溅射法在不同O2／Ar比例下制备HfO2薄膜     

马紫微 《运城学院学报》2011,(5):25-28,35

作为一种性能稳定的绝缘体,HfO2在电子、光学以及能量相关的领域中有着重要的应用。在本工作中,我们使用反应溅射方法在不同O2／Ar比例下制备了HfO2薄膜。XRD结果显示,O2／At比例并不能明显的影响样品的结构。通过Debye—Schener公式估计,样品由纳米晶粒组成。在O2／Ar比例为0．06（功率12W）时制备的样品最接近化学配比。在可见光区域,样品具有很好的透光率,T〉85％。明显的吸收发生在波长小于220nm时。通过Tauc公式可以估算出,样品的带隙在5．051到5．547eV范围内变化。  相似文献   

股份制商业银行内部控制对操作风险防范的促进性研究——基于信息化创新视角的数据检验     

李光绪  高文香  张同健 《郧阳师范高等专科学校学报》2011,31(3):56-60

操作风险控制是我国股份制商业银行所面临的一项重要风险．内部控制是操作风险控制的基础性策略,信息系统是银行的常规性运营平台．基于信息化创新的视角,借助于结构方程模型,实证性的检验揭示了股份制商业银行内部控制对操作风险控制的促进性机理,发现了股份制商业银行操作风险控制的独特性规律．从而为操作风险控制实施的深化提供了现实性的理论指导．  相似文献   

甘蔗糖蜜酒精生产中的废水治理——粗馏残液中悬浮固相的成份、来源及利用     

李德光  李羚  李丽 《保山师专学报》2011,30(5):20-23

酒精粗馏残液中含有一部分固相悬浮物,将残液进行固液分离,并分别加以利用和治理,也许是酒精粗馏残液治理的一条有效途径。本文对残液中固相悬浮物的化学成分及来源进行了分析和阐述,并提出将分离后得到的固相沉淀物直接用作水泥缓凝剂或农作物的间接肥料。  相似文献   

用平面波法计算光子晶体光纤     

孙长伟  王艳春  霍亮 《茂名学院学报》2011,21(6):35-37,46

本文讨论了平面波法在光子晶体光纤中的应用,在光子晶体光纤的横截面内选取包含芯层的一个大晶格,形成一个假想的二维周期结构,用平面波将模式磁场展开．就可以求解任意横截面光纤中的麦克斯韦方程。  相似文献   

固体超强酸SO₄^2-/ZrO₂-Al₂O₃的制备及催化酯化反应性能研究   总被引：1，自引：0，他引：1  

訾俊峰 《许昌学院学报》2011,30(5):87-89

制备了固体超强酸SO42-/ZrO2-Al2O3,并将其作为催化剂应用于乙酸正丙酯的合成.结果表明,SO42-/ZrO2-Al2O3对乙酸正丙酯的合成有较好的催化活性,酯化率可以达到98%以上.  相似文献   

Paving the road toward the use of β-Fe2O3 in solar water splitting: Raman identification,phase transformation and strategies for phase stabilization     

Ningsi Zhang  Xin Wang  Jianyong Feng  Huiting Huang  Yongsheng Guo  Zhaosheng Li  Zhigang Zou 《国家科学评论(英文版)》2020,7(6):1059

Although β-Fe₂O₃ has a high theoretical solar-to-hydrogen efficiency because of its narrow band gap, the study of β-Fe₂O₃ photoanodes for water splitting is elusive as a result of their metastable nature. Raman identification of β-Fe₂O₃ is theoretically and experimentally investigated in this study for the first time, thus clarifying the debate about its Raman spectrum in the literature. Phase transformation of β-Fe₂O₃ to α-Fe₂O₃ was found to potentially take place under laser and electron irradiation as well as annealing. Herein, phase transformation of β-Fe₂O₃ to α-Fe₂O₃ was inhibited by introduction of Zr doping, and β-Fe₂O₃ was found to withstand a higher annealing temperature without any phase transformation. The solar water splitting photocurrent of the Zr-doped β-Fe₂O₃ photoanode was increased by 500% compared to that of the pure β-Fe₂O₃ photoanode. Additionally, Zr-doped β-Fe₂O₃ exhibited very good stability during the process of solar water splitting. These results indicate that by improving its thermal stability, metastable β-Fe₂O₃ film is a promising photoanode for solar water splitting.  相似文献   

