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Analysis of a varnish applied by Nicéphore Niépce to make a print used for photographic purpose transparent
Authors:Agns Lattuati-Derieux  Jean-Philippe Echard  Sylvie Thao-Heu  Bertrand Lavdrine
Institution:a MNHN, CNRS, MCC, centre de recherche sur la conservation des collections (CRCC), 36, rue Geoffroy-Saint-Hilaire, CP 21, 75005 Paris, France;b Laboratoire de recherche et de restauration, Musée de la musique, Cité de la musique, 221, avenue Jean-Jaurès, 75019 Paris, France
Abstract:Nicéphore Niépce carried out a lot of meticulous experiments that led him to the invention of photography. In particular, in the 1820s, he obtained heliographs by coating a substrate with a light-sensitive substance, which was then exposed to light under a paper print made translucent with the help of varnish. The objective of the work described here is to determine how Niépce made these paper prints transparent. Did he use his experimental knowledge on photosensitive resins, or did he apply commonly used recipes of his time to make paper transparent? To date, no studies have been carried out on the varnish used by Nicéphore Niépce and no previous research has undertaken analytical investigations on Nicéphore's prints, using Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Gas Chromatography/Mass Spectrometry (GC/MS). In this paper, we identify the varnishes used by Nicéphore Niépce on four transparent prints, now belonging to the Nicéphore Niépce museum in Chalon-sur-Saône, France. The varnish he used was based on a diterpenic Pinaceae sp. resin (most probably colophony). The finding is supported by historical knowledge about varnishes.
Keywords:Nicé  phore Nié  pce  Photography  Print  Infrared  Gas chromatography  Mass spectrometry  Varnish  Diterpenoid resin  Colophony  Venice turpentine
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