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本文从距离矩阵和邻接矩阵出发,结合矩阵的数学知识,提出了一种新的拓扑指数Qx=(W×V)1/8,用最小二乘法拟合b.p.(℃),得到线性回归方程为:b.p.(℃)=-277.814+165.248Qx(r=0.993) 相似文献
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Carcinogenic and mutagenic polycyclic aromatic hydrocarbons (PAHs) generated in coal combustion have caused great environmental health concern. Seventeen PAHs (16 high priority PAHs recommended by USEPA plus Benzo[e]pyrene) present in five raw bituminous coals and released during bituminous coal combustion were studied. The effects of combustion temperature, gas atmosphere, and chlorine content of raw coal on PAHs formation were investigated. Two additives (copper and cupric oxide) were added when the coal was burned. The results indicated that significant quantities of PAHs were produced from incomplete combustion of coal pyrolysis products at high temperature, and that temperature is an important causative factor of PAHs formation. PAHs concentrations decrease with the increase of chlorine content in oxygen or in nitrogen atmosphere. Copper and cupric oxide additives can promote PAHs formation (especially the multi-ring PAHs) during coal combustion. 相似文献
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用反相高效液相色谱法测定了１５种致突变硝基多环芳烃的正辛醇－水分配系数和水溶解度，所得结果分别与摇瓶法和动态联柱法测定值相符较好。 相似文献
4.
环境中多环芳烃的研究进展 总被引：1，自引：0，他引：1
潘瑾 《重庆第二师范学院学报》2006,19(3):28-31
介绍了多环芳烃的来源和危害,同时综述了国内外对多环芳烃的样品预处理及检测方法,并对其发展趋势进行了简要讨论。 相似文献
5.
李荣毅 《鞍山师范学院学报》2012,14(2):34-37
通过对鞍山市城区采暖期与非采暖期环境空气中多环芳烃的监测,了解本地区环境空气中多环芳烃的基本分布特征. 相似文献
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Benjamin Bartl Martin Zapletal Štěpán Urbánek Monika Krejčí Slavíková Jiří Trejbal Zdeněk Hrdlička 《文物保护研究》2013,58(3):138-145
ABSTRACTMechanical properties of aged beeswax were studied by an indirect measurement, using hydrogenated beeswax as a model material. The adequacy of the model was evaluated by comparison of its chemical composition and thermal properties with those of samples of historical beeswax. It was found that the gradual decrease in content of unsaturated compounds in beeswax contributes significantly to changes of its mechanical properties. As a consequence, beeswax artefacts become increasingly prone to mechanical damage during natural ageing. Understanding the difference between mechanical properties of recent and historical beeswax is primarily important from the point of view of safe handling and storage of such artefacts. Besides, this knowledge could help conservation scientists, e. g. when preparing model samples for testing new conservation methods. 相似文献
7.
丁爱芳 《南京晓庄学院学报》2007,23(6):63-65
文章研究采集了江苏省南京市六合区农田土壤的表层土(0—15cm),用高效液相色谱测定了土壤中16种多环芳烃(PAHs)的含量.结果表明,采样点土壤中PAHs总量在45.6μg/kg~210.9μg/kg之间.在检测的PAHs中,二环、三环、四环的PAHs含量之和约为总量的51.0%~92.5%.采用PAHs总量和内梅罗综合污染指数方法评价污染水平,南京市六合区农田采样点土壤中PAHs含量基本上是处于安全水平. 相似文献
8.
Xiao-dong LI Yong REN Sha-sha JI Xia-li HOU Tong CHEN Sheng-yong LU Jian-hua YAN 《浙江大学学报(A卷英文版)》2015,(4)
目的：探索中国生活垃圾焚烧残灰中重金属、氯苯、多环芳烃等有毒成分的排放特性、排放水平及相互之间的关联特性,并认识其产生、排放与焚烧炉型、焚烧条件的关联,以探索控制其危害的有效方法。方法：1.对中国几个典型的生活垃圾焚烧炉现场采样,获得多个飞灰和底渣的样品;2.通过多种不同的检测手段和方法,分别检测残灰的基本物理化学特性、氯苯、多环芳烃和主要金属元素的浓度;3.结合焚烧炉型和焚烧特性等条件,分析各有毒成分的排放特性和相互之间的关联特性。结论：1.氯苯、多环芳烃和重金属受焚烧因素影响,在残灰中的排放特性各不相同,流化床焚烧炉能消除焚烧和原始垃圾的扰动,能控制氯苯在残灰中的排放,但多环芳烃排放控制不如炉排焚烧炉;2.残灰中主要的有机有毒成分为高氯代氯苯和2至4环等少环类多环芳烃;3.氯苯和多环芳烃在残灰中的含量可能因为不同的产生机理而表现出一定的负关联特点;4.残灰中的金属主要为铝和铁等轻金属,浓度远高于重金属元素,而无毒重金属（主要为Mn、Ni、As和Zn）浓度高于有毒重金属元素（Cu、Pb和Cr）,且不同金属表现出不同的对氯苯和多环芳烃的催化促进或抑制作用。 相似文献
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对气相色谱-质谱联用仪（GC-MS）和行业标准SH/T0741-2004汽油中烃族组成测定法（多维气相色谱法）在仪器结构、分析原理、分析过程等方面进行比较,并通过实例用GC-MS验证市售汽油组分,得出采用GC-MS分析汽油组分要比行业标准SH/T0741-2004实用、方便、快捷、准确. 相似文献
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根据分子结构的特点 ,用距离矩阵和染色矩阵表征分子中基团的特性和连接性 ,通过探讨芳烃摩尔折射度与分子结构间的定量关系 ,发展一种直接根据分子结构计算芳烃摩尔折射度的方法 .该方法将基团贡献法和拓扑方法有机地结合在一起 ,具有基团贡献法适用范围广和拓扑方法计算结果可靠的特点 .对 2 1 1种烷基苯、烷基萘和烷基联苯的计算结果表明 ,摩尔折射度计算值与实验值的一致性令人满意 ,平均误差 0 55% . 相似文献