| Ionic Liquid-Complex Pd/C System as Catalyst for Copolymerization of CO and Styrene简 |
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| 引用本文： | 王海霞,郭锦棠,胡光,冯亚凯,武瑞涛.Ionic Liquid-Complex Pd/C System as Catalyst for Copolymerization of CO and Styrene简[J].天津大学学报(英文版),2014,20(1):48-53. |
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| 作者姓名： | 王海霞 郭锦棠 胡光 冯亚凯 武瑞涛 |
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| 基金项目： | Supported by the Tianjin Natural Science Foundation （No. 07JCYBJC00600）. |
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| 摘 要： | The copolymerization of CO and styrene catalyzed by Pd/C toward the formation of polyketones(PK)was studied in the N-valeronitrile-N'-methylimidazolium hexafluorophosphate(C4CNmim]+PF-6) medium. The synthesized PK was characterized by Fourier transform infrared(FTIR), elemental analysis, 13C-nuclear magnetic resonance(13C-NMR), differential scanning calorimetry(DSC), thermogravimetric analysis(TGA) and gel permeation chromatography(GPC). The supported ionic liquid film on the surface of Pd/C catalyst can prevent the products from covering the hole of active carbon due to its chemical stability and weak coordination ability with metal ions, and thus efficiently improve the catalytic activity. The effects of different amounts of ionic liquid on the catalytic activity and reusability of the catalyst and the molecular weight of PK were discussed. When the usage of ionic liquid is 10wt%(0.1 g ionic liquid / 1 g active carbon carrier) and the theoretical content of Pd2+ is 5wt%(0.05 g Pd2+/ 1 g active carbon carrier), the highest catalytic activity 2 963.64 gSTCO/(gPd·h) is achieved with the molecular weight and polydispersity index of PK as Mn=9 684, Mw=13 452 and Mw /Mn=1.389.
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| 关 键 词： | 离子液体 催化剂 苯乙烯 Pd 共聚 CO 体复合 C系统 |
Ionic liquid-complex Pd/C system as catalyst for copolymerization of CO and styrene |
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| Haixia Wang,Jintang Guo,Guang Hu,Yakai Feng,Ruitao Wu.Ionic liquid-complex Pd/C system as catalyst for copolymerization of CO and styrene[J].Transactions of Tianjin University,2014,20(1):48-53. |
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| Authors: | Haixia Wang Jintang Guo Guang Hu Yakai Feng Ruitao Wu |
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| Institution: | 1. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China
2. College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang, 050024, China
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| Abstract: | The copolymerization of CO and styrene catalyzed by Pd/C toward the formation of polyketones (PK)was studied in the N-valeronitrile-N′-methylimidazolium hexafluorophosphate (C4CNmim]+PF6 -) medium. The synthesized PK was characterized by Fourier transform infrared(FTIR), elemental analysis, 13C-nuclear magnetic resonance (13C-NMR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and gel permeation chromatography (GPC). The supported ionic liquid film on the surface of Pd/C catalyst can prevent the products from covering the hole of active carbon due to its chemical stability and weak coordination ability with metal ions, and thus efficiently improve the catalytic activity. The effects of different amounts of ionic liquid on the catalytic activity and reusability of the catalyst and the molecular weight of PK were discussed. When the usage of ionic liquid is 10wt% (0.1 g ionic liquid / 1 g active carbon carrier) and the theoretical content of Pd2+ is 5wt% (0.05 g Pd2+/ 1 g active carbon carrier), the highest catalytic activity 2 963.64 gSTCO/(gPd · h) is achieved with the molecular weight and polydispersity index of PK as M n = 9 684, M w = 13 452 and M w/M n = 1.389. |
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| Keywords: | supported ionic liquid Pd/C catalyst copolymerization polyketones |
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