| 走向现实的“纳米催化” |
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| 引用本文： | 包信和,申文杰,潘秀莲,傅 强,李微雪.走向现实的“纳米催化”[J].中国科学院院刊,2011(Z1):39-45. |
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| 作者姓名： | 包信和 申文杰 潘秀莲 傅 强 李微雪 |
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| 作者单位： | 催化基础国家重点实验室(中国科学院大连化学物理研究所) 大连 116023;催化基础国家重点实验室(中国科学院大连化学物理研究所) 大连 116023;催化基础国家重点实验室(中国科学院大连化学物理研究所) 大连 116023;催化基础国家重点实验室(中国科学院大连化学物理研究所) 大连 116023;催化基础国家重点实验室(中国科学院大连化学物理研究所) 大连 116023 |
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| 摘 要： | 作为关键和核心技术,催化在能源、环境、农业以及人类健康等领域正发挥着越来越重要的作用。借助纳米科学和技术的发展和进步,以纳米体系的电子调制为理论基础,通过纳米层次对催化剂形貌的调变,高活性晶面定量设计和控制暴露得以实现;从理论上预示并实验验证了碳纳米管的“协同限域效应”和金属??氧化物的“界面限域效应”。根据大量的实验研究和理论分析,提出“纳米限域催化”的新概念,并在CO氧化、合成气定向转化和燃料电池相关的催化过程中得到了初步验证。
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| 关 键 词： | 催化 纳米 碳材料 能源 |
| 收稿时间： | 2011/1/13 0:00:00 |
Nanocatalysis Toward Reality |
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| Bao Xinhe,Shen Wenjie,Pan Xiulian,Fu Qiang and Li Weixue.Nanocatalysis Toward Reality[J].Bulletin of the Chinese Academy of Sciences,2011(Z1):39-45. |
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| Authors: | Bao Xinhe Shen Wenjie Pan Xiulian Fu Qiang and Li Weixue |
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| Institution: | State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, CAS 116023 Dalian;State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, CAS 116023 Dalian;State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, CAS 116023 Dalian;State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, CAS 116023 Dalian;State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, CAS 116023 Dalian |
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| Abstract: | Several examples have been presented to demonstrate a successful translation of the novel concepts of nano-confined catalysis into the real catalytic processes. The concepts shown in the model catalysts are based on the synergetic electorn confinements derived from the channels of carbon nanotubes and the interface between noble-metal and oxides with coordinately unsaturated low valent states. Their realization and application in several catalytic reactions, such as selective oxidation and syngas conversion illustrate a promising and efficient way to design active sites for nanocatalysts. |
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| Keywords: | catalysis nano carbon material energy |
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