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1.
《文物保护研究》2013,58(4):229-240
Abstract

This paper describes a novel technique to stabilize the relative humidity (RH) of the air inside museum showcases by using a synthetic hydrophobic membrane coupled with a hygroscopic solution in a membrane contactor. RH-monitoring data for two identical test cases, one of them controlled by a set-up with a plane-plate membrane contactor crossed by forced air and lithium chloride (LiCl) solution flows, show a significant stabilizing effect on RH fluctuations. A theoretical model permits forecasts in close agreement with the experimental RH data. Further calculations carried out over a one-year period show that notable damping of external RH variations can be obtained by using a low air circulation rate, small membrane surface area and low solution mass per unit case volume. A more general analytical solution in harmonic conditions is derived and discussed.  相似文献   

2.
Conditions of relative humidity (RH) and temperature within museums and buildings holding collections of cultural heritage objects are often maintained around a strictly controlled set point of about 50 ± 5% RH and 20 or 21 ± 2°C to provide safe, stable conditions for hygroscopic artifacts. It has recently been proposed that these ranges should be relaxed to values that are less energy-intensive to maintain while still being safe for the objects in the collection, with the aim of reducing both carbon footprint and energy use. It is also suggested that conditions should be determined by the needs of individual objects and by the local climate of the region, rather than applying overall values across the museum as a whole. This proposal has led to much discussion within the conservation community. The suggested values, a stable humidity within the range 40–60% RH and a stable temperature within the range 16–25°C for most objects, apart from the most vulnerable, are derived from the results of experimental research on the responses of individual materials to particular conditions of RH and temperature, as well as observations of the behaviour of cultural heritage objects in their own environments and on loan. This paper describes briefly the historical and scientific background to the present discussion.  相似文献   

3.
ABSTRACT

Many museums are housed in historic buildings, sometimes the building itself is part of the museum collection. Creating a stable environment by providing a nearly constant temperature and relative humidity at correct levels decreases the risk of object degradation. Maintaining this steady indoor environment, however, increases energy consumption and risks to the historic building. Museum display cases offer a solution to the mitigation of risks to which valuable objects may be subjected by providing an extra layer of protection to indoor climate fluctuations. The Anne Frank House is a historic house museum located in Amsterdam. The museum has undergone several renovations in the last years to deal with an increase in the number of visitors to over 1.2 million a year. The original diaries and other documents of Anne Frank are permanently on display in the Anne Frank House. With the recent refurbishment the possibility arose to design a new state-of-the-art display case. This study presents the results of the experimental research related to the design, performed in-situ. The temperature and relative humidity in the new exhibition space and inside the new display cases were monitored to gain insight into the hygrothermal behavior of these controlled environments. A complementary numerical study was performed to investigate effects of dynamic climate control of the exhibition gallery and climate conditions in the display case under various circumstances. Four main conclusions are presented in this paper. The investigated display case design is able to provide a stable relative humidity environment by means of silica gel, while using an active box-in-box climate control system to create stable temperature conditions. The inner case temperature depends on the temperature supplied by the display case air handling unit. Protocols must be in place in case of malfunction or failure of the climate control system of the display case. The air handling unit of the case needs to be shut off to create a passive environment for the objects on display until necessary actions are taken. Exhibition gallery set points can be less stringent when susceptible museum objects are on display in the display case. The environments are separated and provide an opportunity for energy saving set point strategies. The last conclusion drawn is that the numerical study provides valuable insight into imposing dynamic control of set points for temperature and relative humidity in the exhibition gallery and the effect on the display case environment.  相似文献   

4.
ABSTRACT

This experimental program, implemented by the Managing Collection Environment Initiative at the Getty Conservation Institute, has provided data about the response of historic objects to changes in relative humidity (RH). Alongside other less sensitive documentation techniques (visual observation, physical measurements, photography, and 3D scanning), acoustic emission (AE) was monitored for six historic, museum-like wooden objects exposed to gradually increasing RH variations. Quantitative calibration of AE sensors and an anti-correlation measuring scheme to reduce environmental noise allowed the AE system to effectively trace micro-damage development caused by environmentally induced stress. Using an epidemiological approach, with respect to sample selection and experimental protocol, the obtained results can be used to explore the acceptable range of climate fluctuations for museum collections. The study’s well-controlled environmental protocol also allowed for the examination of the concept of ‘proofed fluctuation’ by the analysis of object response to reoccurring conditions.  相似文献   

