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NomenclatureCsh—solventconcentrationinanascenthollowfiber ( g·cm-3 )fo—dragcoefficientattheexternalsurfaceofanascenthollowfiberF( γE)—materialfunctiondefined (Eq .( 2 ) )g—gravitationalfunction ( 980cm·s-2 )G(Csh)—materialfunctiondefined (Eq .( 2 ) )Ho—thecombinedreciprocalradiiofthecurvaturesattheouterskinofthenascenthollowfiber (cm-1)L—air gapdistance (cm )Ri—innerradiusofanascenthollowfiber (cm)Ro—outerradiusofanascenthollowfiber (cm)R′o,R″o—thefirstandsecondorderderivat… 相似文献
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In an effort to find the effect of mass transfer ,surface tesion and drag forces on the velocity distribution,the mathematical model of the velocity profile of a nascent hollow fiber during membrane formation in the air gap region was numerically simulated by using the Runge-Kutta method (fourth-order method).The effect of mass transfer on velocity distribution based on the complicated function(G(Ch^s))was presented and the dffects of a complicated function were studied in two cases:in the first case,G(Ch^s) was constant;in the second,G(Ch^s) was variable.The latter was done by varying with the concentration of solvent in a nascent hollow fiber through the air-gap region.One empirical equation was used to describe this change and the predected values had a better agreement with the experimental values.To verify the moedl hypotheses,hollow fiber membranes were spun from 20:80 polybenzimidazole/polyetherimide dopes with 25.6 wt％ solid in N,N-dimethylacetamide (DMAc) using water as the external and internal coagulants.Based on the experimental results of dry-jet wet-spinning process for the fabrication of hollow fiber membranes,it is found that the model calculated values were in a good agreement with the experimental values. 相似文献
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