耗散颗粒动力学模拟油水体系相行为     

曹晓荣 《山东教育学院学报》2010,25(6):29-32

用耗散颗粒动力学模拟方法（Dissipative Particle Dynamics,DPD）研究了油分子量、油分子浓度、剪切及表面活性剂SDS（十二烷基硫酸钠）对油水体系相行为的影响.发现随着油分子量的增加,油水界面张力增加;随着油浓度的增加,体系由最初的水包油聚集状态逐渐演变为油水分层状态.随着剪切速率的加大,油滴被逐渐拉长,最后断裂;表面活性剂加入油水体系后,以亲水头基伸入水相、疏水尾巴伸入油相的方式分布在油水界面上.  相似文献   

Detection of Hydrogen Peroxide Photogenerating from a Hypocrellin B Derivative     

刘光艳  马江华 《天津大学学报(英文版)》2003,9(2):144-147

Hypocrellins,includinghypocrellinA (HA)andhypocrellinB (HB) (Fig .1) ,arenewtypesofphoto sensitivepigments growingabundantlyinChina[1,2 ] .Theyexhibitseveraladvantagesoverhaematoporphyrinderivatives (HPDs) presentlyusedinclinics[3] .Howev er,hypocrellinsarelipophilicagentsandexhibitweakab sorptioninthe phototherapeuticwindow (6 0 0— 90 0nm) ,whichpreventsfurtherinvestigationsontheirbio logicalconsequencesandlimitstheirPDTapplicationclinically .Fig .1　Chemicalstructuresofhypocrellinpare…  相似文献   

A Critical Review on Clinical Application of Separation Techniques for Selective Recognition of Uracil and 5-Fluorouracil     

Khushaboo Pandey  Rama Shankar Dubey  Bhim Bali Prasad 《Indian journal of clinical biochemistry : IJCB》2016,31(1):3-12

The most important objectives that are frequently found in bio-analytical chemistry involve applying tools to relevant medical/biological problems and refining these applications. Developing a reliable sample preparation step, for the medical and biological fields is another primary objective in analytical chemistry, in order to extract and isolate the analytes of interest from complex biological matrices. Since, main inborn errors of metabolism (IEM) diagnosable through uracil analysis and the therapeutic monitoring of toxic 5-fluoruracil (an important anti-cancerous drug) in dihydropyrimidine dehydrogenase deficient patients, require an ultra-sensitive, reproducible, selective, and accurate analytical techniques for their measurements. Therefore, keeping in view, the diagnostic value of uracil and 5-fluoruracil measurements, this article refines several analytical techniques involved in selective recognition and quantification of uracil and 5-fluoruracil from biological and pharmaceutical samples. The prospective study revealed that implementation of molecularly imprinted polymer as a solid-phase material for sample preparation and preconcentration of uracil and 5-fluoruracil had proven to be effective as it could obviates problems related to tedious separation techniques, owing to protein binding and drastic interferences, from the complex matrices in real samples such as blood plasma, serum samples.  相似文献