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Reductive cyclodimerization of arylmethylidenemalononitriles promoted by samarium and catalytic amount of iodine:facile synthesis of cyclopentene derivanves
Abstract:Samarium and a catalytic amount of iodine were used to obtain functionalized cyclopentenes by reductive dimerization followed by intramolecular cyclization of 1,1-dicyanoalkenes under mild conditions.
Keywords:Metallic samarium  Catalyzed by iodine  1  1-dicyanoalkenes  Reductive cyclodimerization  Cyclopentene derivatives
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