondary minerals at the surface and in the pore spaces formed after the prolonged permanence in seawater under oxidising or reducing conditions. Pore-size distribution was also determined in the same fragments that had been subjected to the salt extraction routines. Three salt extraction methods were tested: two methods based on diffusion processes (water immersion under stationary conditions and under mechanical stirring conditions) and one method based on both diffusive and advective processes (multiple packages of sepiolite). The obtained experimental data allowed us to identify strengths and weaknesses of the tested procedures with practical spin-off for archaeologists and restorers (efficiency, kinetics, compatibility with the ceramic substrate, costs and simplicity of use). Salt extraction under mechanical stirring was the most effective method and, for this reason, is suitable for laboratory fieldwork during or immediately after submarine archaeological excavations. Similar advantages are also intended for the preliminary treatments of the most precious findings prior to museum storage.  相似文献   

2.
Salt crystallization is a major cause of damage in porous materials such as stone, brick and ceramics. The paper reports results of an analytical study on tiles of glazed ceramics that are seriously damaged by acetate salt crystallization. Measurements of the ionic composition of the salt mixture in the tiles and in the efflorescences were carried out. Based on the available information on the phase equilibria in the system comprising of the main constituents chloride, nitrate, acetate, calcium and sodium, the crystallization pathways of the various solid phases are traced. It is shown that a combination of qualitative XRD analysis of the phases present in the efflorescences together with a quantitative determination of the ionic composition is sufficient for the quantitative analysis of major crystalline species in the efflorescences, i.e. Ca3(CH3COO)3Cl(NO3)2 · 7H2O, thecotrichite, and NaCl, halite. The concentrations of these salts are obtained from a solution of the mass balance by least squares analysis. Their formation from the salt mixtures present in the tiles that are subject to acetic acid vapor attack is consistent with the solubility diagram of the above mentioned quinary system. Finally, the possibilities of preventive conservation of salt contaminated ceramics in typical museum environments are discussed.  相似文献   

3.
To create photorealistic three-dimensional (3D) models of real scenes and objects is a challenging problem that demands advanced knowledge of computer vision and computer graphics. Systems that can reconstruct the 3D model of cultural artefacts have found many applications such as virtual museum and historical archiving. While there are methods for 3D digitization of cultural artefacts with high geometric resolution, there are still limitations in achieving high textural resolution for virtual exhibition. One major problem is that the object surface exhibits specular reflection of illuminated light during the acquisition of surface texture. The shading of the target object does not match to other objects or pictures in the virtual scene. Also, if texture of the object must be composed of multiple images, the mismatch of shading (radiometric difference) among the images can be very prominent. In order to create high visual quality exhibition, the specular reflections must be eliminated and then the virtual scene is relit by a synthetic light source. Most existing methods for the identification and removal of specular reflection component demand special device or rely on information obtained in a single image. In order to reconstruct a complete 3D model, we need to acquire a multi-view image sequence. We therefore propose a new method that is applicable for the separation of diffuse and specular reflection components in multi-view image sequence. Also, our method can tackle the specular reflection across the texture boundary. The image sequence is first normalized by the estimated illumination color. Based on the dichromatic reflection model, the specular chromaticity is replaced by the corresponding diffuse chromaticity, which can always be found in neighboring views with the highlights already faded away. We test the new method in modeling Yixing ceramic teapots. The shape model of the teapot is obtained by a laser scanner. The diffuse image sequence is then used to generate the texture map. We create the virtual scene with the photorealistic 3D teapot model, some synthetic 3D models and still pictures. Interactive exhibition of the artefact is achieved with the control of the mouse and simple keyboard commands. This paper gives an account of the procedures for the creation of interactive virtual exhibition of ceramic artefacts.  相似文献   

4.
The present paper reports a new method for converting ettringite and thaumasite in non-expansible and insoluble phases, for its application in the restoration of concrete artefacts subjected to deterioration through sulphate attack. The salts were synthesized by different processes and, after characterization by means of XRD, FT-IR and optical microscopy, were treated with a series of chemicals in order to induce their decomposition. In particular, different solutions containing barium nitrate, barium hydroxide and ammonium oxalate were used to achieve the complete transformation of both phases in barite, witherite, scarbroite and whewellite. Barium hydroxide seemed to be the most appropriate reactant because the others could give rise to efflorescence within the pores of the mortars by leaving free nitrate or sulphate ions inside the materials. The experimental technique was also tested on two concrete samples collected from the bell-tower of St. Nicholas’ Cathedral in Nicosia (Sicily) with encouraging results.  相似文献   

