The effect of modifiers on the stability of a vinyl acetate/ethylene copolymer dispersion     

Jane L. Down 《文物保护研究》2016,61(1):26-45

This paper examines the effect of modifiers on the stability of a vinyl acetate/ethylene copolymer dispersion adhesive upon aging. Eighteen common modifiers were added to a well-characterized vinyl acetate/ethylene copolymer dispersion (Dur-O-Set^® E-150) in known concentrations and dry-film samples were subjected to 16–17 years of dark aging and seven to eight years of light aging. Yellowing, pH, gloss, swelling, cohesive strength, and flexibility were monitored for changes upon aging. Generally, the neat Dur-O-Set^® E-150 (no additives) was found to become acidic on aging, but was fairly resistant to yellowing. It also swelled substantially in toluene, was of high gloss, medium strength, and flexible, and remained so on aging. No modifier was found to improve these properties. Various solvents, wetting agents, and thickeners did not alter the properties by much, while plasticizers, freeze-thaw stabilizer, glycerin, and certain fillers had a more negative effect.  相似文献   

醋酸钙镁冰雪融化剂的制备及融冰效果小试   总被引：2，自引：0，他引：2  

肖进兵  邢军  孙永正  王景昌  徐海燕 《大连大学学报》2003,24(4):32-34

本文制备了醋酸钙美(CMA) 冰雪融化剂并在实验室小试了其融冰能力,并与氯化钠和氰化钙进行了比较。结果表明,CMA组成和环境温度对CMA融冰效果有很大影响。CMA适宜在环境温度-11℃以上使用,CMA中钙镁比为7:3时,融冰能力可以达到氯化钠和氯化钙的75％～80％,是一种优良的冰雪融化剂。  相似文献   

磷钨杂多酸催化合成乙酸正己酯     

朱蕾 《许昌学院学报》2007,26(2):115-117

以磷钨杂多酸为催化剂,通过乙酸和正己醇的酯化反应合成了乙酸正己酯,并对影响酯化率的因素进行了研究.结果表明:反应的最佳条件为:乙酸为0.1 mol时,醇酸物质的量比为1.4,催化剂用量为0.3 g,带水剂为15 mL,在温度为110~130℃下,反应30 min,酯化率可达99.6%以上.  相似文献   

3,7-二甲基-2-十三碳醇乙酸酯的合成——松叶蜂Diprion pini性信息素活性组分     

孟祎  陈立功  许艳杰  古险峰  宋芸 《天津大学学报(英文版)》2001,7(4):282-285

对松叶蜂 diprion pini性信息素活性组分 3,7-二甲基 -2 -十三碳醇乙酸酯的全合成进行了研究 .以丙二酸二乙酯和 2 ,3-环氧丁烷为原料 ,分别合成了两个重要结构单元—— 2 -甲基 -1-辛烷基锂和 3,4-二甲基 -γ-丁内酯 .2 -甲基 -1-辛烷基锂与 3,4-二甲基 -γ-丁内酯反应 ,得到的酮醇再经黄鸣龙还原 ,得到 3,7-二甲基 -2 -十三碳醇 ,经酯化 ,得到 3,7-二甲基 -2 -十三碳醇乙酸酯  相似文献   

一水合硫酸氢钠催化合成乙酸正己酯   总被引：2，自引：2，他引：2  

朱蕾 《许昌学院学报》2003,22(2):47-48

研究了以硫酸氢钠为催化剂，乙酸和正己醇为原料合成乙酸正己酯，并考察了反应条件对酯化率的影响．结果表明，在适宜条件下其酯化率可达97．6％．  相似文献   

稀土复合固体超强酸SO_4~(2-)/TiO_2/Ce~(4+)催化合成乙酸环己酯及动力学研究     

邓斌  梁超伦  陈六平 《湘南学院学报》2007,28(5):62-66

研究了以稀土复合固体超强酸SO42-/TiO2/Ce4+为催化剂合成乙酸环己酯的反应,在反应温度分别为100℃、110℃、120℃下,测出酯化反应的动力学参数,建立了动力学方程,并与无催化剂作用下合成乙酸环己酯反应的活化能及动力学方程进行了比较.实验结果表明,该催化酯化反应的优化合成条件是:乙酸用量为0.262 1mol时,醇酸摩尔比为1.5:1,催化剂用量为1.0g,带水剂环己烷的加入量为12mL.稀土复合固体超强酸SO42-/TiO2/Ce4+可使反应的活化能明显降低,是合成乙酸环己酯的有效催化剂.  相似文献   

