Comparison of oil and egg tempera paint systems using time-of-flight secondary ion mass spectrometry     

Zachary E. Voras  Kristin deGhetaldi  Brian Baade  Eric Gordon  Glenn Gates  Thomas P. Beebe 《文物保护研究》2016,61(4):222-235

Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is quickly becoming a critical tool in the field of art conservation. This technique provides high-resolution spatial maps of both inorganic and organic components located within cross-sectional samples collected from works of art. With recent advances in surface analysis, ToF-SIMS can now be used to identify specific amino acids present in protein-containing materials as well as fatty acids in drying oils. For example, the detection of the ion fragment associated with the amino acid hydroxyproline can be used to confirm the use of animal glue in a paint sample. As an analytical technique, ToF-SIMS avoids the need for derivatization/silylation reagents, with no interference by the presence of pigments. Furthermore, the layered systems that are often encountered in historical paint samples remain intact throughout the analytical procedure. This allows for the co-localization of organic and inorganic species in specific layers (e.g. egg yolk paint atop a glue ground). Because of this ability to localize the analytical signal to approximately 6?µm or less, the mass spectral information can be used to produce mass-resolved and spatially-resolve images which can be correlated to previous studies of the same samples. In this study, ToF-SIMS was used to analyze a paint cross section obtained from a painting attributed to Raphael, and another from a painting by the Sienese artist Matteo di Giovanni.  相似文献   

Predicting Use: COUNTER Usage Data Found to be Predictive of ILL Use and ILL Use to be Predictive of COUNTER Use     

Mitchell Scott 《期刊图书馆员》2016,71(1):20-24

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Rugby,Modernity and Controversy: Le P'tit Parigot (1926) by René Le Somptier     

Thomas Bauer 《Sport in History》2016,36(2):145-161

The history of sports literature has enjoyed renewed interest over the last few years, with a noticeable increase in the number of Anglo-Saxon works and the revival of French research. Through fiction, it is possible to understand the processes whereby ideas spread and collective imaginaries are constructed. In this regard, this article revisits the history of rugby union through the prism of a cine-novel, Le P'tit Parigot (1926), which was presented in serialised form via the newspaper L'Intransigeant and as a six-episode film in cinemas. It depicts the misfortunes of Georges Grigny-Latour, also known as the ‘P'tit Parigot’, son of an academic and captain of the French rugby union football team. This sport serial is a historical source of precious and useful information enabling us to address the representations of rugby at the time. The article aims to characterise the ambiguous identity of the sport during the Roaring Twenties, an identity that was torn between a Parisian spirit cultivating the idea of rugby as the inheritance of Anglo-Saxon values, and a provincial vision using it as a means of territorial expression.  相似文献   

The expected value of possession in professional rugby league match-play     

Thomas Kempton  Nicholas Kennedy  Aaron J. Coutts 《Journal of sports sciences》2016,34(7):645-650

This study estimated the expected point value for starting possessions in different field locations during rugby league match-play and calculated the mean expected points for each subsequent play during the possession. It also examined the origin of tries scored according to the method of gaining possession. Play-by-play data were taken from all 768 regular-season National Rugby League (NRL) matches during 2010–2013. A probabilistic model estimated the expected point outcome based on the net difference in points scored by a team in possession in a given situation. An iterative method was used to approximate the value of each situation based on actual scoring outcomes. Possessions commencing close to the opposition’s goal-line had the highest expected point equity, which decreased as the location of the possession moved towards the team’s own goal-line. Possessions following an opposition error, penalty or goal-line dropout had the highest likelihood of a try being scored on the set subsequent to their occurrence. In contrast, possessions that follow an opposition completed set or a restart were least likely to result in a try. The expected point values framework from our model has applications for informing playing strategy and assessing individual and team performance in professional rugby league.  相似文献   

Performance differences when using 26- and 29-inch-wheel bikes in Swiss National Team cross-country mountain bikers     

Thomas Steiner  Beat Müller  Thomas Maier  Jon Peter Wehrlin 《Journal of sports sciences》2016,34(15):1438-1444

The purpose of this study was to analyse the effect of bike type – the 26-inch-wheel bike (26“ bike) and the 29-inch-wheel bike (29“ bike) – on performance in elite mountain bikers. Ten Swiss National Team athletes (seven males, three females) completed six trials with individual start on a simulated cross-country course with 35 min of active recovery between trials (three trials on a 26“ bike and three trials on a 29“ bike, alternate order, randomised start-bike). The course consisted of two separate sections expected to favour either the 29“ bike (section A) or the 26“ bike (section B). For each trial performance, power output, cadence and heart rate were recorded and athletes’ experiences were documented. Mean overall performance (time: 304 ± 27 s vs. 311 ± 29 s; P < 0.01) and performance in sections A (P < 0.001) and B (P < 0.05) were better when using the 29“ bike. No significant differences were observed for power output, cadence or heart rate. Athletes rated the 29“ bike as better for performance in general, passing obstacles and traction. The 29“ bike supports superior performance for elite mountain bikers, even on sections supposed to favour the 26“ bike.  相似文献   

Positional group significantly influences the offensive and defensive skill involvements of junior representative rugby league players during match play     