5.
《文物保护研究》2013,58(2):88-94
Abstract

This paper examines the impact of relative humidity on jades by enclosing the samples under constant relative humidity (RH) of 32, 49, 61.5, and 81.7% at the same temperature of 40 ± 0.1°C for 160 days. The simulated samples were pure and dense tremolite jade and serpentine jade, impure tremolite jade and serpentine jade containing some calcite, and serpentinized calcite, which are all common materials of ancient jade found in archaeological excavations. All samples were characterized through particle-induced X-ray emission and a glossmeter. The degree of deterioration proved to be greater in impure materials than in pure ones. The best RH to conserve various kinds of materials differs: for pure tremolite and serpentine, all of the RH levels are equal; for impure tremolite with some calcite, 61.5 and 81.7% were superior; for impure serpentine with some calcite, the highest RH (81.7%) was best; and as to the serpentinized calcite, there is no clear conclusion as yet and further research is needed.  相似文献   

6.
《文物保护研究》2013,58(2):104-112
Abstract

An exhibition case displaying ancient bronzes was found to have a high leak-rate and was subject to a variety of environmental factors. Because of the original case design, passive means of control were not proving effective. A simple, low-output (below 28l.min?1) drying system based on hollow fibre (polysulfone) technology was tested and installed in the case to maintain the microenvironment below 43% relative humidity (RH). The membrane was tested below industrially-specified pressure parameters (less than 4 bar) and found to produce a range of consistent RH outputs suited to museum use. After some years in service, the system has proved reliable and simple to operate; optimum performance was achieved with more continuous operation.  相似文献   

7.
From rainy season to summer in Japan, the climate is humid. Especially in these seasons, it is difficult to maintain suitable conditions of temperature and relative humidity in exhibition and storage rooms in museums. Such climate conditions and problems are common to many countries in East Asia. Analysis using computer simulation can be a powerful tool because it is cheap and allows the simulation of a range of conditions without having to make changes to buildings and environments surrounding cultural objects. In this study, a storage building in which there is no air-conditioning unit was chosen as a target. The modelling of temperature and relative humidity in storage spaces was conducted using the Thermal and Airflow Network Model Simulation Program for buildings (NETS). The effect of seismic retro-fitting on the variation of temperature was predicted using NETS and the results were evaluated by comparing with the measured values. As a result, the heat transfer was successfully calculated and the modelled temperature represents the measured values reasonably well. Computing relative humidity by taking into account the effect of porous hygroscopic materials is challenging. In order to overcome this problem, the κ-ν model was adopted. We have some improvements but the study is still ongoing.  相似文献   

8.
ABSTRACT

Historic buildings in Denmark have a high relative humidity (RH) all year, so the interiors are exposed to biological degradation. The acceptable range for RH is 60–70%, which is higher than the usual recommendations for museums and galleries. There are two options for humidity control: conservation heating or mechanical dehumidification. Calculation of the energy performance of a generic building was used to determine which method is the most efficient. Studies of a cottage in Liselund Park, and of two medieval churches in Hellerup and Vemb have confirmed these predictions: dehumidification is less energy consuming than conservation heating in buildings with poor thermal insulation and a moderate air infiltration rate (AER?<?0.6?h?1). Dehumidification is suitable for historic buildings, where heating is not needed for human comfort. A condensing dehumidifier uses less than half the energy per kg water compared to an absorption dehumidifier. But it does not work at temperatures below 2°C. The combination of a condensing dehumidifier and a little heating to prevent frost is the most energy efficient solution for humidity control. These results are only valid in mild and humid climatic conditions similar to Denmark.  相似文献   

9.
《文物保护研究》2013,58(1):8-17
Abstract

Absorbent materials such as wood, paper and cotton stabilize the atmosphere of show-cases against the relative humidity changes caused by temperature variation and by exchange of air with the surroundings.

There are several exchange processes between the air in the case and the outside air: diffusion through porous COllstruction materials, air flow caused by temperature and pressure changes and airflow by convection in a show-case whose relative humidity differsfrom that of its environment. The air changes about once a day in show-cases made by conventional joinery techniques. The rate of exchange can be reduced to less than five volumes a year by sealing a show-case so that only one small hole is left for pressure equalization. A dust and sulphur dioxide filter can then be fitted to maintain a pure atmosphere within.

