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1.
《文物保护研究》2013,58(2):54-61
AbstractSamples of pigments from excavated wall paintings of Vergina’s second tomb were analyzed by the non-destructive methods of X-ray fluorescence, X-ray diffraction and mineralogical microscopic examinations. The results showed that one type of blue pigment was used, the well-known Egyptian blue. The red pigments, except one which is haematite, are cinnabar (HgS), and the grey pigments are carbon. None of the black pigments contained manganese compounds. 相似文献
2.
《文物保护研究》2013,58(3):107-119
AbstractSamples of pigments from excavated wall-paintings at the great civilization center of the Greek Bronze Age, Thera, have been analysed by the non-destructive methods of X-ray fluorescence, X-ray diffraction and mineralogical microscopic examination. The results showed that three types of blue pigment were used, namely the well-known Egyptian blue, glaucophane, which is a sodium magnesium (or iron) aluminium hydroxide silicate which occurs as a natural mineral on Santorini, and a mixture of Egyptian blue and glaucophane. Black pigments were rather puzzling in that some of them are carbon as expected, and some are manganese compounds. The rest of the pigments are very similar to those previously examined from Mycenae and Knossos. 相似文献
3.
《文物保护研究》2013,58(3):117-122
AbstractSamples of pigments from a wall-painting of a house of the first Pompeian style (400 Bc–168 BC) found in Pella, Greece, were analyzed by the non-destructive methods of X-ray fluorescence and X-ray diffraction. Red pigments were identified as cinnabar and iron oxide pigments (haematite and goethite). Blue was the well-known Egyptian blue and yellow was identified as goethite. A characteristic feature of the wall-painting was the presenceof green earth, i.e. celadonite and glauconite, encountered for the first time in this series of investigations. 相似文献
4.
《文物保护研究》2013,58(1):81-83
AbstractThe ceremonies ofthe Maya people of Chiapas, Mexico, combine Catholic symbolism and ancient ritual. The clothes belonging to the effigies of saints, as well as other textiles, are taken out of storage, washed, dried and incensed in preparation for the saint's feast day. One such feast, Chuc Nichim, is described in detail, and the conservation implications of the rituals are discussed. 相似文献
5.
《文物保护研究》2013,58(3):188-189
AbstractBlue and white Chinese porcelain specimens from Dehua and Zhangzhou kiln sites from the Ming dynasty (AD 1368–1644), and Jingdezhen kiln sites from the Yuan (AD 1280–1368) to Ming dynasties were collected. The chemical compositions of these valuable samples were determined using energy dispersive X-ray, fluorescence (EDXRF) spectrometry, a non-destructive method, and some Jingdezhen samples were analyzed by scanning electron microscopy and transmission electron microscopy. The EDXRF results were subjected to correspondence analysis. Differences in the composition of the specimen bodies were found for specimens from different production sites. The blue and white Jingdezhen imperial, porcelain from the Yuan to Ming dynasties can be divided into two periods based on differences in the chemical composztion and microstructure of the pigments. The reasons for these variations are discussed. 相似文献
6.
《文物保护研究》2013,58(2):116-121
AbstractThe use of Prussian blue in nineteenth-century Japan has been extensively researched, particularly in relation to the ‘blue revolution’ in ukiyo-e prints but its use by Chinese artists has not received the same degree of attention. A commodity traded by the East India Company, this pigment was used to ‘improve’ the colour of tea, but in or about 1825 the trade abruptly ceased. It now seems fairly clear that the cessation of the Prussian blue trade coincided with the setting up of a Prussian blue factory at the northern gate of Canton, and that knowledge of the industrial process was possibly acquired covertly from a London manufacturer. The pigment has been identified chemically among paint fragments collected during the dis-binding of an album of Chinese botanical watercolours sent from Canton to the Horticultural Society of London by tea inspector John Reeves between 1817 and 1830. This finding suggests that conservators should not exclude the possibility of finding Prussian blue on Chinese work dating from at least the early part of the nineteenth century. 相似文献
7.
《文物保护研究》2013,58(4):231-254
AbstractAnalyses of pigments from palettes used by J.M.W. Turner (active c.1792–c.1850) by means of microscopy, microchemical analysis, thin-layer chromatography, energy-dispersive X-ray analysis, X-ray diffraction and Fourier transform infrared spectroscopy are given. The occurrence of pigments in Turner's dated oil paintings and watercolours is also given, arranged by five-year periods. These findings are discussed in the context of published analyses of pigments from the first half of the nineteenth century. Turner used cobalt blue, emerald green, viridian, orange vermilion, barium chromate, chrome yellow, chrome orange and chrome scarlet within a few years of their known dates of discovery. It has become clear that Turner was using, or at least experimenting with, practically all the pigments known to be available at that time. In a few cases, in the light of these results, ideas on the availability of pigments to English artists have been revised backwards to the first known date of manufacture. Turner also possessed and used a wide range of red and yellow organic pigments, but few organic greens. The dyestuff extracted from Rubia tinctorum L. madder on an aluminiumcontaining substrate can be distinguished from the same madder on different substrates by its strong pink fluorescence in both ultraviolet and green light. The other red organic pigments (a second madder, brasilwood and cochineal dyestuffs on a range of substrates containing aluminium, copper, iron, aluminium/copper and clays) show negligible fluorescence. The red organic pigments were used in oil medium as well as watercolour, the yellows only in watercolour medium. 相似文献
8.
