| NO3^-对B-Z振荡反应的影响及其在分析中的应用 |
| |
| 引用本文： | 杨秋玲.NO3^-对B-Z振荡反应的影响及其在分析中的应用[J].临沂师范学院学报,2008,30(3):54-57. |
| |
| 作者姓名： | 杨秋玲 |
| |
| 作者单位： | 临沂师范学院,化学化工学院,山东,临沂,276005 |
| |
| 摘 要： | 研究了NO3^-对B-Z化学振荡反应的影响．结果表明：NO3^-的加入明显改变该振荡反应的诱导期，且诱导期的改变值△tin与所加入NO3^-的浓度有良好的线性关系，线性范围3．334×10^-5-1．000×10^-3mol·L^-1，相关系数为0．9959．NO3^-CH2（COOH）2-KBrO3-H2SO4-Ce（SO4）2振荡体系诱导期表观活化参数Ein为109．1kJ·mol^-1．
|
| 关 键 词： | 硝酸根 振荡反应 诱导期 |
Effect of NO-3 on the B-Z Oscillating Chemical Reaction and Its Analytical Application |
| |
| YANG Qiu-ling.Effect of NO-3 on the B-Z Oscillating Chemical Reaction and Its Analytical Application[J].Journal of Linyi Teachers' College,2008,30(3):54-57. |
| |
| Authors: | YANG Qiu-ling |
| |
| Institution: | YANG Qiu-ling (School of Chemistry and Chemical Engineering, Linyi Normal University, Linyi Shandong 276005, China) |
| |
| Abstract: | The effect of NO3^- on the B-Z oscillating chemical reaction was studied. The results show that the addition of NO3^- can change the induction period of the proposed system and the change of induction period （Atin） is linearly proportional to the concentration of NO3^- added in the range of 3.334× 10^-5-1.000× 10^-3mol·L^-1, with the regression coefficient of 0.9959. The apparent activation Parameter of inductory phase （Ein） is obtained,Ein = 109.1kJ·mol^-1 |
| |
| Keywords: | NO3- B-Z oscillating chemical reaction induction period |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
