微型化学实验测定化学反应速度常数     

张姣姣  申德君 《贵阳学院学报(自然科学版)》2006,1(1):36-38

用微型化学实验和常规化学实验测定化学反应速率常数,在误差允许范围内比较微型化学实验的优越性.  相似文献   

对单分子反应机理的探索     

张曼华 《贵阳学院学报(自然科学版)》2006,1(2):8-11

化学动力学的主要问题之一,是对单分子反应一级动力学作出解释.以Lindemann历程为基础,阐明单分子反应机理的动力学特征,并指出只有在整个反应是一级和三级混合在一起的降变过程,才是真正的Lindemann历程.  相似文献   

Evaluation of adverse drug reaction formatting in drug information mobile phone applications     

Sean M. McConachie  Dena Berri  Jewel Konja  Christopher A. Giuliano 《Journal of the Medical Library Association》2022,110(1):81

Objective:To evaluate the differences in presentation (formatting) of adverse drug reaction (ADR) information within drug monographs in commonly used drug information (DI) mobile device applications.Methods:A cross-sectional analysis of ADR formatting of twenty commonly prescribed oral medications within seven DI mobile applications was performed. Databases were assessed for ADR information, including presence of placebo comparisons, severity of ADR, onset of ADR, formatting of ADRs in percentile (quantitative) format or qualitative format, whether references were used to cite information, and whether ADRs are grouped by organ system. Data was collected by two study investigators and discrepancies were resolved via consensus.Results:The seven DI mobile applications varied significantly on every analyzed ADR variable with the exception of ADR onset, which was absent in all databases. Significant differences were found for variables known to impact clinical judgment such as placebo comparisons and qualitative versus quantitative formatting. Placebo comparisons were most common among monographs in Lexicomp (30%) but were absent among monographs within other applications. Quantitative information was commonly used in most databases but was absent in Epocrates. Qualitative formatting was present in all Epocrates and Micromedex applications but absent in the majority of other applications. Substantial variations were also found in severity and grouping information.Conclusion:Substantial variation in ADR formatting exists among the most common DI mobile applications. These differences may translate into alternative interpretations of medical information and thus impact clinical judgment. Health care librarians and clinicians should consider ADR formatting when choosing between DI applications.  相似文献   

NiCo_2O_4纳米结构阵列的水热合成与氧析出特性研究     

陈传胜  张作胜  陈伟杰  乔浏 《安徽职业技术学院学报》2020,(1):16-19,41

钴酸镍纳米材料具有良好的电催化氧析出反应(Oxygen Evolution Reaction,OER)活性,是一种很有发展潜力的非贵金属电催化材料。文章以碳纤维纸为基底,采用水热合成的方法对纳米结构钴酸镍的生长进行了系统的研究,分别考察了生长温度、前驱体浓度和配比、生长时间对产物的形貌、尺寸、物相结构、OER电化学性能的影响,通过对比分析后发现在生长温度100℃、生长时间5h、镍钴比为2:1时所获得的多孔片状钴酸镍纳米结构具有最佳的OER特性。  相似文献   

MINRES法和有限元法解奇摄动反应扩散方程     

尹军伟  陈玉福 《中国科学院研究生院学报》2008,26(6):721-725

讨论奇摄动反应扩散方程 的数值逼近求解问题, 及 均为正实数. 利用有限元方法并结合最小残量法, 给出求解该问题的一个新方 法, 该方法修正了单纯采用有限元方法求解时在边界附近呈现出的非正常扰动的 现象, 避免了因为 过小所引起的解的变异, 从而得到更加精确的数值结果.  相似文献   

固定化脂肪酶合成蔗糖月桂酸酯的研究     

李云凯  张志众  程磊 《唐山学院学报》2014,(3):84-86

以固定化脂肪酶为催化剂,以DMSO/叔丁醇有机溶剂为反应体系,在室温条件下催化合成蔗糖酯。研究表明:月桂酸与蔗糖的摩尔比为大于8,反应温度为30℃,脂肪酶用量为0.3g,缓冲液的pH值为7.5,反应6h时,酯化反应的相对转化率较高。反应产物的薄层色谱和红外光谱分析结果证实所合成的产物为蔗糖月桂酸酯。  相似文献   

