质子膜表面粗糙化对质子交换膜燃料电池膜电极性能改善研究 |
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作者姓名: | 张熙贵 夏保佳 刘娟英 王涛 钦佩 |
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作者单位: | 中国科学院上海微系统与信息技术研究所,传感技术国家重点联合实验室,上海,200050 |
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摘 要: | 通过对Nafion117表面粗糙化和“预先溶胀法”制备技术提高了微型PEM燃料电池膜电极(MEA)的极化性能. 循环伏安(CV)和交流阻抗(EIS)等电化学检测手方法证明, Nafion117表面粗糙化后扩展了催化层/质子膜三相界面区域,增大了电化学反应的催化活性点,降低了界面的接触阻抗.
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关 键 词: | 质子交换膜燃料电池 膜电极 Nafion117 粗糙化 极化性能 |
Study on MEA Performance Based on Roughened Nafion117 Membrane |
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Authors: | ZHANG Xi-Gui XIA Bao-Jia LIU Juan-Ying WANG Tao QIN Pei |
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Institution: | State Key Joint Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai, 200050 |
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Abstract: | Polarization performance of the MEA fabricated by surface roughening and solvent pre-treating of Nafion117 membrane was improved. Cyclic Voltammetry (CV) and Electrochemical Impedance Spectra(EIS) analysis suggested that the three-phases interface of catalyst/ membrane was expanded and the interface contact impedance was reduced with the roughened Nafion117 membrane as the MEA’s separator. |
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Keywords: | µ PEMFC MEA Nafion117 membrane Surface roughening Polarization performance |
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