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1.
付淑英 《韩山师范学院学报》2010,31(3):35-37,42
以直流反应磁控溅射方法在Si(111)基底上制备薄膜TiN.研究发现:在保持其他工艺参数不变的条件下,溅射气压在0.3~1.3 Pa范围内,薄膜的主要成分是(111)择优取向的立方相TiN.当溅射气压为0.5 Pa时,沉积的薄膜膜层致密均匀,色泽金黄,膜厚为115.8 nm,结晶性能好.在可见光区半透明而在红外光区呈高反射,红外反射率为90%,具有良好的太阳光谱选择性. 相似文献
2.
The structural characteristics and optical and electrical properties of molecular-beam-epitaxy (MBE) grown ZnS0.8Se0.2 thin films on indium-tin-oxide(ITO) glas substrates were investigated in this work. TheX-ray diffraction (XRD) results indicated that high quality polycrystalline ZnS0.8Se0.2 thin film grown at the optimized temperature had a prefered orientation along the (111) planes. The transmission electron
microscopy (TEM) cross-sectional micrograph of the sample showed a well defined columnar structure with lateral crystal dimension
in the order of a few hundred angstroms. Ultraviolet (UV) photoresponsivity as high as 0.01 A/W had been demonstrated and
for wavelengths longer than 450 nm, the response was down from the peak response by more than 3 orders of magnitude. The thin
ZnS0.8Se0.2 photosensor layer, with a wide energy gap and anisotropic electrical property, makes a transmission UV liquid crystal light
valve (LCLV) with high resolution feasible.
Project supported by the National Natural Science Foundation of China (No. 59910161981) and RGC grant from the Hong Kong Government
Grant (No. NSFC/HKUST 35), China 相似文献
3.
Aluminum nitride (AlN) thin films with high c-axis orientation have been prepared on a glass substrate with an Al bottom electrode by radio frequency (RF) reactive magnetron sputtering. Based on the analysis of Berg's hysteresis model, the improved sputtering system is realized without a hysteresis effect. A new control method for rapidly depositing highly c-axis oriented AlN thin films is proposed. The N2 concentration could be controlled by observing the changes in cathode voltage, to realize the optimum processing condition where the target could be fixed stably in the transition region, and both stoichiometric film composition and a high deposition rate could be obtained. Under a 500 W RF power of a target with a 6 cm diameter, a substrate temperature of 450 ℃, a target-substrate distance of 60 mm and a N2 concentration of 25%, AlN thin film with preferential (002) orientation was deposited at 2.3 μm/h which is a much higher rate than previously achieved. Through X-ray diffraction (XRD) analysis, the full width at half maximum (FWHM) of AlN (002) was shown to be about 0.28°, which shows the good crystallinity and crystal orientation of AlN thin film. With other parameters held constant, any increase or decrease in N2 concentration results in an increase in the FWHM of AlN. 相似文献
4.
Measurement of the thermal transport properties of dielectric thin films using the micro-Raman method 总被引:1,自引:0,他引:1
The micro-Raman method is a non-contact and non-destructive method for thermal conductivity measurement. To reduce the measurement error induced by the poor fit of the basic equation of the original micro-Raman method, we developed a new basic equation for the heat source ofa Gaussian laser beam. Based on the new basic equation, an analytical heat transfer model has been built to extend the original micro-Raman method to thin films with submicrometer- or nanometer-scale thickness. Experiments were performed to measure the thermal conductivity of dielectric thin films with submicrometer- or nanometer-scale thickness. The thermal resistance of the interface between dielectric thin films and their silicon substrate was also obtained. The obtained thermal conductivity of silicon dioxide film is 1.23 W/(m.K), and the interface thermal resistance between silicon dioxide film and substrate is 2.35×10^-8 m^2.K/W. The thermal conductivity and interface thermal resistance of silicon nitride film are 1.07 W/(m.K) and 3.69×10^-8 m^2.K/W, respectively. The experimental results are consistent with reported data. 相似文献
5.
INTRODUCTION Veselago (1968) showed that if both the permit- tivity ε and the magnetic permeability μ of a material are negative, the propagation direction of an elec- tromagnetic (EM) wave will be opposite to its energy flow direction. Such media are called left-handed materials (LHMs) since the electric field E, magnetic field H, and wave vector k in these media form a left-hand triplet of vectors, instead of a right-hand triplet observed in conventional materials. For a long time, … 相似文献
6.