Kyle J. M. Bennett  Job Fransen  Brendan R. Scott  Colin E. Sanctuary  Tim J. Gabbett  Ben J. Dascombe 《Journal of sports sciences》2016,34(16):1542-1546

This study examined the skill involvements of three positional groups across a junior representative rugby league season. Data were collected from 45 rugby league players (mean ± SD; age = 16.5 ± 1.0 years) currently participating in the Harold Matthews and SG Ball Cup. Players were subdivided into hit-up forwards, adjustables and outside backs. The frequency (n · min^?1) of offensive, defensive and overall involvements was coded for each group using a notation system and a practical coach skill analysis tool. Multivariate analysis of variance (MANOVA) revealed a significant effect of playing position on skill involvements (F = 9.06; P < 0.001; ES = 0.41). Hit-up forwards performed a significantly greater frequency of offensive (0.31 ± 0.10), defensive (0.42 ± 0.15) and overall involvements (0.74 ± 0.19) when compared to adjustables (0.20 ± 0.08, 0.28 ± 0.08 and 0.52 ± 0.15, respectively) and outside backs (0.20 ± 0.12, 0.11 ± 0.07 and ± 0.31 ± 0.17, respectively). Further, adjustables performed a significantly greater number of defensive (0.28 ± 0.08) and overall involvements (0.52 ± 0.15) when compared to outside backs (0.11 ± 0.07 and 0.31 ± 0.17, respectively). The findings of this study suggest that it is important to consider a junior player’s positional group when analysing their skill involvements. Information gained from this study could assist in the design of specific training methodologies for junior rugby league players in high-level talent development programmes.  相似文献   

Cuba’s Challenges Hosting the 1991 Pan-American Games and the Spectacle of the Revolution’s ‘Soft Power’     

Thomas F. Carter 《国际体育史杂志》2016,33(1-2):186-202

Abstract

This paper examines the confluence of global, regional, and national politics in the lead up to the 1991 Pan-American Games hosted by Cuba. Cuba’s contentious selection as host was wholly underpinned by the international politics of the time. Once selected, the preparations for the Games in Havana were surrounded by an unprecedented domestic economic crisis fueled by shifts in global politics. This paper analyzes how international politics informed the hosting of the 1991 Pan-American Games, and shaped the political challenge the Cuban government faced in hosting such an event. The Revolution’s use of sport domestically and internationally came to the forefront in its efforts as host and the results of those efforts proved to be providential given the emerging political economic contexts during and in the ensuing years after the Games.  相似文献   

Validity of Self-Reported Pedometer Steps per Day in College Students     

Brittany Star Overstreet  Scott E. Crouter  George A. Butler  Cary M. Springer  David R. Bassett 《Measurement in physical education and exercise science》2016,20(3):140-145

The purpose of this article was to examine the validity of self-reported pedometer steps/day. Forty-seven participants were provided a New Lifestyles NL-2000 (NL-2000; Lees Summit, MO, USA) pedometer and a physical activity (PA) diary for 3 weeks, but not informed of the data-storing capabilities. For weeks 2 and 3, each participant was given a step goal of 3,000 steps/day above week 1 average. A 2 × 3 repeated measures analysis of variance (ANOVA) was used to examine differences between reported steps/day. Bland–Altman plots assessed the mean bias and limits of agreement between reporting methods. Mean self-reported and NL-2000 steps/day were 9,264 ± 3,555 and 8,971 ± 3,590 steps/day (n = 26, p > .05). Mean biases were 216 ± 1,753 (week 1), –506 ± 1,355 (week 2), and –590 ± 1,360 (week 3) steps/day. Negative mean bias values indicate higher self-reported steps/day. Mean steps/day were similar between recording methods, but large differences were observed among individuals, suggesting self-reported steps/day may be valid for PA research at the population level, but not the individual level.  相似文献   

An Examination and Validation of an Adapted Youth Experience Scale for University Sport     

Scott Rathwell  Bradley W. Young 《Measurement in physical education and exercise science》2016,20(4):208-219

Limited tools assess positive development through university sport. Such a tool was validated in this investigation using two independent samples of Canadian university athletes. In Study 1, 605 athletes completed 99 survey items drawn from the Youth Experience Scale (YES 2.0), and separate a priori measurement models were evaluated (i.e., 99 items, YES 2.0, YES for Sport [YES-S]). Confirmatory factor analysis (CFA) and exploratory structural equation modeling (ESEM) results indicated issues with model fit. Post-hoc modifications improved fit, resulting in a 46-item, 9-factor model with five positive and four negative dimensions. In Study 2, 511 athletes completed the same items. The resultant model was confirmed using both CFA (comparative fit index [CFI] = .911, standardized root mean square residual [SRMR] = .056, root mean square error of approximation [RMSEA] = .040) and ESEM (CFI = .956, SRMR = .023, RMSEA = .034). The resultant University Sport Experience Survey provides a reliable and factorially valid instrument for measuring development in university sport.  相似文献   

Carbohydrate mouth rinse and caffeine improves high-intensity interval running capacity when carbohydrate restricted     

Andreas M. Kasper  Scott Cocking  Molly Cockayne  Marcus Barnard  Jake Tench  Liam Parker 《European Journal of Sport Science》2016,16(5):560-568

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