| [Cu~(2+)(phen)(SCN~-)_2]_n配合物的合成及晶体结构 |
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| 引用本文： | 杜仲祥,王灵芝,吉苏宁.[Cu~(2+)(phen)(SCN~-)_2]_n配合物的合成及晶体结构[J].洛阳师范学院学报,2007,26(2):67-69. |
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| 作者姓名： | 杜仲祥 王灵芝 吉苏宁 |
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| 作者单位： | 1. 洛阳师范学院化学系,河南洛阳,471022
2. 洛阳师范学院科研处,河南洛阳,471022 |
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| 摘 要： | 以1,10-邻菲咯啉为配体,合成了标题配合物,该化合物的分子式Cu2+(phen)(SCN-)2,分子量359.90,采用经单色化的Mo ka(λ=0.71073)射线测定,共收集3850个衍射点,其中独立衍射点1555个,Ι>2ó(I)]可观测点数1233个。结果表明该化合物属单斜晶系,C2/c空间群,其晶胞参数:a=1.4067(3)nm,b=1.03281(18)nm,c=1.02975(18)nm,β=111.104(2)o,V=1.3957(4)nm3,z=4,Dc=1.713g.cm-3,μ=1.859 mm-1,F(000)=724,s=1.024,(Δρ)max=0.307e-3和(Δρ)m in=-0.305e-3。该配合物是四配位的平面四边形结构。
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| 关 键 词： | 1 10-邻菲咯啉 硫氰酸钾 氯化铜 超分子 晶体结构 |
| 文章编号： | 1009-4790（2007）02-0067-03 |
| 修稿时间： | 2007-01-04 |
Synthesis and Crystal Structure of Complex [Cu2+(phen)(SCN-)2]n |
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| DU Zhong-xiang,WANG Ling-zhi,JI Su-ning.Synthesis and Crystal Structure of Complex [Cu2+(phen)(SCN-)2]n[J].Journal of Luoyang Teachers College,2007,26(2):67-69. |
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| Authors: | DU Zhong-xiang WANG Ling-zhi JI Su-ning |
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| Institution: | 1. Chemistry Department, Luoyang Teachers College, Luoyang 471022, China; 2. Scientific Research Management, Luoyang Teachers College, Luoyang 471022, China |
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| Abstract: | The reaction of transition metal with 1,10-phenanthroline base gave the title complex Cu(2+)(phen)(SCN-)2 phen= 1,10-phenanthroline,SCN-=silver thiocyanate],and its crystal structure was determined by x-ray diffraction.The complex crystallizes in monoclinic,space group C2/c with a=1.4067(3)nm,b=1.03281(18)nm,c=1.02975(18) nm β=111.104(2),V=1.3957(4)nm3,z=4,Dc=1.713g.cm(-3),μ=1.859 mm(-1),F(000)=724,s=1.024,(Δρ)max= 0.307 和(Δρ)min =-0.305e(-3).In the complex,the Cu(Ⅱ) atom is four-coordinated to assume a plane quadrilateral geometry. |
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| Keywords: | 1 10-phenanthroline potassium thiocyanate copper chloride supermolecule crystal structure |
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