AbstractDisoloured and pure smalt were investigated by means of X-ray diffraction, electron microscopy and reflectance spectroscopy. It was found that the discolouration of smalt could not be explained in terms of devitrification or recrystallisation. Electron micrographs of replicas show a distinctly attacked grain surface with residues of organic material. Ultramicrotome thin sections of discoloured grains illustrate that an unaltered core is embedded in a material no longer showing the conchoidal fracture and presumably consisting of an organo-metal compound.The reflectance spectrum of discoloured smalt gives evidence that the cobalt ion is in sixfold (octahedral) co-ordination rather than in fourfold (tetrahedral) co-ordination, while the characteristic blue colour of unaltered smalt depends on the purely tetrahedral co-ordination of cobalt.It is therefore concluded that the discolouration reaction may be started by the catalytic influence of cobalt on the oil medium but that eventually the grain surface itself is attacked,involving the oxidation of Co2+ to Co3+ and a change of co-ordination of the cobalt ions. The reaction proceeds from the grain boundary to the centre and may leave, at an intermediate stage of the process, an unaltered smalt core within the otherwise discoloured grain. 相似文献
9.
Pigments on a figurative wall painting in Poudeh village, central Iran, were analysed by micro X-ray fluorescence spectrometry, micro Raman spectroscopy, scanning electron microscopy coupled with energy dispersive X-ray spectrometry, micro Fourier transform infrared spectroscopy, X-ray diffractometry, and polarised light microscopy. Red lead, ultramarine blue, chrome yellow, brass powder, white huntite, and lammerite (Cu3(AsO4)2) were identified as red, blue, yellow, golden, white, and green pigments, respectively, while gypsum and barite were used as extender. In addition, glushinskite (MgC2O4·2H2O) was identified as a deterioration product of white huntite. Moreover, several analytical studies suggested that lammerite was a degradation product of emerald green (Cu(CH3COO)2·3Cu(AsO2)2) originally used as green pigment in the painting. The formation of lammerite is suggested to be due to the migration of arsenic throughout the paint layer. Based on the pigments identified, the wall painting is dated from the mid-nineteenth century to the mid-twentieth century. 相似文献
10.
《文物保护研究》2013,58(3):212-222
AbstractIt is still unclear why some of the blue enamel on sixteenth- and seventeenth-century stained window glass is flaking off, while enamel layers with other colours are still in relatively good condition. In order to obtain a better understanding of this conservation problem, 31 historical recipes used for the fabrication of blue enamel were compared with results from the chemical analysis of 25 historic samples. The chemical composition and the microstructure of the enamels were analysed in cross-section by means of electron probe microanalysis (EPMA). This study demonstrated that the variation in chemical composition of the samples can be explained by the use of the wide range of recipes existing at that time. Although this study gave an insight into the composition, heterogeneity and use of colouring substances, no clear relation could be found between the parameters analysed and the deterioration rate of the blue enamel paint layer. 相似文献
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《文物保护研究》2013,58(3):195-208
AbstractPyrolysis–gas chromatography was applied to the characterization of synthetic organic pigments. On pyrolysis, azo pigments and phthalocyanine blue yield characteristic fragments. These pyrolysis products were identified, and the mechanism of decomposition was studied. In the case of paint samples, the main pyrolysis products derive from the medium, although the presence of additional peaks enables azo pigments and phthalocyanine blue to be characterized. Some examples of the analysis of artists' paints are given and the peaks are identified. The main limitation of this technique is that it is impossible to detect chemically and thermally stable pigments, or inorganic components. 相似文献
13.
Lapis Lazuli in an Enigmatic ‘Purple7rsquo; Pigment from a Thirteenth-Century BC Greek Wall Painting
《文物保护研究》2013,58(4):252-266
AbstractThis paper presents the first evidence of lapis lazuli or lazurite that was detected unexpectedly using micro-Raman spectroscopy during research to identify an enigmatic purple hue on the thirteenth-century BC Greek Bronze Age wall paintings from Gla. The lapis lazuli material was found as part of a mixture including a red iron oxide and an as yet unidentified purple staining material. Existing purple mixtures of that period are also discussed. The identification of lapis lazuli at Gla may prove to be the earliest known use of this pigment in buon fresco, in both Eastern and Western painting traditions. Furthermore, this precedes the next known use of the material as a pigment by 1800 years. The existence of this blue pigment is also discussed within the context of the blue pigment palette of the Bronze Age Aegean and eastern Mediterranean Bronze Age (3300–1100 BC), to show its use in relation to other blue materials and to demonstrate the technology and knowledge mastered by the artists who used this lazurite. 相似文献
14.
