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加氢脱硫滴流床反应器数学模型的建立和工业应用
引用本文:吴楠,廖尾英,董少英.加氢脱硫滴流床反应器数学模型的建立和工业应用[J].唐山学院学报,2022,35(3):71-76.
作者姓名:吴楠  廖尾英  董少英
作者单位:唐山学院 新材料与化学工程学院, 河北 唐山 063000;唐山工业职业技术学院 继续教育学院, 河北 唐山 063299;唐钢美锦(唐山)煤化工有限公司, 河北 唐山 063700
摘    要:在前期研究获得催化剂Co-Mo/Al2O3-TiO2加氢脱硫动力学数据的基础上,对加氢脱硫滴流床反应器进行研究,建立数学模型,用于模拟百万吨柴油加氢脱硫滴流床反应器的传质传热过程、床层压降大小及催化剂使用效果。结果显示,生产硫含量符合欧Ⅳ车用标准的柴油,催化床层高度需要8.5 m;床层压降和床层温度变化均在合理范围内。

关 键 词:滴流床反应器  催化加氢脱硫  数学模型

Construction and Industrial Application of the Mathematical Model for Hydrodesulfurization Trickle-Bed Reactor
WU Nan,LIAO Wei-ying,DONG Shao-ying.Construction and Industrial Application of the Mathematical Model for Hydrodesulfurization Trickle-Bed Reactor[J].Journal of Tangshan College,2022,35(3):71-76.
Authors:WU Nan  LIAO Wei-ying  DONG Shao-ying
Institution:School of New Materials and Chemical Engineering, Tangshan University, Tangshan 063000, China;School of Continuing Education, Tangshan Polytechnic College, Tangshan 063299, China; Tanggang Meijin(Tangshan) Coal Chemical Industry Co. Ltd, Tangshan 063700, China
Abstract:Based on the kinetic data of Co Mo/Al2O3-TiO2 catalyst in the previous hydrodesulfurization, the trickle-bed hydrodesulfurization reactor is studied, and the mathematical model is established to simulate the mass and heat transfer process, bed pressure drop value and the catalytic effect of the million-ton diesel hydrodesulfurization trickle-bed reactor. The results show that the production of the diesel with the sulfur content in accordance with the European IV automotive standard requires the catalytic bed height of 8.5 m, and the bed pressure drop and the bed temperature change within a reasonable range.
Keywords:trickle-bed reactor  catalytic hydrodesulfurization  mathematical model
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