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THE STRUCTURE OF THERMOPLASTIC STARCH
作者姓名:高建平  于九皋  王为
作者单位:天津大学化学系
摘    要:用扫描电镜和偏光显微镜研究了热塑性淀粉的颗粒结构,晶态结构和糊化温度,并用X-射线衍射测定了热塑性淀粉的结晶度和峰型,结果表明在压力、温度、剪切力和添加剂的作用下,原淀粉的颗粒结构和晶态结构受到破坏.淀粉在挤出过程中可熔融,部分晶态结构(球晶)转变为非晶态结构,X-射线衍射峰型也发生变化,说明有配合物生成.

关 键 词:热塑性淀粉,颗粒结构,挤出塑化,糊化温度

THE STRUCTURE OF THERMOPLASTIC STARCH
Abstract:The granular structure, crystal structure and gelatinization temp. of thermoplastic starch were studied with a polarized light microscope and a scanning electron microscope, and the crystallinity and crystalline patterns were determined through X ray diffraction. The results indicate that the original granular structure and spherical crystalline structure of starch were disrupted by the action of pressure, heat and shear force with the help of additives. The starch can be melted during extrusion, and part of the spheric crystal was destroyed and changed into a continual amorphous with a few crystalline fractions dispersed in it. The configuration of starch molecules changed from double helices to single helix, which indicated the formation of the complex.
Keywords:thermoplastic starch  granular structure  gelatinization temperature  extrusion
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