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Pigment identification in a Greek icon by optical microscopy and infrared microspectroscopy
Authors:Dimitra Kovala-Demertzi  Leuteris Papathanasis  Rocco Mazzeo  Mavroudis A Demertzis  Evagelia A Varella  Silvia Prati
Institution:1. Department of Chemistry, University of Ioannina, 45110 Ioannina, Greece;2. Universita’ di Bologna, sede di Ravenna, Via Tombesi dall’Ova 55, 48100 Bologna, Italy;3. Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
Abstract:Optical microscopy, cross-section and fragment Micro-FTIR spectroscopic techniques along with microchemical tests were used for the identification of pigments in two different samples of an icon. Representing the Last Judgement, and painted by the Greek master Ioannis from the village of Kapesovo in the year 1771, the kneeling desk icon under investigation is a noteworthy contribution to the study of materials in post-Byzantine visual arts. The main components found in the ground layer of both samples were gypsum, beeswax and a proteinaceous material. Cinnabar, Prussian blue and cerussite were identified on the paint layers. The binding medium on the paint layers was weddelite. The materials used in the painting and ground layers were characterized in order to clarify the painting technique. Proteinaceous materials have been identified as binders for the pigments, indicating a tempera painting technique.
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