乙烯的制备及性质实验的改进     

任有良  张国春  陈凤英 《商洛学院学报》2011,25(6):34-37

在制备乙烯的反应物中加入少量的三氧化二铁和氧化锌的混合物,可使反应平稳,副反应减少,产率显著提高。防爆燃烧管和改良导管等创新器具的使用,不仅使燃烧更加安全,褪色现象更加明显,而且减少了乙烯的用量,提高了乙烯的利用效率。  相似文献   

光声光谱技术进行气体检测研究综述   总被引：2，自引：0，他引：2  

逯美红  郝瑞宇  王志军  何春乐  周小芳 《长治学院学报》2011,28(5)

光声光谱技术是近几年发展起来的一种以光声效应为基础的新型光谱分析检测技术。基于其极高的检测灵敏度,已成为一种快速、安全、可靠、有效的微量气体检测技术手段。文章对光声光谱气体检测的基本原理及其在气体检测研究中的最新进展进行了概括和总结,并对其在乙烯等果蔬气体检测中的研究前景进行了分析。  相似文献   

A multiple-dose pharmacokinetics of polyethylene glycol recombinant human interleukin-6 (PEG-rhIL-6) in rats     

He XL  Yin HL  Wu J  Zhang K  Liu Y  Yuan T  Rao HL  Li L  Yang G  Zhang XM 《Journal of Zhejiang University. Science. B》2011,12(1):32-39

Radiation therapy has been widely applied in cancer treatment. However, it often causes thrombocytopenia (deficiency of white blood cells) as an adverse effect. Recombinant human interleukin-6 (rhIL-6) has been found to be a very effective way against this thrombocytopenia, but IL-6 has low stability in blood, which reduces its efficacy. To increases the stability and half-life of rhIL-6, it was modified by polyethylene glycol (PEG). The pharmacokinetics and the tissue distribution of PEG-rhIL-6 labeled with ¹²⁵I were examined after subcutaneous injection in rats. The pharmacokinetic pattern of PEG-rhIL-6 was defined with linear-kinetics, and we fitted a one-compartment model with half-lives of 10.44–11.37 h (absorption, t _{1/2K a}) and 19.77–21.53 h (elimination, t _1/2Ke), and peak concentrations at 20.51–21.96 h (t _peak) in rats. Half-lives and t _peak of PEG-rhIL-6 were longer than those of rhIL-6 previously reported. In the present study, for deposition of PEG-rhIL-6 in rats, the tissue distribution examination showed that blood was the major organ involved, rather than liver. However, as to the elimination of PEG-rhIL-6, the major organ was the kidney. The excretion fraction of the injection dose recovered from urine was 23.32% at 192 h after subcutaneous administration. Less than 6% of PEG-rhIL-6 was eliminated via the feces at 192 h. These results indicate that PEG-rhIL-6 is a good candidate drug formulation for patients with cancer.  相似文献   

丙烯酸酯和醋酸乙烯酯二元共聚物的合成、表征与降凝助滤效果   总被引：1，自引：0，他引：1  

薛兆民  张爱阳 《临沂师范学院学报》2002,24(6):25-27

主要介绍了丙烯酸酯和醋酸乙烯酯二元共聚物（简称AV）类柴油降凝剂的合成和降凝助滤效果。AV柴油降凝剂，是以丙烯酸酯、醋酸乙烯酯为原料，以甲苯为溶剂，以偶氮二异丁腈为引发剂，恒温聚合制得。该剂对胜利油田胜华炼油厂0＃柴油的纯降凝度可达19℃，冷滤点降低可达9℃，对东明、濮阳、汤阴、大庆等地的柴油也有很好的降凝和降冷滤点效果。  相似文献