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质子膜表面粗糙化对质子交换膜燃料电池膜电极性能改善研究
作者姓名:张熙贵  夏保佳  刘娟英  王涛  钦佩
作者单位:中国科学院上海微系统与信息技术研究所,传感技术国家重点联合实验室,上海,200050
摘    要:通过对Nafion117表面粗糙化和“预先溶胀法”制备技术提高了微型PEM燃料电池膜电极(MEA)的极化性能. 循环伏安(CV)和交流阻抗(EIS)等电化学检测手方法证明, Nafion117表面粗糙化后扩展了催化层/质子膜三相界面区域,增大了电化学反应的催化活性点,降低了界面的接触阻抗.

关 键 词:质子交换膜燃料电池  膜电极  Nafion117  粗糙化  极化性能  

Study on MEA Performance Based on Roughened Nafion117 Membrane
Authors:ZHANG Xi-Gui  XIA Bao-Jia  LIU Juan-Ying  WANG Tao  QIN Pei
Institution:State Key Joint Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai, 200050
Abstract:Polarization performance of the MEA fabricated by surface roughening and solvent pre-treating of Nafion117 membrane was improved. Cyclic Voltammetry (CV) and Electrochemical Impedance Spectra(EIS) analysis suggested that the three-phases interface of catalyst/ membrane was expanded and the interface contact impedance was reduced with the roughened Nafion117 membrane as the MEA’s separator.
Keywords:µ  PEMFC  MEA  Nafion117 membrane  Surface roughening  Polarization performance  
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