Xia A-gen Ye Jian-ting Ye Quan-lin Tao Xiang-ming Jin Jin-sheng Ye Gao-xiang 《浙江大学学报(A卷英文版)》2001,2(4):379-383
A new aluminum thin film percolation system, deposited on glass and silicon wafer surfaces by a vapor deposition method, was
investigated. By using the expansive and mobile behaviors of the silicone oil, the Al films are quenched gradually by the
silicone oil during the deposition process. TheR-I behavior of the film system was studied, and the anomalous conductivity indicated that, at very low current, the hopping
and tunneling effects in the films are much stronger than those of the normal film systems.
Project supported by NSFC (Grant No. 19874016) and the Special Fund of Zhejiang Provincial Natural Science Foundation for
Young Scientists (Grant No. 1997-RC9603). 相似文献
7.
采用直流反应磁控溅射法,制备了铝掺杂的氧化锌薄膜.结果显示:薄膜在500℃退火后透光率高,光敏特性良好,并且有明显的紫外光响应.其XRD衍射谱表明随着O2与Ar流量比的增加,对应于(002)晶面的衍射峰趋于尖锐,c轴取向突出明显. 相似文献
8.
Amorphous InGaZnO (a-IGZO) films were deposited on the corning eagle XG (EXG) glass substrates using magnetron sputtering
method. The structure, surface morphology, electrical and optical properties of these films were investigated by X-ray diffraction
(XRD), scanning electron microscopy (SEM), semiconductor parameter analyzer and spectrophotometry, respectively. The influence
of oxygen flow on the electrical properties of IGZO thin films was studied, showing that increasing oxygen flow changes the
resistivity with six orders of magnitude. The contact resistance of ITO/IGZO is 7.35×10−2 Ω·cm2, which suggests that a good ohmic contact exists between In2O3: Sn (ITO) and IGZO film. 相似文献
9.
In this paper, the Tφ-convex functions were introduced as a generalizations of convex functions. Then the characteristics of the Tφ-convex functions were discussed. Furthermore, some new inequalities for the Tφ-convex functions were derived. 相似文献
10.
WANG Jing-qin WANG Hai-tao WEN Ming ZHU Yan-cai 《浙江大学学报(A卷英文版)》2007,8(3):459-463
Because of the different ways in which contact materials work, the basic requirements for silver metal oxide contact materials are different. They are anti-welded and anti-erosion when closed, anti-erosion when broken, and arc easily moved and have smaller contact resistance. In this paper, La2O3 is used as a stable oxide in contact material to replace CdO. A new type of Ag/SnO2-La2O3-Bi2O3 contact material is first obtained through using powder metallurgical method. Then electrical contact material parameter tester is used to test the electrical contact performance of the contact material. Through experiments, the arcing voltage and current curves, arcing energy curves, fusion power curves while broken and contact resistance while closed were obtained. Analysis of the results showed that the addition of La2O3 makes the contact material have the following advantages: smaller electrical wear, smaller arc energy, smaller contact resistance and arc is more easily extinguished. 相似文献
11.
Xiao-li ZHAN ;Bi CHEN ;Qing-hua ZHANG ;Ling-min YI ;Bo JIANG ;Feng-qiu CHEN 《浙江大学学报(A卷英文版)》2008,9(9):1304-1308
A series of new amphiphilic poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) (PMTFPS-b-PEO) diblock copolymers with different ratios of hydrophobic segment to hydrophilic segment were prepared by coupling reactions of end-functlonal PMTFPS and PEO homopolymers. Copolymers were shown to be well defined and narrow molecular weight distribution (MWD) (1.07-1.3) by characterizations such as gel permeation chromatography (GPC) and ^1H-nudear magnetic resonance (^1H-NMR). 相似文献
12.
Hierarchical Bayesian method for estimating the failure probabilityp
i under DOOF by taking the quasi-Beta distributionB(p
i−1, 1, 1,b) as the prior distribution is proposed in this paper. The weighted Least Squares Estimate method was used to obtain the formula
for computing reliability distribution parameters and estimating the reliability characteristic values under DOOF. Taking
one type of aerospace electrical connector as an example, the correctness of the above method through statistical analysis
of electrical connector accelerated life test data was verified.
Project (No. 59975081) supported by the National Natural Science Foundation of China 相似文献
13.
Study of the SISO mixedH
2/l1 problem for discrete time systems showed that there exists a unique optimal solution which can be approximated within any
prescribed missing error bound inl
2 norm with solvable suboptimal solutions and solvable superoptimal solutions.
Project supported by the National Natural Science Foundation of China (No. 60174026) and the Scientific Research Foundation
for Returned Overseas Chinese Scholars of Zhejiang Province (No. J20020546) 相似文献
14.