5.
During the excavation of the Etruscan and Roman harbour of Pisa, several shipwrecks were found. The wooden timbers constituting the ship C and ship F (which date back to the first and the second century A.D., respectively, as attested by archaeological findings) were selected in order to collect information about the technological knowledge of the time. Pinus pinaster Aiton was essentially utilised for the planking of ship C and Quercus sp. caducifolia for that of ship F. The choice of timber for the other parts of ship C hull was much more differentiated. Ship C seems to be built in a careful way and its characteristics when added to its overall lightness, seem to reflect its use as a higher capacity boat built for sea sailing. Ship F seems more linked to short voyages in inner fresh waters. The utilisation of different woods was linked not only to the technological characteristics of wood, but also to their easy availability. Palynological analysis, carried out on the clay sediments embedding the shipwrecks, has shown that the flora of Pisa area in that time period would have allowed the acquisition of all the timber species used for both the ships’ construction, with the exception of the fig wood. However, a foreign origin of the timber from somewhere else in the Northern Mediterranean area has not been excluded.  相似文献   

6.
We describe the results of electromigration desalination of two soluble salt-contaminated Galician granites. The efficacy of electromigration, which had not been previously applied to granite, was assessed for two types of granite contaminated with a 20% NaCl solution and seawater. Desalination effectiveness was evaluated as follows: (1) analysis of anode and cathode ion content during testing; (2) analysis of ions at different distances from the electrodes after testing; (3) pH assessment of the stone surfaces; and (4) evaluation of colour changes. Results were very satisfactory; by the end of testing, chloride was reduced by almost 100% in both the NaCl and seawater contaminated samples. Sulfate reduction was also significant, despite this ion's lower mobility. The granite pH values remained close to neutral and colour changes were minimal. The difference in effectiveness of the process for the two types of stone was associated with their dissimilar pore structure.  相似文献   

7.
The crystallization of soluble salts plays a significant role in the deterioration of porous cultural property. A common response to salt damage problems is to undertake treatments aimed at reducing the salt content of the affected object, most typically through the application of poultices. The process of poulticing is in theory relatively simple: the wet poultice material is applied to the surface of the object to be treated, and is kept in place for some period of time before being removed. However, in practice, the efficiency of the salt extraction, or even the location of salt accumulation post treatment is more difficult to predict. This paper examines the physical principles of salt ion and moisture transport by which poultices function, and shows how depending on the application methodology, these treatments can be divided into diffusion and advection-based methods. The maximum salt extraction efficiency, the depth to which this can be achieved, and the time scale required is estimated for each type of poulticing system, to gain a better understanding of their working properties and performance. Finally, the pros, cons and limitations of desalination treatments are discussed.  相似文献   

8.
Desalination is a relatively new intervention in the field of conservation of architectural heritage. Especially the desalination of immovable objects, such as masonry structures, is still a trial-error practice. In the field, different desalination materials and methods are used, sometimes with unsatisfactory results. Better understanding of the desalination process is needed in order to support the conservator with clear guidelines for choosing a suitable desalination material and method. The research presented in this paper constitutes the first step towards the development of a modular system of poultices, which can be adapted, i.e. fine-tuned to different types of substrates. Starting point is to make use of advection, i.e. the transport of salt ions with water flow. This transport mechanism is faster than diffusion and the application on immovable objects is relatively easy. In order to optimize salt extraction, a poultice working by advection should have smaller pores than the substrate. Starting from this principle the pore sizes of different desalination materials (sand, cellulose, kaolin and bentonite) mixed in different proportions, have been measured. Interesting results were obtained, showing that the desalination materials commonly used in the field are often not the most suitable ones. On the basis of the results, recipes for poultices, adapted to a specific substrate, can be formulated.  相似文献   

9.
Various types of Late Neolithic decorated pottery excavated in Polyplatanos (Imathia, Greece) such as Crusted (C), Classical Dimini (CD), Black-on-Red (BoR), Cream-on-Red (CoR) and Graphite (G) were archaeometrically studied in order to investigate their provenance and to clarify specific technological features. The clay bodies, the paints and the slips were stereoscopically analyzed, while their elemental composition was determined, using non-destructive multi-elemental micro X-ray fluorescence spectroscopy. Furthermore, the analytical data were statistically treated using multivariate exploratory techniques (Principal Component Analysis, PCA). As a result, novel technological information was derived especially concerning the Crusted type ceramics, which have not been widely examined by archaeometric means up to now, while useful provenance associations were also derived from the statistical combination of the studied groups.  相似文献   

