| 钼镍催化剂催化合成溴代正辛烷 |
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| 引用本文： | 秦晋颖,邹贵田.钼镍催化剂催化合成溴代正辛烷[J].贵阳金筑大学学报,2008(4). |
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| 作者姓名： | 秦晋颖 邹贵田 |
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| 作者单位： | 贵阳学院生物与环境工程系 |
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| 摘 要： | 以正辛醇和氢溴酸为原料,钼镍粉做催化剂,合成了溴代正辛烷。经实验确定反应条件为:n(氢溴酸)/n(正辛醇)=3.0,催化剂用量为反应物总质量的3%,反应时间2.5h,反应温度128~133℃,溴代正辛烷产率为87.6%,催化剂重复使用,催化活性基本不变。
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| 关 键 词： | 钼镍催化剂 溴代正辛烷 催化 |
Catalytic Synthesis of N-Octyl Bromide by the Solid Mo-Ni Catalyst |
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| QIN Jin-ying Zou Gui-tian.Catalytic Synthesis of N-Octyl Bromide by the Solid Mo-Ni Catalyst[J].Journal of Jinzhu University of Guiyang,2008(4). |
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| Authors: | QIN Jin-ying Zou Gui-tian |
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| Institution: | (Department of Biology and Environmental Engineering; Guiyang University; Guiyang Guizhou 550005; China); |
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| Abstract: | The present article carries our the research on the synthesis of n-bromide with hydrobromic acid and n-octylalcohol by the solid Mo-Ni catalyst.The results showed that the optimum conditions should be that n(hydrobromic acid)/n(n-octylalcohol)=3.0,the amount of catalyst Mo-Ni 3% of total mass of reactants,the reaction time 2.5h and the temperature 128~133℃.The yield of n-octyl bromide was about 87.6%,furthermore the catalyst in the reaction can be reused again and again,and its catalytic activation maintain... |
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| Keywords: | solid mo-ni catalyst n-octyl bromide catalysis |
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