| 二苯胺在抗爆剂TKC组分1,2-二氯乙烷中电子转移性质的研究 |
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| 引用本文： | 郁章玉,靳明,齐丽云.二苯胺在抗爆剂TKC组分1,2-二氯乙烷中电子转移性质的研究[J].临沂师范学院学报,2003,25(6):1-4. |
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| 作者姓名： | 郁章玉 靳明 齐丽云 |
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| 作者单位： | 曲阜师范大学,化学科学学院,山东,曲阜,273165 |
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| 基金项目： | 山东省自然科学基金资助(Y2000B03) |
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| 摘 要： | 采用气相色谱／质谱联用技术(GC／MS)分析抗爆剂TKC辅助剂的成分．以抗爆剂的常用调合组分1，2-二氯乙烷做溶剂利用循环伏安法研究二苯胺的电子转移性质．结果表明：二苯胺类正离子自由基发生“尾-尾”偶合为联苯胺类化合物．
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| 关 键 词： | 抗爆剂 气相色谱／质谱联用 二苯胺 循环伏安 电子转移性质 |
| 文章编号： | 1009-6051(2003)06-0001-04 |
| 修稿时间： | 2003年10月29 |
Electron Transfer Properties of DipHenylamine in 1,2- Dichloromethane of TKC Antiknock |
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| YU Zhang-yu,JIN Ming,QI Li-yun.Electron Transfer Properties of DipHenylamine in 1,2- Dichloromethane of TKC Antiknock[J].Journal of Linyi Teachers' College,2003,25(6):1-4. |
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| Authors: | YU Zhang-yu JIN Ming QI Li-yun |
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| Abstract: | Gas chromatograpHy/mass spectrometry (GC/MS) was used to analyze the chemical constituents of TKC antiknock. Electron transfer properties of dipHenylamine was studied by cyclic voltammetry in 1,2-Dichloromethane elected from TKC Antiknock. Experimental results indicate that low parent concentration and nonaqueous solvents are in favor of substituted benzidine produced by tail-tail coupling of cation radicals. |
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| Keywords: | antiknock GC/MS dipHenylamine cyclic voltammetry electron transfer properties |
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