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微电解法处理炼化企业二级出水的研究
引用本文:张淼,张国珍,宋文艳.微电解法处理炼化企业二级出水的研究[J].兰州石化职业技术学院学报,2014(1):13-16.
作者姓名:张淼  张国珍  宋文艳
作者单位:兰州交通大学环境与市政工程学院,甘肃兰州730070
基金项目:长江学者和创新团队发展计划资助项目(IRT0966);国家自然科学基金(51068014);国家支撑计划(2006BAJ08808-03);国际水体污染控制与治理科技重大专项资助项目(2008ZX07425-005)
摘    要:以西北某炼化企业二级出水为研究对象,研究了铁炭在水中微电解作用有效降解CODCr的作用机理。通过微电解降解炼油二级出水CODCr实验,确定了最佳工艺参数:Fe/C质量比为3∶2,海绵铁投加量为15g/L,反应时间为2.5h,反应pH为3,填料粒度范围在1~2mm。在最佳参数运行下,出水CODCr去除率高达75%以上,达到了《城市污水再生利用工业用水水质》(GB/T 19923-2005)出水水质要求。

关 键 词:微电解  炼油废水  深度处理  CODCr

Research on Advanced Treatment for Secondary Effluent of Petrochemical Enterprises by Micro -electrolysis Process
Institution:ZHANG Miao, ZHANG Guo - zhen, SONG Wen -yan( School of Environmental and Municipal Engineering & Institute of Environmental Ecology, Lanzhou Jiaotong University Lanzhou 730070, China )
Abstract:Setting the secondary effluent of a certain refinery in northwest China as the research object, the author researches the mechanism of ferric - carbon micro - electrolysis action to degrade CODer effectively in water. De- grade CODcr of refining secondary effluent by means of micro - electrolysis experiments, meeting water quality re- quirements, " The reuse of urban recycling water - Water quality standard for industrial uses ( GB/T 19923 - 2005 )". At last to define the optimum craft parameters by experiments: the mass ratio of Fe/C is 3:2, the dosage of sponge iron is 15g/L, the reaction time is 2.5h, the pH of the experiment is 3, the packing particle size range is 1 -2mm. Under the optimum operation parameters, removal rate of the effluent CODcr reaches up to 75%, which also enhances the biodegradability of waste water.
Keywords:micro - electrolysis  refinery waste water  advanced treatment  CODcr removal rate
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