排序方式: 共有4条查询结果,搜索用时 12 毫秒
1
1.
2.
目的对我国某水域的海鱼和淡水鱼样品开展二噁英污染水平与同系物轮廓表征研究,并评估该典型地区人群通过鱼暴露二噁英的膳食摄入量.方法通过布点抽样采集8个养殖点(海水与淡水各半)31份样品,以同位素稀释的HRGC/HRMS-多离子检测方式测定样品中的PCDDs/Fs.结果海水养殖鱼和淡水养殖鱼中PCDD/Fs平均浓度以湿重计分别为1.43和3.34pg/g,以WHO-TEQ计分别为0.28pg/g和0.43pg/g.OCDD、2,3,7,8-TCDF为最主要的优势污染同系物;如以毒性的主要贡献者计,则以1,2,3,7,8-PeCDD、2,3,4,7,8-PeCDF、2,3,7,8-TCDD为主.该地区人群摄入鱼的二噁英PCDD/Fs的平均膳食暴露量的估算是0.63pgWHO-TEQ/kg BW·day.结论该水域中的鱼已受到了一定程度的PCDD/Fs污染,淡水养殖高于海水养殖(约为1倍).鱼体中所检测到的二噁英污染的平均水平低于欧盟制定的限量标准(1.0pg WHO-TEQ/g). 相似文献
3.
目的:对我国某水域的海鱼和淡水鱼样品开展二噁英污染水平与同系物轮廓表征研究,并评估该典型地区人群通过鱼暴露二噁英的膳食摄入量。方法:通过布点抽样采集8个养殖点(海水与淡水各半)31份样品,以同位素稀释的HRGC/HRMS-多离子检测方式测定样品中的PCDDs/Fs。结果:海水养殖鱼和淡水养殖鱼中PCDD/Fs平均浓度以湿重计分别为1.43和3.34pg/g,以WHO-TEQ计分别为0.28pg/g和0.43Pg/g。OCDD、2,3,7,8-TCDF为最主要的优势污染同系物;如以毒性的主要贡献者计,则以1,2,3,7,8-PeCDD、2,3,4,7,8-PeCDF、2,3,7,8-TCDD为主。该地区人群摄入鱼的二噁英PCDD/Fs的平均膳食暴露量的估算是0.63PgWHO-TEQ/kg BW-day。结论:该水域中的鱼已受到了一定程度的PCDD/Fs污染,淡水养殖高于海水养殖(约为1倍)。鱼体中所检测到的二噁英污染的平均水平低于欧盟制定的限量标准(1.0PgWHO-TEQ/g)。 相似文献
4.
Objective:PCDD/Fs level in 22 fish samples was investigated in Pearl river Delta area in order that the PCDD/Fs pollution level in common fish can be evaluated. Methods: Dibenzo-p-Dioxins and Dibenzo-Furans was extracted from the sample by Soxhlet extraction, concentrated then purified by column chromatography, carbon column enrichment,. Confirmation and quantitative analysis at ppt(pg/g) level of PCDD/Fs was performed by HRGC/HRMS using multiple ion detection mode(MID). Certified reference material using Proficiency test sample fish muscle test material 0613 that was obtained from Central Science Laboratory(CSL) in Britain. Results: The average of concentration in wet weight is 1.261 ng/kg,, the average total WHO-TEQ for 22 samples is 0.246ng/kg wet weight. Generally, OCDD, 2,3,7,8-TCDF,1,2,3,4,6,7,8-HpCDD was the main contributors to the total 17 PCDD/Fs detected, average account for 21%,16%,14%, respectively. While 1,2,3,7,8-PeCDD, 2,3,4,7,8-PeCDF, 2,3,7,8-TCDD were main contributors to the total WHO-TEQ, account for 40%,27%,13% respectively. The total TEQ for 22 fishes ranged from 0.03ng/kg wet weight to 0.878 ng/kg wet weight. Conclusions: PCDD/Fs level was largely different from sample to sample depending on the sample kinds. The level in the Pearl river Delta area fish samples is not distinct comparing with other countries, but some kind fish level should be paid more attention on it since its higher level. The relationship between source of PCDD/Fs and PCDD/Fs level in fish will be studied deeply in the future. 相似文献
1