《文物保护研究》2013,58(2):84-86
AbstractEgyptian blue has been identified positively in a Roman mediaeval fresco of the lower church of San Clemente. The date around the middle of the ninth century A.D. of the mural painting extends by five centuries the previously known period of use of this famous pigment. 相似文献
15.
《文物保护研究》2013,58(1):15-32
AbstractAn investigation for light exposure on pigments in low-oxygen environments (in the range 0–5% oxygen) was conducted using a purpose-built automated microfadometer for a large sample set including multiple samples of traditional watercolour pigments from nineteenth-century and twentieth-century sources, selected for concerns over their stability in anoxia. The pigments were prepared for usage in watercolour painting: ground and mixed in gum Arabic and applied to historically accurate gelatine glue-sized cotton and linen-based papers. Anoxia benefited many colorants and no colorant fared worse in anoxia than in air, with the exception of Prussian blue and Prussian green (which contains Prussian blue). A Prussian blue sampled from the studio materials of J.M.W. Turner (1775 ? 1851) was microfaded in different environments (normal air (20.9% oxygen) 0, 1, 2, 3.5, or 5% oxygen in nitrogen) and the subsequent dark behaviour was measured. The behaviour of the sample (in normal air, anoxia, and 5% oxygen in nitrogen) proved to be consistent with the 55 separately sourced Prussian blue samples. When exposed to light in 5% oxygen in nitrogen, Prussian blue demonstrated the same light stability as in air (at approximately 21°C and 1 atmosphere). Storage in 5% oxygen is proposed for ‘anoxic’ display of paper-based artworks that might contain Prussian blue, to protect this material while reducing light-induced damage to other components of a watercolour, including organic colorants and the paper support. 相似文献
16.
《文物保护研究》2013,58(1):22-26
AbstractVery small paint samples from Cosimo Tura's ‘The Annunciation with Saint Francis and Saint Louis of Toulouse’ were submitted to amino acid analysis in order to determine the nature of the binding media. The four panels appeared to have been painted with egg tempera, and showed extensive localized deterioration in the blue areas but not in the other coloured areas. Following the Picotag method, the samples were hydrolyzed in an acid vapor, derivatized with iso-thiocyanatobenzene, and analyzed using reversed phase high pressure liquid chromatography (HPLC). Amino acid analysis demonstrated that the red and brown areas were painted using egg yolk as the binding medium, while the blue areas were painted with animal-skin glue (distemper). Analysis of the green paint indicated a mixture of egg yolk and glue. The use of these techniques makes it possible to identify proteinaceous materials in art objects from samples in the microgram range. 相似文献
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18.
《文物保护研究》2013,58(4):149-154
AbstractThe small areas of white metallic pigment seen on the south wall of J. M. Whistler's ‘Peacock Room’ in the Freer Gallery of Art are platinum; this has been used, with a yellow-brown ground, to overpaint a preceding layer of silver which, in one place only, is over a preceding layer of gold. The yellow metallic pigment is confirmed as gold and the blue colour of the south wall and elsewhere is based on Prussian blue. On a separate wood panel a green was tentatively identified as copper resinate, and iron-oxide-based pigments appear to be present. In all areas investigated a white, used as a ground and in admixture, was essentially lead white and calcium carbonate. The significance of these results is discussed briefly. 相似文献
19.
ABSTRACT This article presents historical and scientific analysis, as well as the conservation treatment of a newly rediscovered Roman wall painting fragment, now in the collection of the Harvard Art Museums. Although the piece has not previously been published, it was among a group of fragments removed from a Roman villa near Boscotrecase in southern Italy, an area that has been key to the study of Roman wall painting and other decoration. Technical imaging confirms the use of painting techniques consistent with other high-quality paintings in the area. Materials analysis revealed a palette consistent with published findings of Roman wall paintings, including abundant use of Egyptian blue and green earth. Of interest was the use of Egyptian blue as an optical brightener in select white passages. Despite the high quality of the painting, no cinnabar was present, and all red passages were achieved using hematite. Multiple different white minerals were identified including calcite, aragonite, and gypsum. The widespread presence of gypsum is unusual and may point to alteration. 相似文献
20.
《文物保护研究》2013,58(1):11-12
AbstractNew equipment is described which allows precise location of the X-ray source under the portion of interest of a painting undergoing radiography. It utilizes an electromagnetic wave transmitter placed on the painting and four sensors on the movable carriage containing the X-ray tube which process the signals and indicate, by an LED display, the necessary movements of the carriage. 相似文献