Fe3O4@PCDP纳米复合材料的制备及其在类芬顿体系中的应用 |
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作者姓名: | 陈凤霞 马家海 |
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作者单位: | 1. 中国科学院大学中丹学院, 北京 100190;
2. 中国科学院大学化学科学学院, 北京 100049 |
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基金项目: | Supported by the National Natural Science Foundation of China(21377126,41573115) and Science and Education Integration Foundation of Institute of Chemistry, Chinese Academy of Sciences |
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摘 要: | 制备Fe3O4@PCDP纳米复合材料作为高效、环境友好的异相类芬顿催化剂,探究其对罗丹明B(RhB)的降解性能。借助XRD、FTIR和SEM等方式对Fe3O4@PCDP纳米复合材料的结构进行表征,结果显示催化剂成功制备。并探究H2O2用量和pH对罗丹明B降解效果的影响。在最佳反应条件下,反应42 h后RhB去除率可达到87.25%。循环3次依然具有较好降解效果,且催化剂结构未变化,催化性能稳定。
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关 键 词: | Fe3O4@PCDP 催化剂 芬顿反应 |
收稿时间: | 2019-03-04 |
修稿时间: | 2019-04-17 |
Preparation of Fe3O4@PCDP nanocomposite and its application in Fenton-like system |
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Authors: | CHEN Fengxia MA Jiahai |
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Institution: | 1. Sino-Danish College, University of Chinese Academy of Sciences, Beijing 100190, China;
2. School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China |
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Abstract: | In this study, a Fe3O4@PCDP nanocomposite is prepared as a highly efficient and eco-friendly heterogeneous Fenton-like catalyst that is used for the degradation of Rhodamine (RhB). The structure of the Fe3O4@PCDP nanocomposite is characterized by XRD, FTIR, and SEM, and the results demonstrate that it is synthesized successfully. The catalytic capacity of Fe3O4@PCDP is evaluated on the basis of various parameters, including the concentration of H2O2 and the pH value. The removal rate of RhB reaches 87.25% 42 h after the reaction under the optimal condition. The structure of Fe3O4@PCDP does not change and the catalytic performance is stable after the third cycle. |
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Keywords: | Fe3O4@PCDP" target="_blank">3O4@PCDP')">Fe3O4@PCDP catalyst Fenton reaction |
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