Low valence vanadium oxide(VO2-x) thin films were prepared on SiO2/Si substrates at room temperature by direct current facing targets reactive magnetron sputtering, and then processed through rapid thermal annealing. The effects of the annealing on the structure and phase transition property of VO2 were discussed. X-ray photoelectron spectroscopy, X-ray diffraction technique and Fourier transform infrared spectroscopy were employed to study the phase composition and structure of the thin films. The resistance-temperature property was measured. The results show that VO2 thin film is obtained after annealed at 320℃ for 3 h, its phase transition temperature is 56 ℃, and the resistance changes by more than 2 orders. The vanadium oxide thin films are applicable in thermochromic smart windows, and the deposition and annealing process is compatible with micro electromechanical system process. 相似文献
15.
Sorption of wastewater containing reactive red X-3B on inorgano-organo pillared bentonite 总被引:2,自引:0,他引:2
Zeng XQ 《Journal of Zhejiang University. Science. B》2006,7(4):314-319
Bentonite is a kind of natural clay with good exchanging ability. By exchanging its interlamellar cations with various soluble cations, such as quaternary ammonium cations and inorganic metal ions, the properties of natural bentonite can be greatly improved. In this study, hexadecyltrimethylammonium bromide (HDTMA), CaCl2, MgCl2, FeCl3, AlCl3 were used as organic and inorganic pillared materials respectively to produce several kinds of Ca-, Mg-, Fe-, Al-organo pillared bentonites. Sorption of reactive red X-3B on them was studied to determine their potential application as sorbents in wastewater treatment. The results showed that these pillared bentonites had much improved sorption properties, and that the dye solutions' pH value had some effect on the performance of these inorgano-organo pillared bentonites. Isotherms of reactive X-3B on these pillared bentonites suggested a Langmuir-type sorption mechanism. 相似文献
16.
α-diketones and β-diketones react with Grignard reagents in the presence of a catalytic amount of Cp2TiCl2 to yield α-ketols and corresponding ketones respectively. Sulfoxides can be deoxygenated by Cp2TiCl2/Al system. The possible mechanisms are also discussed.
Project (No. 20072033) supported by the National Natural Science Foundation of China and the Specialized Research Fund for
the Doctoral Program of Higher Education Ministry, China 相似文献
17.
Objective To explore how arylamine N-acetyltransferases (NATs) is related to cell apoptosis.
Methods NAT activity in apoptotic HepG2 cells was measured using high performance liquid chromatography (HPLC); the apoptosis rate
of HepG2 cells acted upon by an NAT inhibitor was measured using flow cytometry.
Results NAT activity was lowered in apoptotic HepG2 cells; apoptosis rate induced by camptothecin (CAM) increased after inhibition
of NAT activity in HepG2 cells.
Conclusion NAT can inhibit apoptosis in HepG2 cells.
Project supported by the National Natural Science Foundation of China (No. 30400591), the Science Foundation of Heilongjiang
Province, China (Nos. D2004-13 and D200505), and the Young Scientist Fund of Harbin City, China (No. 2004AFQXJ035) 相似文献
18.
SO4^2- / TiO2-La2O3, a novel solid superacid, was prepared and its catalytic activities at different synthetic conditions are discussed with esterification of n-butanoic acid and n-butyl alcohol as probing reaction. The optimum conditions have also been found, mole ratio of n(La^3+):n(Ti^4+) is 1:34, the soaked consistency of H2SO4 is 0.8 tool/L, the soaked time of HESO4 is 24 h, the calcining temperature is 480 ℃, the calcining time is 3 h. Then it was applied in the catalytic synthesis often important ketals and acetals as catalyst and revealed high catalytic activity. Under these conditions on which the molar ratio of aldehyde/ketone to glycol is l: 1.5, the mass ratio of the catalyst used in the reactants is 0.5%, and the reaction time is 1.0 h, the yields of ketals and acetals can reach 41.4%-95.8%. 相似文献
19.
Samarium and a catalytic amount of iodine were used to obtain functionalized cyclopentenes by reductive dimerization followed
by intramolecular cyclization of 1,1-dicyanoalkenes under mild conditions.
Preject (No. 20072033) supported by the National Natural Science Foundation of China, and Zhejiang Provincial Natural Science
Foundation of China 相似文献
20.
Thermodynamic Optimization of DyCl3 -NaCl System 总被引:2,自引:0,他引:2
In this paper, the phase diagram of the DyCl3 -NaCl system is optimized and calculated with CALPHAD ( calculation of phase diagram ) technology. A set of thermodynamic functions of compounds Na3 DyCl6, NaDyCl4, and NaDY2 Cl7 have been optimized and calculated based on an interactive computer-assisted analysis. The optimized thermodynamic parameters, calculated phase diagram and experimental phase diagram are thermodynamically serf-consistent. 相似文献