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交联高分子溶胀度测定及经验特征函数确定
引用本文:罗文君,刘浴辉,卜庭江.交联高分子溶胀度测定及经验特征函数确定[J].实验技术与管理,2012,29(4):45-47,52.
作者姓名:罗文君  刘浴辉  卜庭江
作者单位:中国地质大学材料与化学学院,湖北武汉,430074
基金项目:国家自然科学基金面上项目
摘    要:将溶胀度的表征由质量改变推演为体积改变,在实验操作上变重量称量为数字化的高度显示,设计了相应的恒温测量装置,使得变温、恒温测量及溶剂组分改变情况下的交联高分子溶胀度的测量可以方便、连续地实施,简化了操作,提高了测量精度。给出几种自行制备的交联高分子样品的测量结果以及藉此建立的表征溶胀动力学过程的经验特征函数。

关 键 词:溶胀度  测量装置  溶胀平衡  体积相变  经验特征函数

Determination on swelling degree of crosslinking polymer and its empirical characteristic function
Luo Wenjun , Liu Yuhui , Bu Tingjiang.Determination on swelling degree of crosslinking polymer and its empirical characteristic function[J].Experimental Technology and Management,2012,29(4):45-47,52.
Authors:Luo Wenjun  Liu Yuhui  Bu Tingjiang
Institution:(Faculty of Material Science & Chemistry,China University of Geosciences,Wuhan 430074,China)
Abstract:The determination of swelling degree is derived to be denoted by volume change instead of mass change,as a result,weighting for a sample can be replaced of a digital altitude display.This paper designs and makes a kind of determining device,and by the device,the swelling degree can be determined continuously and expediently in such cases as changing or constant temperatures and when a sample is in mixed solvents.Using the device,some actual determined results of several homemade samples and empirical characteristic functions have been found as well,which can be used as determination for swelling kinetic process.
Keywords:swelling degree  determining device  swelling equilibrium  phase transition on volume  empirical characteristic function
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