| 化学反应动力学 |
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| 引用本文： | 戴东旭,张东辉,杨学明.化学反应动力学[J].中国科学院院刊,2011(Z1):80-92. |
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| 作者姓名： | 戴东旭 张东辉 杨学明 |
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| 作者单位： | 分子反应动力学国家重点实验室(中国科学院大连化学物理研究所) 大连 116023;分子反应动力学国家重点实验室(中国科学院大连化学物理研究所) 大连 116023;分子反应动力学国家重点实验室(中国科学院大连化学物理研究所) 大连 116023 |
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| 摘 要： | 氟原子加氢分子及其同位素分子的反应(F+H2/D2/HD)在化学反应动力学的研究发展中一直扮演着重要的角色。在过去的10年里,科学家们通过精心设计的实验和高精度的理论计算,使得有关该反应体系的态-态动力学研究,特别是对反应机制、过渡态结构及其动力学性质、非绝热效应的认识有了长足的进步,得到了有关F+H2这个教科书式的反应体系动力学行为的结论性的研究成果。
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| 关 键 词： | 氟原子 氢分子 化学反应动力学 反应过渡态 非绝热效应 |
| 收稿时间： | 2010/12/2 0:00:00 |
Dynamics of F+H2 Reaction and Its Isotopic Analogs |
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| Dai Dongxu,Zhang Donghui and Yang Xueming.Dynamics of F+H2 Reaction and Its Isotopic Analogs[J].Bulletin of the Chinese Academy of Sciences,2011(Z1):80-92. |
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| Authors: | Dai Dongxu Zhang Donghui and Yang Xueming |
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| Institution: | State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, CAS 116023 Dalian;State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, CAS 116023 Dalian;State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, CAS 116023 Dalian |
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| Abstract: | The reaction of F+H2 reaction and its isotopic variants have played a central role in the development of chemical reaction dynamics. Using improved experimental and theoretical methods, we have made significant advances in the study of the state-to-state chemical dynamics of these reactions in recent years. Strong interactions between theory and experiment have significantly enhanced our understandings of reaction mechanism, transition state, and non-adiabatic effect of these reactions, providing the textbook-like examples of dynamical resonances in elementary chemical reactions. |
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| Keywords: | F atom H2 molecular chemical reaction dynamics transition state of reaction non-adiabatic effect |
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