10.
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11.
The ‘Cotto Variegato’ are tiles used in Lombardy, between the XVII and XIX centuries as flooring for several historical buildings. Tiles are produced by the processing of two compositionally distinct clays. The main stylistic character of these tiles is a banded texture producing a veined aspect, in which white and red bands are also folded. The artefacts were hand crafted using two clayey raw materials of different composition, that are only partially mixed before the firing. The colour differences are produced during the firing. In all samples white and red portions are always composed of Ca-rich and Ca-poor clay, respectively. The multi-layered texture was obtained by a multiple folding and pressing process of the mixture. The interference of fold limbs with the tile surface gives the ‘variegato’ style to tiles. The paper explains how basic petrological knowledge can be applied to the study of ceramic artefacts in order to define provenance of the raw material, firing technology and how ancient craftsmen transformed the natural clayey materials into floor tiles. The methodological approach is that commonly applied to the study of the rocks and consists of textural analyses, at a different observational scale, combined with X-ray powder diffraction, X-ray fluorescence and microprobe analyses.  相似文献   

12.
Ceramic samples made with a mixture of 70% ball clay and 30% quartz sand were moulded and then fired at 900 °C in an electric kiln. Samples were then treated with different products and analyses and tests were performed to evaluate the physical changes induced by the application of these products and their effects on the quality of the ceramics. A petrographic study indicated that the ceramics were composed of quartz, small amounts of mullite and sanidine and traces of hematite. Mineral clays (i.e. kaolinite) disappeared during firing. Two consolidating products (Paraloid B72 and Tegovakon V) and one water repellent (Silo 111) were applied to samples by capillarity, and physical changes (colour, water flow, porosity and pore size distribution) were measured. Finally, we carried out salt crystallization tests in order to determine which product improved the quality of the ceramics. Treated samples registered a decrease in porosity and a general increase in pore size. The application of Silo 111 drastically reduced water absorption by immersion and by capillarity. This product was also responsible for a decrease in pore interconnection. Samples treated with Tegovakon V performed better in terms of their overall hydric behaviour. Silo 111 was the only product that did not modify the colour of samples when compared with untreated ones, and after accelerated aging tests, samples treated with this product hindered the absorption of saline solution into ceramic pores and prevented their decay. Paraloid B72 did not improve any of the properties of the ceramics.  相似文献   

13.
Many consider salvage value and tourism expenditures as the only economic values of a historic shipwreck. This paper looks at one alternative, the non-market value generated by management of shipwrecks as submerged maritime cultural resources. We consider the question: How much are people willing to pay to maintain shipwrecks in their pristine state? The contingent valuation method was implemented during summer 2001 as part of a telephone survey to households in eastern North Carolina. We find that households are willing to pay about $35 in a one-time increase in state taxes. Willingness to payis internally validated by expected relationships with prices and income but fails to pass the scope test. We speculate that we inadvertently succumbed to the well-known “birds” problem. The double-bounded willingness to pay questions are not incentive compatible and are subject to starting point bias, despite efforts to minimize these effects.  相似文献   

14.
Over the last years, there was an increasing interest in keeping suitable microclimatic conditions for the preservation of artefacts: the artefacts preservation requirements may diverge from those of the museums visitors, willing to enjoy the works of art in a situation of psycho-physical wellness. The HVAC designers and engineers will have then to cooperate closely with the curator, in order to define a compromise between conflicting environmental performance requirements. In particular at the stage of air-conditioning system design or retrofit, it is extremely important to carry out a series of preliminary analysis to evaluate and monitor the existing environmental conditions and to anticipatory simulate and predict the post-intervention conditions. To this aim, advanced fluid-dynamic investigation tools (Computational Fluid Dynamic [CFD] techniques) enable to deal with the specificity of such topics and provide a useful decision-making support.  相似文献   

15.
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16.
Within the framework of an excavation project aimed to systematically characterize the various aspects of settlement and activities in Northern Jordan, a considerable collection of slag lumps and iron artifacts of different forms and typologies excavated from the archaeological site of Barsinia were collected. Excavations have revealed other metallurgical materials such as pottery tuyeres and furnace-like structure. Studying those finds was important because of their archaeological and technological interests. For the analytical and metallurgical study, X-ray diffraction was used to identify the mineralogical composition of samples. Inductively coupled plasma-optical emission spectrometer, energy dispersive X-ray and X-ray fluorescence spectrometer were used to determine the accurate elemental composition of these finds. Furthermore examinations by using metallographic, polarizing microscope and scanning electron microscopy were employed to diagnose the characteristic morphology and environmental effects of these archaeometallurgical finds. Microstructural investigations emphasized that iron production processes were performed locally at the archaeological site of Barsinia even if the iron ores were imported from other mining location in Jordan. Direct or “bloomer” was the main method used for smelting iron ores followed by smithing methods to locally produce iron artifacts. This, most probably, was the state of technology from the Bronze Age to the Byzantine period. To ensure the stability of these deteriorated finds for future research, required treatment and conservation processes were successfully carried out.  相似文献   