A highly alkaline-stable metal oxide@metal–organic framework composite for high-performance electrochemical energy storage     

Shasha Zheng  Qing Li  Huaiguo Xue  Huan Pang  Qiang Xu 《国家科学评论(英文版)》2020,7(2):305

Most metal–organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to alkaline aqueous solutions, thus precluding their use as potential electrode materials for electrochemical energy storage devices. Here, we present the design and synthesis of a highly alkaline-stable metal oxide@MOF composite, Co₃O₄ nanocube@Co-MOF (Co₃O₄@Co-MOF), via a controllable and facile one-pot hydrothermal method under highly alkaline conditions. The obtained composite possesses exceptional alkaline stability, retaining its original structure in 3.0 M KOH for at least 15 days. Benefitting from the exceptional alkaline stability, unique structure, and larger surface area, the Co₃O₄@Co-MOF composite shows a specific capacitance as high as 1020 F g⁻¹ at 0.5 A  g⁻¹ and a high cycling stability with only 3.3% decay after 5000 cycles at 5 A g⁻¹. The as-constructed solid-state flexible device exhibits a maximum energy density of 21.6 mWh cm⁻³.  相似文献   

浅谈对专业化舞台灯光的认识     

伊天夫  叶皛 《演艺科技》2020,(1):13-17

结合多个灯光设计案例,阐述对专业化舞台灯光的认识,包括如何推动高品质、高质量的专业化舞台灯光发展,当代灯光技术进步对灯光设计师提出的新要求、对灯光设备及灯光厂家的要求等。  相似文献   

Programmable deformation of patterned bimorph actuator swarm     

Jia-Nan Ma  Yong-Lai Zhang  Dong-Dong Han  Jiang-Wei Mao  Zhao-Di Chen  Hong-Bo Sun 《国家科学评论(英文版)》2020,7(4):775

Graphene-based actuators featuring fast and reversible deformation under various external stimuli are promising for soft robotics. However, these bimorph actuators are incapable of complex and programmable 3D deformation, which limits their practical application. Here, inspired from the collective coupling and coordination of living cells, we fabricated a moisture-responsive graphene actuator swarm that has programmable shape-changing capability by programming the SU-8 patterns underneath. To get better control over the deformation, we fabricated SU-8 micropattern arrays with specific geometries and orientations on a continuous graphene oxide film, forming a swarm of bimorph actuators. In this way, predictable and complex deformations, including bending, twisting, coiling, asymmetric bending, 3D folding, and combinations of these, have been achieved due to the collective coupling and coordination of the actuator swarm. This work proposes a new way to program the deformation of bilayer actuators, expanding the capabilities of existing bimorph actuators for applications in various smart devices.  相似文献   

Large-scale multiferroic complex oxide epitaxy with magnetically switched polarization enabled by solution processing     

Cong Liu  Feng An  Paria S M Gharavi  Qinwen Lu  Junkun Zha  Chao Chen  Liming Wang  Xiaozhi Zhan  Zedong Xu  Yuan Zhang  Ke Qu  Junxiang Yao  Yun Ou  Zhiming Zhao  Xiangli Zhong  Dongwen Zhang  Nagarajan Valanoor  Lang Chen  Tao Zhu  Deyang Chen  Xiaofang Zhai  Peng Gao  Tingting Jia  Shuhong Xie  Gaokuo Zhong  Jiangyu Li 《国家科学评论(英文版)》2020,7(1):84

Complex oxides with tunable structures have many fascinating properties, though high-quality complex oxide epitaxy with precisely controlled composition is still out of reach. Here we have successfully developed solution-based single-crystalline epitaxy for multiferroic (1-x)BiTi_(1-y)/2Fe_yMg_(1-y)/2O₃–(x)CaTiO₃ (BTFM–CTO) solid solution in large area, confirming its ferroelectricity at the atomic scale with strong spontaneous polarization. Careful compositional tuning leads to a bulk magnetization of 0.07 ± 0.035 μ_B/Fe at room temperature, enabling magnetically induced polarization switching exhibiting a large magnetoelectric coefficient of 2.7–3.0 × 10⁻⁷ s/m. This work demonstrates the great potential of solution processing in large-scale complex oxide epitaxy and establishes novel room-temperature magnetoelectric coupling in epitaxial BTFM–CTO film, making it possible to explore a much wider space of composition, phase, and structure that can be easily scaled up for industrial applications.  相似文献