In heated rooms without air-conditioning the RH may fall dangerously low in winter. A static method of RH control for a show-case is described. This is a saturated solution of sodium bromide covered by a silicone rubber membrane.  相似文献   

10.
Salt crystallization is recognized as a major cause of damage to porous building materials, threatening the sustainable preservation of our valuable built heritage. Unfortunately, the crystallization behavior of the detected salt mixtures is complex and not fully understood. While the deliquescence points of single salts are well documented, this is not the case for salts in a mixture where one is confronted with the presence of different cations and anions. In this paper the salt content of the murals and the limestone tracery of the main entrance porch from the sixteenth century church of St. James in Liège, Belgium is investigated and related to the climatic conditions of its environment. Concerning the salt load, the research consists of hygroscopic moisture content measurements, quantitative ion analyses, and the prediction of phase equilibria using the thermodynamic model ECOS/RUNSALT. This model can predict the salt crystallization sequences of a particular ion mixture. The output is mathematically evaluated with collected temperature and relative humidity data, which enables the calculation of the number of salt crystallization–deliquescence cycles. The results show that even small amounts of salts can cause damage over a long period of time when the environment causes frequent cycles of crystallization–deliquescence over time. It is shown how a mixture of small amounts of (double) salts, including hygroscopic ones, can have a significant effect on the decay of historic building materials in the case of daily changing climatic conditions and periods of extreme drought. As a result, the crystallization of double salts and hygroscopic salts such as calcium nitrate cannot be ignored. The scientific method and the results are described.  相似文献   

11.
《文物保护研究》2013,58(4):269-277
Abstract

simple mathematical model is presented that predicts the decay time of the internal relative humidity (RH) of backboard-protected canvas paintings when subjected to external RH fluctuations. The model takes into account the permeance of the canvas and the hygroscopicity of the enclosed materials. Predictions from the model are tested experimentally. The wooden stretcher releases moisture more slowly than expected, providing less buffering than predicted by the model. The practical implications of these findings are discussed.  相似文献   

12.
《文物保护研究》2013,58(2):47-52
Abstract

An environmentally controlled case is described for conserving a Fayum panel painting on loan to the Brooklyn Museum which exhibited a high degree of sensitivity to changes in relative humidity. The case was constructed of aluminium with a glass front, sealed in an air-tight fashion with a gasketted metal frame. It was intended to maintain a level of 50% RH in order to relax the panel painting from its high degree of warping, returning it to its original contour, and to conserve it permanently in this micro-climate. The humidity control agent found very satisfactory for this purpose was silica gel pre-conditioned to produce the 50% RH environment. The method of preparation of the gel was by exposure over a saturated solution of magnesium nitrate hexahydrate. The authors have detailed the construction of the case and method of installation of the Fayum portrait, as well as the technique of silica gel maintenance. The interior climate has been controlled satisfactorily since November 1974.  相似文献   

13.
ABSTRACT

Control of relative humidity (RH) for collections care is challenging in U.K. historic houses because they are often highly ventilated with poor heat retention, a porous building fabric and naturally tend to high (60–80%) RH if unheated. The significance of the building means that large-scale modifications and installation of air handling systems may be unfeasible and undesirable for the conservation of the building. In the late 1980s the National Trust, for English, Wales and Northern Ireland, investigated conservation heating as an RH control method that works with the natural environment of historic buildings, mimicking historic heating and requiring only modification of existing heating services or a light touch installation of new heating systems. The National Trust adopted conservation heating as its preferred method for environmental control in historic buildings from the 1990s. This method was presented at the IIC 1994 Ottawa congress on preventive conservation. Conservation heating has since been adopted by many historic house management organisations, particularly across north-west Europe, where it is well suited to the climate. This paper reviews conservation heating developments implemented by the National Trust since 1994, in response to a changing external context, new knowledge and developments in operational practice.  相似文献   

