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新型有机锡化物作为润滑添加剂的合成与摩擦学特性
引用本文:刘仁德,陶德华,赵源,曹卫国,张建华,付尚发.新型有机锡化物作为润滑添加剂的合成与摩擦学特性[J].上海大学学报(英文版),2004,8(1).
作者姓名:刘仁德  陶德华  赵源  曹卫国  张建华  付尚发
摘    要:


Preparation and Tribological Performance of Novel Organotin Compound as Lubricant Additive
LIU Ren-de,TAO De-hua,ZHAO Yuan,CAO Wei-guo,ZHANG Jian-hua,FU Shang-fa.Preparation and Tribological Performance of Novel Organotin Compound as Lubricant Additive[J].Journal of Shanghai University(English Edition),2004,8(1).
Authors:LIU Ren-de  TAO De-hua  ZHAO Yuan  CAO Wei-guo  ZHANG Jian-hua  FU Shang-fa
Abstract:Oil-soluble stannous naphthenate (SN) is synthesized by using naphthenatic acid and SnO.And its molecular structure is confirmed by IR and multielement oil analyzer (MOA).The tribological performances of the organotin as lubricant additive are evaluated with a four-ball friction and wear tester.These experiments indicate that the wear scar diameter (WSD) and friction coefficient are diminished while the load-carrying capability increased by comparison with that of base oil.The elemental composition of the boundary lubricating film is examined by means of Auger electron spectroscopy (AES).Synergistic effect is found in the load-carrying capability of the complex of SN and sulfured olefin.The analytical results of AES indicate that the good performance of stannous naphthenate is attributed to the formation of a boundary lubricating film containing Sn on the rubbed surface.
Keywords:stannous naphthenate  organotin  synthesis  additive  tribological performance  synergistic effect
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