2-（4-甲硫苯氧基）-5-芳基亚甲基-4H-咪唑啉-4-酮衍生物的合成及杀菌活性     

孙勇  黄明权  朱圣平  丁宗庆  周新 《郧阳师范高等专科学校学报》2003,23(3):29-32

研究了应用烯基膦亚胺1与间氯苯基异氰酸酯、对甲硫苯酚的串联aza-Wittig反应,来合成2-(4-甲硫基苯氧基)-5-芳基亚甲基-4H-咪唑啉-4-酮衍生物3的方法.探讨了反应进行的条件和产物的波谱性质,提出了可能的环化反应机理.生成的环化产物均为新的化合物,其结构经元素分析、IR、~1HNMR和MS确正.并探讨了所合成的新型杂环化合物的生物活性,结果表明部分化合物表现出良好的抑菌活性,其中以3e及3f活性最好,在质量分数5×10~(-5)时,对水稻纹枯菌和苹果轮纹菌的抑制率均达到85％～95％的A级水平.  相似文献   

影响男子排球运动员扣球起跳动作效果的 动力学研究          下载免费PDF全文

贾谊 《河北体育学院学报》2017,31(5):64-70

目的:研究男子排球运动员扣球起跳蹬地动作过程中,人体下肢的相关力学参数特征.对象:男子大学生排球运动员10名.方法:使用高速人体动作捕捉系统及三维测力台,对相关运动学和动力学参数进行采集.结果:①起跳过程中,地面反作用力峰值和均值均为优势腿大于非优势腿;②非优势腿地面反作用力峰值与重心最大高度呈高度负相关(r=-0.961,P=0.002＜0.05);③双脚同时着地过程中,优势腿地面反作用力冲量明显大于非优势腿,两脚地面反作用力冲量差与重心最大高度呈显著负相关(r=-0.531,P=0.034＜0.05).结论:①在后排起跳过程中,优势腿与非优势腿表现出不同的用力形式;②应当通过适当控制非优势腿在着地初期的制动作用,并在双脚最后用力阶段有意识地提高非优势腿的参与程度,以提高人体的起跳高度;③排球运动员髌腱炎的发病可能与踝关节绕矢状轴力矩和膝关节绕垂直轴力矩较大有关.  相似文献   

Postural stability,clicker reaction time and bow draw force predict performance in elite recurve archery     

Wayne Spratford  Rhiannon Campbell 《European Journal of Sport Science》2017,17(5):539-545

Recurve archery is an Olympic sport that requires extreme precision, upper body strength and endurance. The purpose of this research was to quantify how postural stability variables both pre- and post-arrow release, draw force, flight time, arrow length and clicker reaction time, collectively, impacted on the performance or scoring outcomes in elite recurve archery athletes. Thirty-nine elite-level recurve archers (23 male and 16 female; mean age?=?24.7?±?7.3 years) from four different countries volunteered to participate in this study prior to competing at a World Cup event. An AMTI force platform (1000Hz) was used to obtain centre of pressure (COP) measurements 1s prior to arrow release and 0.5s post-arrow release. High-speed footage (200Hz) allowed for calculation of arrow flight time and score. Results identified clicker reaction time, draw force and maximum sway speed as the variables that best predicted shot performance. Specifically, reduced clicker reaction time, greater bow draw force and reduced postural sway speed post-arrow release were predictors of higher scoring shots. It is suggested that future research should focus on investigating shoulder muscle tremors at full draw in relation to clicker reaction time, and the effect of upper body strength interventions (specifically targeting the musculature around the shoulder girdle) on performance in recurve archers.  相似文献   

Kinematic and kinetic analysis of overhand,sidearm and underhand lacrosse shot techniques     

Charles A. J. Macaulay  Pro Stergiou  Darren Stefanyshyn  Luciano Tomaghelli 《Journal of sports sciences》2017,35(23):2350-2356

Lacrosse requires the coordinated performance of many complex skills. One of these skills is shooting on the opponents’ net using one of three techniques: overhand, sidearm or underhand. The purpose of this study was to (i) determine which technique generated the highest ball velocity and greatest shot accuracy and (ii) identify kinematic and kinetic variables that contribute to a high velocity and high accuracy shot. Twelve elite male lacrosse players participated in this study. Kinematic data were sampled at 250 Hz, while two-dimensional force plates collected ground reaction force data (1000 Hz). Statistical analysis showed significantly greater ball velocity for the sidearm technique than overhand (P < 0.001) and underhand (P < 0.001) techniques. No statistical difference was found for shot accuracy (P > 0.05). Kinematic and kinetic variables were not significantly correlated to shot accuracy or velocity across all shot types; however, when analysed independently, the lead foot horizontal impulse showed a negative correlation with underhand ball velocity (P = 0.042). This study identifies the technique with the highest ball velocity, defines kinematic and kinetic predictors related to ball velocity and provides information to coaches and athletes concerned with improving lacrosse shot performance.  相似文献