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金微粒和聚苯胺修饰电极对亚硝酸根电催化氧化研究
引用本文:郝玉翠,李秀荣,吴楠.金微粒和聚苯胺修饰电极对亚硝酸根电催化氧化研究[J].唐山学院学报,2010(3):59-60,63.
作者姓名:郝玉翠  李秀荣  吴楠
作者单位:1. 唐山学院环境与化学工程系,河北唐山,063000
2. 唐山学院学报编辑部,河北唐山,063000
基金项目:唐山市科学技术研究与发展计划项目(09130212c)
摘    要:通过在玻碳电极(GCE)表面电化学沉积金(Au)微粒和聚苯胺(PAni)制备了Au微粒和聚苯胺修饰的玻碳电极(Au/PAni/GCE),并通过循环伏安法研究了亚硝酸根在该修饰电极上的电化学行为,以及探讨了修饰电极对亚硝酸根电催化氧化性能的影响因素。结果表明:Au/PAni/GCE对亚硝酸根具有良好的电催化氧化作用,该性能受聚苯胺和Au微粒的负载量以及底液pH值的影响。

关 键 词:金微粒  聚苯胺  修饰电极  亚硝酸根

The Study on Elecrocatalytic Oxidation of Nitrite by Au Particles and Polyaniline Modified Electrode
HAO Yu-cui,LI Xiu-rong,WU Nan.The Study on Elecrocatalytic Oxidation of Nitrite by Au Particles and Polyaniline Modified Electrode[J].Journal of Tangshan College,2010(3):59-60,63.
Authors:HAO Yu-cui  LI Xiu-rong  WU Nan
Institution:(a. Department of Environmental & Chemical Engineering, Tangshan College, Tangshan 063000, China;b. Edito rial Department, Tangshan College, Tangshan 063000, China)
Abstract:Au particles and polyaniline modified glass carbon electrode (Au/PAni/GCE) was prepared by electrochemically deposite. The electrochemical behaviors of nitrite on Au/PAni/GCE were studied with cyclic voltammetry and the influencing factors of elecrocatalytic oxidation of nitrite on Au/PAni/GCE were discussed. The result show that Au/PAni/GCE has favorable elecrocatalytic oxidation of nitrite and the elecrocatalytic oxidation of nitrite is affected by the amount of polyaniline and Au particles and the pH of base solution.
Keywords:Au particles  polyaniline  modified electrode  nitrite
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