| 氯酸盐电化生产过程的反应模型 |
| |
| 引用本文： | 朱文化,衣宝廉.氯酸盐电化生产过程的反应模型[J].中国科学院研究生院学报,1995(2). |
| |
| 作者姓名： | 朱文化 衣宝廉 |
| |
| 作者单位： | 中国科学院大连化学物理研究所 |
| |
| 摘 要： | 利用氧阴极与ＤＳＡ阳极组装成一种新型氯酸盐电解槽。在分析阳极表面ＯＣｌ－氧化反应途径的基础上改进了阳极表面的反应模型，对扩散层内氯的水解分率进行了计算，并讨论了活性氯转化反应的活化能、阳极表面流体的流动状态以及氯酸盐浓度与电流效率的关系。
|
| 关 键 词： | 氯酸盐，反应模型，氧阴极 |
Reaction Model at the Anode Surface in the Chlorate Cell Process |
| |
| Zhu Wen-hua, Yi Bao-lian.Reaction Model at the Anode Surface in the Chlorate Cell Process[J].Journal of the Graduate School of the Chinese Academy of Sciences,1995(2). |
| |
| Authors: | Zhu Wen-hua Yi Bao-lian |
| |
| Abstract: | A new chlorate cell system with a DSA anode and an oxygen cathode was set up. The reaction model is improved by analyzing the main way of hypochlorite oxidation at the anode surface. The hydrolysis ratio of chlorine in the diffusion layer is calculated. The activation energy of chemical reaction of active chlorine and the flowing pattern of fluid near-the anode surface as well as the relation between the chlorate concentration and current efficiency are discussed in detail. |
| |
| Keywords: | chlorate cell reaction model oxygen cathode |
| 本文献已被 CNKI 等数据库收录！ |
