| 手性二茂铁亚砜配体的合成研究 |
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| 引用本文： | 李高伟,张晓丽,孟团结,凌翠霞,刘瑛,赵文献.手性二茂铁亚砜配体的合成研究[J].商丘师范学院学报,2012(3):59-63. |
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| 作者姓名： | 李高伟 张晓丽 孟团结 凌翠霞 刘瑛 赵文献 |
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| 作者单位： | 商丘师范学院化学化工学院有机新材料合成重点实验室 |
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| 基金项目： | 国家自然科学基金(20972091)资助项目;河南省教育厅自然科学研究计划(2011B150029)资助项目;商丘师范学院大学生创新性实验计划项目(2010-DXS-28) |
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| 摘 要： | 以二茂铁为原料,经金属锂试剂锂化,亲核取代和硫醚的不对称氧化反应高光学纯地合成了手性二茂铁亚砜配体,其结构经红外光谱,核磁共振谱和质谱等物理手段进行了表征,并测定了该配体的ee值.
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| 关 键 词： | 二茂铁 手性亚砜配体 不对称合成 |
Asymmetric synthesis of ferrocenyl sulfoxide ligand |
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| LI Gaowei,ZHANG Xiaoli,MENG Tuanjie,LING Cuixia,LIU Ying, ZHAO Wenxian.Asymmetric synthesis of ferrocenyl sulfoxide ligand[J].Journal of Shangqiu Teachers College,2012(3):59-63. |
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| Authors: | LI Gaowei ZHANG Xiaoli MENG Tuanjie LING Cuixia LIU Ying ZHAO Wenxian |
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| Institution: | * (School of Chemistry and Chemical Engineering,and Key Laboratory of New Organic Materials Synthesis, Shangqiu Normal Univeristy,Shangqiu 476000,China) |
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| Abstract: | The high optically pure chiral ferrocenyl sulfoxide ligand was achieved by metalation,nucleophilic substitution and asymmetric oxidation of sulfide from cheap and easily available ferrocene.The structure of the ligand was confirmed by IR,NMR and MS,the ee was also determined by HPLC analyses using chiralcel OD column. |
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| Keywords: | ferrocene chiral sulfoxide ligand asymmetric synthesis |
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