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锌和镉与均苯三酰胺甘氨酸配合物的合成与荧光性能研究
引用本文:徐涵,潘兆瑞.锌和镉与均苯三酰胺甘氨酸配合物的合成与荧光性能研究[J].嘉应学院学报,2014,32(11):42-45.
作者姓名:徐涵  潘兆瑞
作者单位:1. 黄山学院化学化工学院,安徽黄山,245041
2. 南京晓庄学院生物化工与环境工程学院,南京,211171
基金项目:国家自然科学基金青年基金,安徽高校省级自然科学研究项目,安徽高校省级优秀青年人才基金项目
摘    要:以均苯三酰胺甘氨酸为配体,合成了Zn3L2·15H2O]n(1)和Cd3L2·DMF·7H2O]n(2)(L=均苯三酰胺甘氨酸,DMF=N,N-二甲基甲酰胺).并对其进行了元素分析、红外光谱、热重分析、X-射线粉末衍射和荧光光谱测定,与配体相比,Zn3L2·15H2O]n(1)和Cd3L2·DMF·7H2O]n(2)的荧光光谱发生了不同程度的红移和蓝移,其最大发射峰分别在467nm和428nm.

关 键 词:晶体结构  锌离子  镉离子  配合物  荧光性质

Synthesis and Fluorescence Properties of Zinc and Cadmium Complexes with N,N , N-Tris (carboxymethyl)-1,3,5-benzenetricarboxamide
XU Han,PAN Zhao-ru.Synthesis and Fluorescence Properties of Zinc and Cadmium Complexes with N,N , N-Tris (carboxymethyl)-1,3,5-benzenetricarboxamide[J].Journal of Jiaying University,2014,32(11):42-45.
Authors:XU Han  PAN Zhao-ru
Institution:XU Han, PAN Zhao - ru (1. School of Chemistry and Chemical Engineering, Huangshan University, Huangshan 245041, China; 2. School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University , Nanjing 211171, China)
Abstract:With N, N , N - Tris ( carboxymethyl - 1,3,5 ) - benzenetricarboxamide as ligand, Zn3 L2 · 15H20 ] ( 1 ) and Cd3 L2 · DMF - 7 H2O ] = (2) was synthesized ( L = N, N , N - Tris ( carboxymethyl - 1,3,5 ) - benzene- tricarboxamide, DMF = N, N -Dimethylformamide). The two complexes were characterized by elemental analysis, infrared spectrum,thermal analysis,X- ray powder diffraction and fluorescence spectrum. Compared with the lig- and, the fluorescence spectrum happens red shift and blue shift for Zn3L2 · 15H2O]n( 1 ) and Cd3L2 · DMF · 7H2O]n(2) ,and the maximum emission peaks are at 467nm and 428nm.
Keywords:Methanesulfonate  Pb - Sn - Cu  solution performance
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