14.
《文物保护研究》2013,58(4):251-268
Abstract

Extensive investigations of the deterioration of the romanesque painted wooden ceiling in the church of Saint Martin in Zillis (Switzerland) have revealed three major active deterioration phenomena: (1) tented flaking of paint layers; (2) flaking of the wheat starch fixative together with parts of the paint layer; and (3) fungal growth. These deterioration processes correlate with the dynamics of the prevailing room climate. Both forms of flaking are mainly driven by fluctuations of the relative humidity (RH), whereas the fungal attack can be related to high average RH and stagnant air. Frequent daily fluctuations in RH of up to 20% in summer are due to visitors leaving the doors open, while fluctuations of up to 25% are related to heating in winter. Given the risks of new consolidation treatments, the aim is to slow the decay processes by influencing the climate in the room. Installation of automatic door-closers reduced fluctuations but led to a rise in RH and a reduction of air movement, causing greater fungal growth. Subsequently, an automatic air-exchange system triggered by absolute humidity values was installed to reduce excess humidity and to exchange stale air without producing major fluctuations in the relative humidity. This kind of 'climatisation' has the advantage of being highly flexible, allowing variation of the rate and scale of exchange; it is, moreover, truly reversible.  相似文献   

15.
ABSTRACT

This work considers areas where our present lack of knowledge curtails the effectiveness or efficiency of preventive conservation practice. Mixed media, especially archaeological metals and organics have incompatible requirements for relative humidity (RH). An approach based on understanding the risk versus RH for both materials and considering the showcase performance is elucidated as a solution. Pollution, both the mixed atmospheres around most cultural heritage and the complex, variable nature of deposited particles, are further areas in need of more research. Damage functions and measurement of object deterioration rates are investigated as a path forward, and examples are given.  相似文献   

16.
ABSTRACT

The impact of relative humidity (RH) and temperature variation on the mechanical behaviour of paintings on canvas was investigated, based on the various environmental recommendations that are applied by museums and institutions worldwide. Paint samples were constructed based on the works of twentieth-century artists such as Soulages and Riopelle. The various samples are based on criteria such as paint media, additives, pigment type, canvas type, thickness, type of application, and drying time. Once they are fully dry, paint films behave as elastic, viscoelastic, or viscoplastic materials depending on the chemical nature of their components. These properties, as well as tensile strength, were determined by a series of tensile tests. Other samples were included, originating from discarded oil paintings on canvas from the seventeenth and nineteenth centuries. To carry out mechanical tests under controlled conditions of temperature and RH, a climatic chamber was built around the column of a universal testing machine. Samples were submitted to stress relaxation tests to observe their response to changes in environmental conditions. RH was increased from 20 to 90% and temperature from 15 to 60°C. Reactivity diagrams were drawn based on the results. The endurance limit under mechanical fatigue was determined from the diagrams and helped define the risks associated with each painting type when exposed to the accepted environmental recommendations.  相似文献   

17.
ABSTRACT

The National Museum of Ethnology, Osaka, Japan, collects a vast amount of materials and information related to peoples’ life and culture, and makes them available to society through exhibitions and other activities. The number of collected items is increasing every year: 343581 objects have been collected from Japan and abroad as of March 2017. The continuous efforts have been necessary to improve storage conditions and to save space for both general and special storerooms. The former, which account for 90% of the storage capacity of the museum, are air-conditioned during working hours, with temperature and relative humidity (RH) settings varying with the seasons. The latter, which house objects for which strict conservation conditions are required, are air-conditioned for 24 hours with fixed settings of temperature/RH throughout the year determined by the nature of the materials from which the objects have been made or formed. Storage re-organization began with special storerooms, for which the number of objects and the storage area are far more limited in comparison with the general storerooms. The storage shelves for fur/skin/feather (almost 1000 objects) and for carpets (almost 550 objects) were all renewed in FY2007/2008. Then two large-scale innovation projects for general storerooms were conducted: construction of storage areas for ships equipped with a CO2-based and anoxic pest treatment facility (FY2015), and a complete refurbishing of the general storeroom for large objects (FY2016). Windows were set in the corner of this storeroom to provide visitors an opportunity to view and learn about the museum activities. In parallel to the above projects, daily storage improvement efforts have been undertaken. Storeroom No. 3, chosen as an example for general storerooms for small and medium-sized objects, was used to investigate the range of issues related to the shelving arrangement and storage conditions. Guidelines for storage re-organization were formulated according to the results of the investigation and according to the experiences gained through the renewal of special storerooms. Storage re-organization undertaken in storeroom No. 3 was conducted for 6 years at the rate of around 2000–4000 objects per year with a low budget and with reuse of existing shelves. In FY2016, all objects in storeroom No. 3 were properly redistributed. About 40% of the storage space was saved. Over these 10 years of storage re-organization, preventive measures have been taken for sustainable collection management. As early as FY1992, pest trap investigations have been carried out seasonally. Since FY2004, the results of investigations have been analyzed using a customized computer program. Subsequently, appropriate integrated pest management measures have been taken. In addition, since FY2014, energy-efficient air-condition control has been adopted for general storerooms. It consists of switching off air-conditioning in spring and autumn, and of starting it only when the temperature or RH values become too high in summer or too low in winter. Because the turning-off of air-conditioning causes comparable or even less climatic fluctuation, it was considered acceptable both economically and from a conservation perspective. It is estimated that turning the air-conditioning off during transitional seasons brings cost savings of about 3000000–4000000 JPY (about 26800–35700 USD as of 23 September 2017) per annum, which accounts for almost 30% of the electricity expenditures for all general storerooms.  相似文献   

