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布儒斯特角显微镜和单分子膜表面形貌研究技术
引用本文:刘明贤,甘礼华,陈根,王小兰,陈龙武.布儒斯特角显微镜和单分子膜表面形貌研究技术[J].实验室研究与探索,2005,24(9):15-16.
作者姓名:刘明贤  甘礼华  陈根  王小兰  陈龙武
作者单位:同济大学,化学系,上海,200092
基金项目:上海市科技发展基金资助项目(0352nm094)
摘    要:用布儒斯特角显微镜研究了花生酸分子成膜过程中单分子膜表面形貌的动态变化,发现在气/液界面上花生酸分子首先形成岛状分布,随着表面压的增加形成完整的单分子膜,而当表面压达到崩溃压后薄膜出现裂纹,分子膜重叠,形成多层膜。分析了花生酸单分子膜的形成机理。

关 键 词:单分子膜  表面形貌  花生酸  布儒斯特角显微镜
文章编号:1006-7167(2005)09-0015-02
收稿时间:2005-04-05
修稿时间:2005年4月5日

Research Technique for Surface Morphology of Arachidic Acid Monolayer via BAM
LIU Ming-xian,GAN Li-hua,CHEN Gen,WANG Xiao-lan,CHEN Long-wu.Research Technique for Surface Morphology of Arachidic Acid Monolayer via BAM[J].Laboratory Research and Exploration,2005,24(9):15-16.
Authors:LIU Ming-xian  GAN Li-hua  CHEN Gen  WANG Xiao-lan  CHEN Long-wu
Institution:Dept. of Chemistry, Tongji Univ., Shanghai 200092, China
Abstract:Dynamic domains morphology of arachidic acid monolayer were researched by Brewster angle microscopy(BAM).The results indicate that arachidic acid molecules distribute randomly just as insular domain originally during the formation process of the monolayer at an air/liquid interface,then they are shaped into a whole condensed monolayer with the increase of surface pressure.The monolayer is cracked at the collapse pressure,then they overlap and form a multilayer.The mechanism for this process was analyzed briefly.
Keywords:monolayer  surface morphology  arachidic acid  Brewster angle microscopy(BAM)
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