| 对硝基苯腙基取代丙二酸二乙酯的合成及晶体结构 |
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| 引用本文： | 李延红,张甜,杨红兵,王建平.对硝基苯腙基取代丙二酸二乙酯的合成及晶体结构[J].洛阳师范学院学报,2007,26(5):75-77. |
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| 作者姓名： | 李延红 张甜 杨红兵 王建平 |
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| 作者单位： | 1. 洛阳师范学院化学化工学院,河南洛阳,471022;河南省孟津县第一高中,河南孟津,471100
2. 洛阳师范学院化学化工学院,河南洛阳,471022 |
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| 摘 要： | 在冰盐浴条件下,对硝基苯胺重氮盐与丙二酸二乙酯反应,合成了标题化合物C_(13)H_(15)N_3O_7。经IR、~1HNMR、元素分析和X-射线单晶测定,确认了其结构。化合物属单斜晶系,C2/c空间群,晶胞参数:α=14.331(11)■,b=6.847(5)■,c=32.63(3)■,β=98.149(14)°,V=3169(4)■~3,Z=8,D_c=1.364Mg/m~3,μ=0.112 mm~(-1),F (000)=1360,R=0.0783,wR=0.2461。
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| 关 键 词： | 腙 丙二酸二乙酯 晶体结构 生物活性 |
| 文章编号： | 1009-4790（2007）05-0075-03 |
| 修稿时间： | 2007-05-04 |
Synthesis and Crystal Structure of Diethyl Malonate Substituted by p-Nitro-Phenylhydrazonocarboxyl |
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| LI Yan-hong,ZHANG Tian,YANG Hong-bing,WANG Jian-ping.Synthesis and Crystal Structure of Diethyl Malonate Substituted by p-Nitro-Phenylhydrazonocarboxyl[J].Journal of Luoyang Teachers College,2007,26(5):75-77. |
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| Authors: | LI Yan-hong ZHANG Tian YANG Hong-bing WANG Jian-ping |
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| Institution: | 1. Department of Chemistry, Luoyang Normal University, Luoyang 471022, China ;2. The No. 1 Senior High School of Henan Mengjin Luoyang 471100, China |
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| Abstract: | The title compound has been synthesized by the reaction of ice-salt bath using p-nitro-aniline diazo- nium salt and diethyl malonate. Its structure was confirmed by IR、~1H NMR,elemental analysis and X-ray sin- gle-crystal diffraction.A crystal of the title compound is monoclinic with space group C2/c,a=14. 331(11) ■, b=6.847(5)■,c=32.63(3)■,β=98.149(14)°,V=3169(4)■~3,Z=8,D_c=1.364 Mg/ m~3,μ=0. 112mm~(-1),F(000)=1360,R=0.0783,wR=0.2461. |
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| Keywords: | hydrazone diethyl malonate crystal structure biological activity |
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