18.
Acid-detector (A-D) strips were originally developed to assess the deterioration of acetate film stock, but they can also be used more generally within enclosures to detect volatile acidic pollution. A hand-held reflectance spectrophotometer was used to record the colour of individual strips in order to make consistent and reproducible readings. Calibration was carried out using the yellow-blue axis b*(D65) value in the CIELAB1976 system to measure the colour of A-D strips suspended in enclosed containers over solutions of acetic acid in combinations with glycerol to control the relative humidity (RH). A-D strips were found to be sensitive to changes in high RH (60–90%) but affected little by changes in lower RH or temperatures in the museum display and storage range. A-D strips can be used to establish the presence of volatile acids, record the indication of acid vapour concentration, explore conditions within a container, and to find sources of volatile acidity. They respond very quickly and several can be placed around an object. They therefore show promise for measuring slowly changing conditions, such as seasonal changes and the gradual accumulation of acidity in poorly ventilated containers and spaces. A-D strips proved useful in assessing air quality in storage and display enclosures. Examples and test results are presented. Well-sealed plywood transit frames and storage cases were found to be most polluted with volatile acids. Storage rooms with air filtration systems but filled with wooden objects had significantly reduced air quality.  相似文献   

19.
ABSTRACT

Glass is often seen as a relatively stable material, unaffected by changes in environmental conditions, but recent studies indicate otherwise. Research on the atmospheric deterioration of glass has consistently shown a strong correlation between climate, especially relative humidity (RH), and the rate of deterioration. New studies by the authors have shown that even stable compositions are at risk, when the glasses are exposed to continuous broad fluctuations in RH and temperature. Letting standards slip for the long-term storage of glass can be devastating, eventually leading to irreversible damage that in the final stages can result in the complete destruction of an object. Current research and monitoring of collections at the Corning Museum of Glass indicates that the RH should be within the range of 40–50%. For already crizzled glasses, a tighter control to 40–42% is recommended. Analysis of compositions of already crizzled glasses is ongoing, and hopefully will lead to the identification of at least some groups of glasses that are more at risk. This will help in providing future environmental recommendations for identifiable compositions, selected glass types, or known manufacturers.  相似文献   

20.
ABSTRACT

Samples of conserved archaeological wood of different ages, origins, and conservation histories were aged in a climate chamber for seven months, while the humidity alternated between 30% RH for 12 hours and 80% RH for 12 hours at a constant temperature of 30°C. Photographs were taken once every hour, which enabled the creation of a time-lapse movie. Some samples degraded visibly, whereas others were unaffected. Most of the samples were robust and would be able to survive well even in a very poor museum climate. Among the sensitive samples, three types of degradation were identified, namely disintegration, pyrite oxidation, and efflorescence of white crystals. Disintegration was ascribed to dimensional changes caused by the RH alternations in very fragile wood. The white efflorescence was interpreted as the recrystallization of an alum-associated substance, possibly mercallite (KHSO4). The pyrite oxidation was observed as the efflorescence of a thick yellow, grey, and green powder. Characterization of selected samples was performed using X-ray fluorescence spectrometry, X-ray diffraction spectrometry, scanning electron microscopy with energy dispersive X-ray spectroscopy, inductively coupled plasma – optical emission spectroscopy, Fourier transform infrared spectroscopy, ionic conductivity – liquid chromatography, and pyrolysis-gas chromatography-mass spectrometry with in situ silylation using hexamethyldisilazane.  相似文献   

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