| 溶液体系配合物稳定常数间定量关系的研究进展(Ⅱ) --配合物稳定常数间的定量关系 |
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| 引用本文： | 郭峰,董晓宁,朱元成.溶液体系配合物稳定常数间定量关系的研究进展(Ⅱ) --配合物稳定常数间的定量关系[J].天水师范学院学报,2003,23(5):29-31. |
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| 作者姓名： | 郭峰 董晓宁 朱元成 |
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| 作者单位： | 1. 天水师范学院,化学系,甘肃,天水,741001
2. 兰州农业学校,甘肃,兰州,730020 |
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| 摘 要： | 配合物稳定常数的应用日趋广泛，研究表明在相关联的配合物稳定常数间也存在定量的经验关系。通过配合物稳定常数间的直线自由能关系、logK与logKM(OH) 之间的线性关系、Irving-Williams 序列关系、稳定常数与Lewis酸碱参数的关系、镧系及锕系元素碳酸配合物稳定常数的计算等定量关系分析，表明溶液体系中配位化学的研究进展。
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| 关 键 词： | 配位化学 稳定常数 定量关系 |
| 文章编号： | 1371-1351(2003)05-0029-03 |
| 修稿时间： | 2003年6月11日 |
The Research Advance of Quantitative Relationships among the Stability Constants of Complexes in Solution System |
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| GUO Feng,DONG Xiao-ning,ZHU Yuan-cheng.The Research Advance of Quantitative Relationships among the Stability Constants of Complexes in Solution System[J].Journal of Tianshui Normal University,2003,23(5):29-31. |
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| Authors: | GUO Feng DONG Xiao-ning ZHU Yuan-cheng |
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| Institution: | GUO Feng1,DONG Xiao-ning2,ZHU Yuan-cheng1 |
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| Abstract: | By analyzing the quantitative relationships existing among stability constants, such as the Linear Free Energy Relationship (LFER), the linear relationship between logK and logKM(OH), irving-Williams order, the degree of stability constants relied on the acid-base parameter, and the stability constant's computation of lanthanide and actinoid complexes containing carbonate ion, the advance in coordination chemistry in solution systems has been reviewed with 10 references. |
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| Keywords: | Coordination chemistry Stability constants Quantitative relationships application |
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