17.
AimEstimating physical stability as well as revealing signs of fabrication in metal artefacts via two complementary nondestructive methods, neutron- and X-ray tomography were the main goals of this study.AbstractTo aid conservation management of metal artefacts improved knowledge of the internal structure and degree of corrosion therein is highly desired. In this study, neutron- and X-ray tomography were chosen as two complementary noninvasive visualization techniques to study internal structure and corrosion of five representative examples of archaeological metal artefacts from the Mapungubwe museum collection. Tomography was performed at the Neutron Radiography (SANRAD) facility of the South African Nuclear Energy Corporation where thermal neutrons as well as complementary X-rays are conveniently available under one roof. Comparative studies revealed neutron tomography to be generally superior to X-ray tomography due to the enhanced penetration properties of neutrons through the metal objects. In this paper the rich capability of neutron tomography as a nondestructive visualization aid for scientific conservation purposes is introduced and supported by results achieved for the five selected real artefacts.  相似文献   

18.
Selected copper alloy artefacts from the collection of the Umm Qais museum at Irbid, Jordan, were studied by SEM-EDS analysis, while in situ analyses were performed by means of portable μ-XRF and LIBS spectrometers. Analysis and characterization of base metal and corrosion products of the copper alloyed artefacts were performed in relation to the environmental conditions of the display and as part of the overall assessment of the museum environment. Findings of this study are directed towards guiding a preventive conservation strategy for the copper alloyed artefacts at the Umm Qais museum.  相似文献   

19.
A KrF-excimer laser operating at λ = 248 nm was used for basic studies in cleaning ancient glass surfaces. For irradiation a mask projection technique was applied. A modified optical set-up was designed using cylindrical lenses for large area removal by line scanning. Previous investigations revealed insufficient knowledge about interaction processes between UV-laser radiation and individual surface layers of encrusted historical glass. Thus, first detailed studies were carried out on special model glass samples simulating the behaviour of historical glass. The potential of removing crusts, bio layers as well as layers of different conservation materials (due to former conservation work) were examined. The avoidance of damaging material such as gel layers, paint layers or the bulk glass was of great importance. Removal rates and thresholds for the materials mentioned above were carried out. The collected data enables a comparison and evaluation of the feasibility for the removal of superficial layers from historical glass artefacts. The results indicate that in some cases a closed loop process control will be necessary to avoid over-cleaning.  相似文献   

20.
Roman cements, one of the most extensively produced types of hydraulic binders of the second half of the 19th century, played an important role in the architecture of many European countries. This paper deals with the chemical-mineralogical and microstructural characterisation of historic Roman cement renders from Budapest, Hungary. Different microscopic techniques were used on polished thin sections and fracture surfaces in order to understand the method of producing these renders and the effect of urban pollution on them. The renders exhibited characteristics typical to a Roman cement mortar, such as high binder to aggregate ratios (b/a), mostly fine-grained aggregates and high capillary porosity, but without the shrinkage cracks that are also normally present. This research suggests that coarse residual cement grains may have acted in a manner similar to aggregates by absorbing stress and thereby reducing the formation of shrinkage cracks. Based on the mineral characteristics of residual cement grains, the samples could be divided into two groups, which correspond to either a higher or lower temperature of calcination of the original source material of the cement. Chemical characteristics of the binders suggest the presence of intermixed CaCO3 originating from the carbonation of hydration products and partly from residual calcium carbonate of the raw material. Despite dense and often impermeable coats applied in later renovations and exposure to a polluted urban environment, which resulted in formation of gypsum on the surface of the renders, the samples show good to excellent state of preservation after more than a century. The strong “house of cards”-like arrangement of the complex C-(A)-S-H-type phases is responsible for both the high capillary porosity and the good resistance of Roman cement renders to atmospheric pollution and potentially damaging salts such as Na- and K-chlorides which are found near the base of the building due to sidewalk de-icing. These results help to better understand the behaviour of historic Roman cement renders, which in turn assists in making good decisions in choosing a repair material to future restorations of 19th century façades built with this material.  相似文献   

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